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  • 1
    Online Resource
    Online Resource
    Elsevier BV ; 2019
    In:  Journal of Hydrology Vol. 577 ( 2019-10), p. 123950-
    In: Journal of Hydrology, Elsevier BV, Vol. 577 ( 2019-10), p. 123950-
    Type of Medium: Online Resource
    ISSN: 0022-1694
    Language: English
    Publisher: Elsevier BV
    Publication Date: 2019
    detail.hit.zdb_id: 240687-1
    detail.hit.zdb_id: 1473173-3
    SSG: 13
    SSG: 14
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  • 2
    In: Scientific Data, Springer Science and Business Media LLC, Vol. 9, No. 1 ( 2022-02-10)
    Abstract: Time series of the natural isotopic composition ( 2 H, 18 O) of precipitation and streamwater can provide important insights into ecohydrological phenomena at the catchment scale. However, multi-year, high-frequency isotope datasets are generally scarce, limiting our ability to study highly dynamic short-term ecohydrological processes. Here we present four years of daily isotope measurements in streamwater and precipitation at the Alp catchment (area 47 km 2 ) in Central Switzerland and two of its tributaries (0.7 km 2 and 1.6 km 2 ). This data set reveals short-term responses of streamflow isotopes to precipitation events, which otherwise remain obscured when isotopes are sampled weekly or monthly. The observations span the period June 2015 through May 2019, during which several hydrometeorologic extreme events occurred, including a very dry summer in 2018 and below-average snow accumulation in winter 2016/2017. In addition, we provide daily time series of key hydrometeorological variables that, in combination with the isotope data, can be useful for assessing the robustness of ecohydrological models.
    Type of Medium: Online Resource
    ISSN: 2052-4463
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2022
    detail.hit.zdb_id: 2775191-0
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  • 3
    In: Biogeosciences, Copernicus GmbH, Vol. 15, No. 21 ( 2018-10-30), p. 6399-6415
    Abstract: Abstract. In this commentary, we summarize and build upon discussions that emerged during the workshop “Isotope-based studies of water partitioning and plant–soil interactions in forested and agricultural environments” held in San Casciano in Val di Pesa, Italy, in September 2017. Quantifying and understanding how water cycles through the Earth's critical zone is important to provide society and policymakers with the scientific background to manage water resources sustainably, especially considering the ever-increasing worldwide concern about water scarcity. Stable isotopes of hydrogen and oxygen in water have proven to be a powerful tool for tracking water fluxes in the critical zone. However, both mechanistic complexities (e.g. mixing and fractionation processes, heterogeneity of natural systems) and methodological issues (e.g. lack of standard protocols to sample specific compartments, such as soil water and xylem water) limit the application of stable water isotopes in critical-zone science. In this commentary, we examine some of the opportunities and critical challenges of isotope-based ecohydrological applications and outline new perspectives focused on interdisciplinary research opportunities for this important tool in water and environmental science.
    Type of Medium: Online Resource
    ISSN: 1726-4189
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2018
    detail.hit.zdb_id: 2158181-2
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  • 4
    Online Resource
    Online Resource
    Copernicus GmbH ; 2019
    In:  Hydrology and Earth System Sciences Vol. 23, No. 7 ( 2019-07-15), p. 2983-3005
    In: Hydrology and Earth System Sciences, Copernicus GmbH, Vol. 23, No. 7 ( 2019-07-15), p. 2983-3005
    Abstract: Abstract. Rain-on-snow (ROS) events in mountainous catchments can cause enhanced snowmelt, leading to an increased risk of destructive winter floods. However, due to differences in topography and forest cover, the generation of snowpack outflow volumes and their contribution to streamflow are spatially and temporally variable during ROS events. In order to adequately predict such flood events with hydrological models, an enhanced process understanding of the contribution of rainwater and snowmelt to stream water is needed. In this study, we monitored and sampled snowpack outflow with fully automated snowmelt lysimeter systems installed at three different elevations in a pre-Alpine catchment in central Switzerland. We measured snowpack outflow volumes during the winters of 2017 and 2018, as well as snowpack outflow isotopic compositions in winter 2017. Snowpack outflow volumes were highly variable in time and space, reflecting differences in snow accumulation and melt. In winter 2017, around 815 mm of snowpack outflow occurred at our reference site (grassland 1220 m a.s.l. – metres above sea level), whereas snowpack outflow was 16 % less at the nearby forest site (1185 m a.s.l.), and 62 % greater at another grassland site located 200 m higher (1420 m a.s.l.). A detailed analysis of 10 ROS events showed that the differences in snowpack outflow volumes could be explained mainly by rainfall volumes and initial snow depths. The isotope signals of snowpack outflow were more damped than those of incoming rainwater at all three sites, with the most damped signal at the highest elevation site because its snowpack was the thickest and the residence times of liquid water in its snowpack were the longest, thus enhancing isotopic mixing in the snowpack. The contribution of snowpack outflow to streamflow, estimated with an isotope-based two-component end-member mixing model, differed substantially among the three lysimeter sites (i.e. between 7±4 and 91±21 %). Because the vegetation in our study catchment is a mixture of grassland and forest, with elevations ranging from 1000 to 1500 m a.s.l., our site-specific hydrograph separation estimates can only provide a range of snowpack outflow contributions to discharge from different parts of the study area. Thus, the catchment-average contribution of snowpack outflow to stream discharge is likely to lie between the end-member mixing estimates derived from the three site-specific data sets. This information may be useful for improving hydrological models in snow-dominated catchments.
    Type of Medium: Online Resource
    ISSN: 1607-7938
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2019
    detail.hit.zdb_id: 2100610-6
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  • 5
    Online Resource
    Online Resource
    Copernicus GmbH ; 2018
    In:  Hydrology and Earth System Sciences Vol. 22, No. 7 ( 2018-07-19), p. 3841-3861
    In: Hydrology and Earth System Sciences, Copernicus GmbH, Vol. 22, No. 7 ( 2018-07-19), p. 3841-3861
    Abstract: Abstract. The young water fraction Fyw, defined as the proportion of catchment outflow younger than approximately 2–3 months, can be estimated directly from the amplitudes of seasonal cycles of stable water isotopes in precipitation and streamflow. Thus, Fyw may be a useful metric in catchment inter-comparison studies that investigate landscape and hydro-climatic controls on streamflow generation. Here, we explore how Fyw varies with catchment characteristics and climatic forcing, using an extensive isotope data set from 22 small- to medium-sized (0.7–351 km2) Swiss catchments. We find that flow-weighting the tracer concentrations in streamwater resulted in roughly 26 % larger young water fractions compared to the corresponding unweighted values, reflecting the fact that young water fractions tend to be larger when catchments are wet and discharge is correspondingly higher. However, flow-weighted and unweighted young water fractions are strongly correlated with each other among the catchments. They also correlate with terrain, soil, and land-use indices, as well as with mean precipitation and measures of hydrologic response. Within individual catchments, young water fractions increase with discharge, indicating an increase in the proportional contribution of faster flow paths at higher flows. We present a new method to quantify the discharge sensitivity of Fyw, which we estimate as the linear slope of the relationship between the young water fraction and flow. Among the 22 catchments, discharge sensitivities of Fyw are highly variable and only weakly correlated with Fyw itself, implying that these two measures reflect catchment behaviour differently. Based on strong correlations between the discharge sensitivity of Fyw and several catchment characteristics, we suggest that low discharge sensitivities imply greater persistence in the proportions of fast and slow runoff flow paths as catchment wetness changes. In contrast, high discharge sensitivities imply the activation of different dominant flow paths during precipitation events, such as when subsurface water tables rise into more permeable layers and/or the river network expands further into the landscape.
    Type of Medium: Online Resource
    ISSN: 1607-7938
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2018
    detail.hit.zdb_id: 2100610-6
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  • 6
    Online Resource
    Online Resource
    Copernicus GmbH ; 2020
    In:  Hydrology and Earth System Sciences Vol. 24, No. 3 ( 2020-03-06), p. 1101-1107
    In: Hydrology and Earth System Sciences, Copernicus GmbH, Vol. 24, No. 3 ( 2020-03-06), p. 1101-1107
    Abstract: Abstract. Recent virtual and experimental investigations have shown that the young water fraction Fyw (i.e. the proportion of catchment outflow younger than circa 2–3 months) increases with discharge in most catchments. The discharge sensitivity of Fyw has been defined as the rate of increase in Fyw with increasing discharge (Q) and has been estimated by the linear regression slope between Fyw and Q, hereafter called DS(Q). The combined use of both metrics, Fyw and DS(Q), provides a promising method for catchment inter-comparison studies that seek to understand streamflow generation processes. Here we explore the discharge sensitivity of Fyw in the intensively sampled small Mediterranean research catchment Can Vila. Intensive sampling of high flows at Can Vila allows young water fractions to be estimated for the far upper tail of the flow frequency distribution. These young water fractions converge toward 1 at the highest flows, illustrating a conceptual limitation in the linear regression method for estimating DS(Q) as a metric of discharge sensitivity: Fyw cannot grow with discharge indefinitely, since the fraction of young water in discharge can never be larger than 1. Here we propose to quantify discharge sensitivity by the parameter of an exponential-type equation that expresses how Fyw varies with discharge. The exponential parameter (Sd) approximates DS(Q) at moderate discharges where Fyw is well below 1; however, the exponential equation and its discharge sensitivity metric better capture the non-linear relationship between Fyw and Q and are robust with respect to changes in the range of sampled discharges, allowing comparisons between catchments with strongly contrasting flow regimes.
    Type of Medium: Online Resource
    ISSN: 1607-7938
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2020
    detail.hit.zdb_id: 2100610-6
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  • 7
    Online Resource
    Online Resource
    Copernicus GmbH ; 2020
    In:  Hydrology and Earth System Sciences Vol. 24, No. 5 ( 2020-05-15), p. 2561-2576
    In: Hydrology and Earth System Sciences, Copernicus GmbH, Vol. 24, No. 5 ( 2020-05-15), p. 2561-2576
    Abstract: Abstract. Studying the response of streamwater chemistry to changes in discharge can provide valuable insights into how catchments store and release water and solutes. Previous studies have determined concentration–discharge (cQ) relationships from long-term, low-frequency data of a wide range of solutes. These analyses, however, provide little insight into the coupling of solute concentrations and flow during individual hydrologic events. Event-scale cQ relationships have rarely been investigated across a wide range of solutes and over extended periods of time, and thus little is known about differences and similarities between event-scale and long-term cQ relationships. Differences between event-scale and long-term cQ behavior may provide useful information about the processes regulating their transport through the landscape. Here we analyze cQ relationships of 14 different solutes, ranging from major ions to trace metals, as well as electrical conductivity, in the Swiss Erlenbach catchment. From a 2-year time series of sub-hourly solute concentration data, we determined 2-year cQ relationships for each solute and compared them to cQ relationships of 30 individual events. The 2-year cQ behavior of groundwater-sourced solutes was representative of their cQ behavior during hydrologic events. Other solutes, however, exhibited very different cQ patterns at the event scale and across 2 consecutive years. This was particularly true for trace metals and atmospheric and/or biologically active solutes, many of which exhibited highly variable cQ behavior from one event to the next. Most of this inter-event variability in cQ behavior could be explained by factors such as catchment wetness, season, event size, input concentrations, and event-water contributions. We present an overview of the processes regulating different groups of solutes, depending on their origin in and pathways through the catchment. Our analysis thus provides insight into controls on solute variations at the hydrologic event scale.
    Type of Medium: Online Resource
    ISSN: 1607-7938
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2020
    detail.hit.zdb_id: 2100610-6
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  • 8
    Online Resource
    Online Resource
    Copernicus GmbH ; 2020
    In:  Hydrology and Earth System Sciences Vol. 24, No. 12 ( 2020-12-08), p. 5821-5834
    In: Hydrology and Earth System Sciences, Copernicus GmbH, Vol. 24, No. 12 ( 2020-12-08), p. 5821-5834
    Abstract: Abstract. Automated field sampling of streamwater or precipitation for subsequent analysis of stable water isotopes (2H and 18O) is often conducted with off-the-shelf automated samplers. However, when water samples are stored in the field for days and weeks in open bottles inside autosamplers, their isotopic signatures can be altered by evaporative fractionation and vapor mixing. We therefore designed an evaporation protection method which modifies autosampler bottles using a syringe housing and silicone tube, and we tested whether this method reduces evaporative fractionation and vapor mixing in water samples stored for up to 24 d in 6712 full-size portable samplers (Teledyne ISCO, Lincoln, USA). Laboratory and field tests under different temperature and humidity conditions showed that water samples in bottles with evaporation protection were far less altered by evaporative fractionation and vapor mixing than samples in conventional open bottles. Our design is a cost-efficient approach to upgrade the 1 L sample bottles of the ISCO autosamplers, allowing secure water sample collection in warm and dry environments. Our design can be readily adapted (e.g., by using a different syringe size) to fit the bottles used by many other field autosamplers.
    Type of Medium: Online Resource
    ISSN: 1607-7938
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2020
    detail.hit.zdb_id: 2100610-6
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  • 9
    Online Resource
    Online Resource
    Copernicus GmbH ; 2017
    In:  Hydrology and Earth System Sciences Vol. 21, No. 3 ( 2017-03-23), p. 1721-1739
    In: Hydrology and Earth System Sciences, Copernicus GmbH, Vol. 21, No. 3 ( 2017-03-23), p. 1721-1739
    Abstract: Abstract. High-frequency measurements of solutes and isotopes (18O and 2H) in rainfall and streamflow can shed important light on catchment flow pathways and travel times, but the workload and sample storage artifacts involved in collecting, transporting, and analyzing thousands of bottled samples severely constrain catchment studies in which conventional sampling methods are employed. However, recent developments towards more compact and robust analyzers have now made it possible to measure chemistry and water isotopes in the field at sub-hourly frequencies over extended periods. Here, we present laboratory and field tests of a membrane-vaporization continuous water sampler coupled to a cavity ring-down spectrometer for real-time measurements of δ18O and δ2H combined with a dual-channel ion chromatograph (IC) for the synchronous analysis of major cations and anions. The precision of the isotope analyzer was typically better than 0.03 ‰ for δ18O and 0.17 ‰ for δ2H in 10 min average readings taken at intervals of 30 min. Carryover effects were less than 1.2 % between isotopically contrasting water samples for 30 min sampling intervals, and instrument drift could be corrected through periodic analysis of secondary reference standards. The precision of the ion chromatograph was typically  ∼  0.1–1 ppm or better, with relative standard deviations of  ∼  1 % or better for most major ions in stream water, which is sufficient to detect subtle biogeochemical signals in catchment runoff. We installed the coupled isotope analyzer/IC system in an uninsulated hut next to a stream of a small catchment and analyzed stream water and precipitation samples every 30 min over 28 days. These high-frequency measurements facilitated a detailed comparison of event-water fractions via endmember mixing analysis with both chemical and isotope tracers. For two events with relatively dry antecedent moisture conditions, the event-water fractions were 〈 21 % based on isotope tracers but were significantly overestimated (40 to 82 %) by the chemical tracers. These observations, coupled with the storm-to-storm patterns in precipitation isotope inputs and the associated stream water isotope response, led to a conceptual hypothesis for runoff generation in the catchment. Under this hypothesis, the pre-event water that is mobilized by precipitation events may, depending on antecedent moisture conditions, be significantly shallower, younger, and less mineralized than the deeper, older water that feeds baseflow and thus defines the pre-event endmember used in hydrograph separation. This proof-of-concept study illustrates the potential advantages of capturing isotopic and hydrochemical behavior at a high frequency over extended periods that span multiple hydrologic events.
    Type of Medium: Online Resource
    ISSN: 1607-7938
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2017
    detail.hit.zdb_id: 2100610-6
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  • 10
    Online Resource
    Online Resource
    Copernicus GmbH ; 2018
    In:  Hydrology and Earth System Sciences Vol. 22, No. 11 ( 2018-11-13), p. 5847-5865
    In: Hydrology and Earth System Sciences, Copernicus GmbH, Vol. 22, No. 11 ( 2018-11-13), p. 5847-5865
    Abstract: Abstract. Catchment response to precipitation is often investigated using two-component isotope-based hydrograph separation, which quantifies the contribution of precipitation (i.e., event water Qe) or water from storage (i.e., pre-event water Qpe) to total discharge (Q) during storm events. In order to better understand streamflow-generating mechanisms, two-component hydrograph separation studies often seek to relate the event-water fraction Qe∕Q to storm characteristics or antecedent wetness conditions. However, these relationships may be obscured because the same factors that influence Qe also necessarily influence total discharge Q as well. Here we propose that the fractions of event water and pre-event water relative to total precipitation (Qe∕P and Qpe∕P), instead of total discharge, provide useful alternative tools for studying catchment storm responses. These two quantities separate the well-known runoff coefficient (Q∕P, i.e., the ratio between total discharge and precipitation volumes over the event timescale) into its contributions from event water and pre-event water. Whereas the runoff coefficient Q∕P quantifies how strongly precipitation inputs affect streamflow, the fractions Qe∕P and Qpe∕P track the sources of this streamflow response. We use high-frequency measurements of stable water isotopes for 24 storm events at a steep headwater catchment (Erlenbach, central Switzerland) to compare the storm-to-storm variations in Qe/Q,Qe/P and Qpe∕P. Our analysis explores how storm characteristics and antecedent wetness conditions affect the mobilization of event water and pre-event water at the catchment scale. Isotopic hydrograph separation shows that catchment outflow was typically dominated by pre-event water, although event water exceeded 50 % of discharge for several storms. No clear relationships were found linking either storm characteristics or antecedent wetness conditions with the volumes of event water or pre-event water (Qe, Qpe), or with event water as a fraction of discharge (Qe∕Q), beyond the unsurprising correlation of larger storms with greater Qe and greater total Q. By contrast, event water as a fraction of precipitation (Qe∕P) was strongly correlated with storm volume and intensity but not with antecedent wetness, implying that the volume of event water that is transmitted to streamflow increases more than proportionally with storm size under both wet and dry conditions. Conversely, pre-event water as a fraction of precipitation (Qpe∕P) was strongly correlated with all measures of antecedent wetness but not with storm characteristics, implying that wet conditions primarily facilitate the mobilization of old (pre-event) water, rather than the fast transmission of new (event) water to streamflow, even at a catchment where runoff coefficients can be large. Thus, expressing event- and pre-event-water volumes as fractions of precipitation rather than discharge was more insightful for investigating the Erlenbach catchment's hydrological behaviour. If Qe∕P and Qpe∕P exhibit similar relationships with storm characteristics and antecedent wetness conditions in other catchments, we suggest that these patterns may potentially be useful as diagnostic “fingerprints” of catchment storm response.
    Type of Medium: Online Resource
    ISSN: 1607-7938
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2018
    detail.hit.zdb_id: 2100610-6
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