Format:
Online-Ressource
ISSN:
1099-0682
Content:
Abstract: The reactions of 1‐chloro‐1H‐phosphirenes 5 with disodium tetracarbonlyferrate lead to the selective formation of the mono complexed bi‐1H‐phosphirenes 7, which are converted into the doubly complexed species 9 upon treatment with diiron nonacarbonyl. Photochemical opening of one of the two three‐membered ring systems in 9 furnishes the bridged complexes 10 containing phosphirene and phosphaallyl units together with an iron‐iron σ‐bond.
In:
volume:2001
In:
number:8
In:
year:2001
In:
pages:2067-2073
In:
extent:7
In:
European journal of inorganic chemistry, Weinheim : Wiley-VCH, 1998-, 2001, Heft 8 (2001), 2067-2073 (gesamt 7), 1099-0682
Language:
English
DOI:
10.1002/1099-0682(200108)2001:8〈2067::AID-EJIC2067〉3.0.CO;2-R
URN:
urn:nbn:de:101:1-2023110603435021893570
URL:
https://doi.org/10.1002/1099-0682(200108)2001:8〈2067::AID-EJIC2067〉3.0.CO;2-R
URL:
https://nbn-resolving.org/urn:nbn:de:101:1-2023110603435021893570
URL:
https://d-nb.info/1308700997/34
URL:
https://doi.org/10.1002/1099-0682(200108)2001:8〈2067::AID-EJIC2067〉3.0.CO;2-R
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