UID:
almahu_9949697284502882
Format:
1 online resource (305 p.)
ISBN:
1-282-25767-6
,
9786612257674
,
0-08-088612-4
Series Statement:
Advances in physical organic chemistry,
Content:
Advances in Physical Organic Chemistry provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry. The field is a rapidly developing one, with results and methodologies finding application from biology to solid state physics.* Reviews the application of quantitative and mathematical methods towards understanding chemical problems * Covers organic, organometallic, bioorganic, enzymes and materials topics
Note:
Description based upon print version of record.
,
Front Cover; Advances in Physical Organic Chemistry Volume 43; Copyright Page; Table of Contents; Editor's Preface; Contributors to Volume 43; Chapter 1 Kinetic medium effects on organic reactions in aqueous colloidal solutions; 1 Introduction; 2 Self-aggregating amphiphiles; 3 Reactivity effects in aqueous colloidal solutions; 4 Kinetic models; 5 Hydrotropes and organic reactivity; 6 Micelles and organic reactivity; 7 Vesicles and organic reactivity; 8 Conclusions and future directions; Acknowledgments; References; Chapter 2 Photoremovable protecting groups based on photoenolization
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1 Introduction2 Photoenolization; 3 Photorelease via photoenolization; 4 Conclusion; Acknowledgments; References; Chapter 3 The chemistry of reactive radical intermediates in combustion and the atmosphere; 1 Introduction; 2 Basic concepts of combustion chemistry; 3 Reactive radical intermediate chemistry in combustion; 4 Future challenges in combustion chemistry; 5 Conclusions; Acknowledgments; References; Chapter 4 Stable carbocations and onium ions from polycondensed aromatic and heteroaromatic compounds as models for biological electrophiles and; 1 Introduction; 2 Protocols
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3 Pyrenium ions4 Phenanthrenium ions; 5 Benzanthracenium ions; 6 Chyrsenium and benzo[c]phenanthrenium ions; 7 Carbenium ions and onium cations from hetero-PAHs; 8 Carbenium ions derived from nonalternant PAHs; 9 Miscellaneous systems; 10 Concluding remarks; Acknowledgement; References; Chapter 5 Structural and biological impact of radical addition reactions with DNA nucleobases; 1 Introduction; 2 Hydroxyl and nitrogen dioxide radicals; 3 Alkyl radicals; 4 Aryl radicals; 5 Phenoxyl radicals; 6 Summary; Acknowledgments; References; Chapter 6 Recent studies of persistent carbodications
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1 Introduction2 Gitonic methylium-based carbodi- and polycations; 3 1,2-Carbodications; 4 1,3-Carbodications; 5 1,4-Carbodications; 6 1,5-Carbodications; 7 Benzyl dications; 8 1,6-Carbodications; 9 μ-Hydrido dications; 10 Aromatic dications; 11 Oxygen-stabilized carbodications; References; Author Index; Cumulative Index of Authors; Cumulative Index of Titles; Subject Index
,
English
Additional Edition:
ISBN 0-12-374749-X
Language:
English
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