In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 44, No. 8 ( 1989-8-1), p. 893-895
Abstract:
The colourless compound RbLiS has been prepared as described earlier (H. Sabrowsky, A. Thimm, and P. Vogt-Mertens, Z. Naturforsch. 40b, 1759 (1985)) and its crystal structure determined by X-ray diffraction. Very hygroscopic RbLiS crystallizes in the tetragonal space group P4/nmm (Z = 2) with the cell parameters a = 4.424(3) Å, c = 7.255(2) Å. The structure was solved from 1635 counter reflections (155 symmetry independent reflections) by Patterson and Fourier methods (R = 0.031; wR = 0.031). The structure is characterized by layers of ∞ 2 [LiS 4/4 ]-tetrahedrons separated by double-layers of Rb + to form a PbFCl-type geometry.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-1989-0806
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
1989
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
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