UID:
almahu_9949580755402882
Format:
1 online resource (365 p.)
Edition:
1st ed.
ISBN:
1-283-34799-7
,
9786613347992
,
0-12-387773-3
Series Statement:
Advances in catalysis, v. 54
Content:
Advances in Catalysis fills the gap between the journal papers and the textbooks across the diverse areas of catalysis research. For more than 60 years Advances in Catalysis has been dedicated to recording progress in the field of catalysis and providing the scientific community with comprehensive and authoritative reviews. This series in invaluable to chemical engineers, physical chemists, biochemists, researchers and industrial chemists working in the fields of catalysis and materials chemistry. * In-depth, critical, state-of-the-art reviews * Comprehensive, covers of all as
Note:
Description based upon print version of record.
,
Front Cover; Advances in: Catalysis; Copyright; Contents; Contributors; Preface; Chapter 1: Designing Molecular Catalysts with Enhanced Lewis Acidity; 1. Introduction; 2. Conceptual Background: Generating a More Lewis Acidic Catalytic Center; 3. Attachment of the Oxygen Center Around the Active Metal: Development of Molecular Catalysts Based on the MOM1 Motif...; 3.1. Synthons for Heterometallic Complexes: Main-Group and Transition Metal Hydroxides; 3.1.1. Organic-Substituted Calcium and Strontium Hydroxides; 3.1.2. Aluminum Hydroxides; 3.1.3. Gallium Hydroxides
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3.1.4. Germanium(II) Hydroxide3.1.5. Zirconium Hydroxide; 3.1.6. Silanetriols; 3.2. Synthetic Strategy for Construction of MOM1 Motif; 3.3. Chemical Grafting of a Lewis Acid with Catalytically Active Transition Metals; 3.3.1. Aluminum Oxide with Group-4 Metallocenes; 3.3.2. Half-Metallocene Group-4 Metal Precursors on Aluminum Oxide Surfaces; 3.3.3. Heterometallic Oxides of Aluminum and Non-Metallocene Group-4 Metal Precursors; 3.4. Ethylene Polymerization with Lewis Acid Grafted Heterometallic Catalysts; 3.4.1. Catalytic Activity; 3.4.2. Catalytic Activity and Computational Study
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3.5. Hetero Transition Metals: Assembly and Development of Bimodal Catalyst3.6. Investigation of the Catalytically Active Species; 3.7. Investigations of Styrene Polymerization; 3.8. Construction of AlOLn Motif for Ring-Opening Polymerization Catalysis; 3.8.1. Ring-Opening Polymerization of -Caprolactone; 3.9. Olefin Epoxidation Catalysis; 3.10. Development of Hydroformylation Catalysts; 3.10.1. Hydroformylation of 1-Hexene with Oxygen-Bridged Heterometallic Catalysts; 3.10.2. Water-Soluble Biphasic Hydroformylation Catalysts; 3.11. Effect of Bridging Oxygen
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4. Organometallic Fluorides of Group-4 Metals as Efficient Catalysts for Polymerization5. Summary and Conclusions; Acknowledgments; References; Chapter 2: Modern Strategies in Supramolecular Catalysis; 1. Introduction; 2. Supramolecular Assemblies as Models of Specific Enzyme Functions; 2.1. Binding Site in Close Proximity to a Catalytic or Reactive Center; 2.2. Supramolecular Catalytic Assemblies for Two Simultaneously Complexed Reagents; 2.3. Isolation of the Reactive Species from Solution by Reversible Encapsulation; 3. Synthesis Strategies for Supramolecular Catalysts
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3.1. Assembling the Catalyst Backbone by Using Supramolecular Interactions3.2. Artificial Biomacromolecules for Asymmetric Catalysis; 4. Immobilization of Catalysts on Solid Supports Via Supramolecular Interactions; 5. Conclusions and Outlook; Acknowledgments; References; Chapter 3: Mechanistic Issues in Fischer-Tropsch Catalysis; 1. Introduction; 2. Microkinetics Expressions; 2.1. The Sachtler-Biloen Mechanism (CO Dissociation Mechanism); 2.2. The Pichler-Schulz Mechanism (CO Insertion Route); 3. Physical Chemistry of Elementary Surface Reaction Steps
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3.1. Activation of CO: Structure Dependence and Trends as a Function of Metal
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English
Additional Edition:
ISBN 0-12-387772-5
Language:
English
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