UID:
almahu_9949697830902882
Format:
1 online resource (429 p.)
ISBN:
1-281-05012-1
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9786611050122
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0-08-048123-X
Content:
More sulfuric acid is produced every year than any other chemical. It has a wide range of uses including phosphate fertilizer production, explosives, glue, wood preservatives, and lead-acid batteries. It is also a particularly corrosive and dangerous acid, with extreme environmental and health hazards if not manufactured, used, and regulated properly.Sulfuric Acid Manufacture: Analysis, Control and Optimization keeps the important topics of safety and regulation at the forefront as it overviews and analyzes the process of sulfuric acid manufacture.The first nine chapte
Note:
Description based upon print version of record.
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Front Cover; Title Page; Copyright Page; Preface; Table of Contents; Chapter 1 Overview; 1.1 Catalytic Oxidation of SO2 to SO3; 1.2 H2SO4 Production; 1.3 Industrial Flowsheet; 1.4 Sulfur Burning; 1.5 Metallurgical Offgas; 1.6 Spent Acid Regeneration; 1.7 Sulfuric Acid Product; 1.8 Recent Developments; 1.9 Alternative Process; 1.10 Summary; Suggested Reading; References; Chapter 2 Production and Consumption; 2.1 Uses; 2.2 Acid Plant Locations and Costs; 2.3 Price; 2.4 Summary; Suggested Reading; References; Chapter 3 Sulfur Burning; 3.1 Objectives; 3.2 Sulfur; 3.3 Molten Sulfur Delivery
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3.4 Sulfur Atomizers and Sulfur Burning Furnaces3.5 Product Gas; 3.6 Summary; References; Chapter 4 Metallurgical Offgas Cooling and Cleaning; 4.1 Initial and Final SO2 Concentrations; 4.2 Initial and Final Dust Concentrations; 4.3 Offgas Cooling and Heat Recovery; 4.4 Electrostatic Collection of Dust; 4.5 Water Scrubbing; 4.6 H2O(g) Removal from Scrubber Exit Gas; 4.7 Summary; Suggested Reading; References; Chapter 5 Regeneration of Spent Sulfuric Acid; 5.1 Spent Acid Compositions; 5.2 Spent Acid Handling; 5.3 Decomposition; 5.4 Decomposition Furnace Product
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5.5 Optimum Decomposition Furnace Operating Conditions5.6 Preparation of Offgas for SO2 Oxidation and H2SO4 Making; 5.7 Summary; Suggested Reading; References; Chapter 6 Dehydrating Air and Gases with Strong Sulfuric Acid; 6.1 Objectives; 6.2 Dehydration with Strong Sulfuric Acid; 6.3 Residence Times; 6.4 Recent Advances; 6.5 Summary; Suggested Reading; References; Chapter 7 Catalytic Oxidation of SO2 to SO3; 7.1 Objectives; 7.2 Industrial SO2 Oxidation; 7.3 Catalyst Necessity; 7.4 SO2 Oxidation 'Heatup' Path; 7.5 Industrial Multi Catalyst Bed SO2 Oxidation; 7.6 Industrial Operation
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7.7 Recent Advances7.8 Summary; Suggested Reading; References; Chapter 8 SO2 Oxidation Catalyst and Catalyst Beds; 8.1 Catalytic Reactions; 8.2 Maximum and Minimum Catalyst Operating Temperatures; 8.3 Composition and Manufacture; 8.4 Choice of Size and Shape; 8.5 Choice of Chemical Composition; 8.6 Catalyst Bed Thickness and Diameter; 8.7 Gas Residence Times; 8.8 Catalyst Bed Maintenance; 8.9 Summary; Suggested Reading; References; Chapter 9 Production of H2SO4(l) from SO3(g); 9.1 Objectives; 9.2 Sulfuric Acid Rather than Water; 9.3 Industrial H2SO4 Making
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9.4 Choice of Input and Output Acid Compositions9.5 Acid Temperatures; 9.6 Gas Temperatures; 9.7 Operation and Control; 9.8 Double Contact H2SO4 Making; 9.9 Intermediate vs. Final H2SO4 Making; 9.10 Summary; Suggested Reading; References; Chapter 10 Oxidation of SO2 to SO3 - Equilibrium curves; 10.1 Catalytic Oxidation; 10.2 Equilibrium Equation; 10.3 KE as a Function of Temperature; 10.4 KE in Terms of % SO2 Oxidized; 10.5 Equilibrium % SO2 Oxidized as a Function of Temperature; 10.6 Discussion; 10.7 Summary; Reference; Problems; Chapter 11 SO2 Oxidation Heatup Paths; 11.1 Heatup Paths
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11.2 Objectives
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English
Additional Edition:
ISBN 0-08-044428-8
Language:
English
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