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  • Brantley, Susan L.  (7)
  • Lebedeva, Marina I.  (7)
  • 1
    In: Chemical Geology, Elsevier BV, Vol. 276, No. 3-4 ( 2010-09), p. 129-143
    Type of Medium: Online Resource
    ISSN: 0009-2541
    Language: English
    Publisher: Elsevier BV
    Publication Date: 2010
    detail.hit.zdb_id: 1492506-0
    SSG: 13
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  • 2
    Online Resource
    Online Resource
    Wiley ; 2021
    In:  Hydrological Processes Vol. 35, No. 2 ( 2021-02)
    In: Hydrological Processes, Wiley, Vol. 35, No. 2 ( 2021-02)
    Abstract: Knowing little about how porosity and permeability are distributed at depth, we commonly develop models of groundwater by treating the subsurface as a homogeneous black box even though porosity and permeability vary with depth. One reason for this depth variation is that infiltrating meteoric water reacts with minerals to affect porosity in localized zones called reaction fronts. We are beginning to learn to map and model these fronts beneath headwater catchments and show how they are distributed. The subsurface landscapes defined by these fronts lie subparallel to the soil‐air interface but with lower relief. They can be situated above, below, or at the water table. These subsurface landscapes of reaction are important because porosity developed from weathering can control subsurface water storage. In addition, porosity often changes at the weathering fronts, and when this affects permeability significantly, the front can act like a valve that re‐orients water flowing through the subsurface. We explore controls on the positions of reaction fronts under headwater landscapes by accounting for the timescales of erosion, chemical equilibration, and solute transport. One strong control on the landscape of subsurface reaction is the land surface geometry, which is in turn a function of the erosion rate. In addition, the reaction fronts, like the water table, are strongly affected by the lithology and water infiltration rate. We hypothesize that relationships among the land surface, reaction fronts, and the water table are controlled by feedbacks that can push landscapes towards an ‘ideal hill’. In this steady state, reaction‐front valves partition water volumes into shallow and deep flowpaths. These flows dissolve low‐ and high‐solubility minerals, respectively, allowing their reaction fronts to advance at the erosion rate. This conceptualization could inform better models of subsurface porosity and permeability, replacing the black box.
    Type of Medium: Online Resource
    ISSN: 0885-6087 , 1099-1085
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2021
    detail.hit.zdb_id: 1479953-4
    SSG: 14
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  • 3
    Online Resource
    Online Resource
    Wiley ; 2017
    In:  Earth Surface Processes and Landforms Vol. 42, No. 13 ( 2017-10), p. 2090-2108
    In: Earth Surface Processes and Landforms, Wiley, Vol. 42, No. 13 ( 2017-10), p. 2090-2108
    Abstract: We explore the contribution of fractures (joints) in controlling the rate of weathering advance for a low‐porosity rock by using methods of homogenization to create averaged weathering equations. The rate of advance of the weathering front can be expressed as the same rate observed in non‐fractured media (or in an individual block) divided by the volume fraction of non‐fractured blocks in the fractured parent material. In the model, the parent has fractures that are filled with a more porous material that contains only inert or completely weathered material. The low‐porosity rock weathers by reaction‐transport processes. As observed in field systems, the model shows that the weathering advance rate is greater for the fractured as compared to the analogous non‐fractured system because the volume fraction of blocks is 〈 1. The increase in advance rate is attributed both to the increase in weathered material that accompanies higher fracture density, and to the increase in exposure of surface of low‐porosity rock to reaction‐transport. For constant fracture aperture, the weathering advance rate increases when the fracture spacing decreases. Equations describing weathering advance rate are summarized in the ‘List of selected equations’. If erosion is imposed at a constant rate, the weathering systems with fracture‐bounded bedrock blocks attain a steady state. In the erosional transport‐limited regime, bedrock blocks no longer emerge at the air‐regolith boundary because they weather away. In the weathering‐limited (or kinetic) regime, blocks of various size become exhumed at the surface and the average size of these exposed blocks increases with the erosion rate. For convex hillslopes, the block size exposed at the surface increases downslope. This model can explain observations of exhumed rocks weathering in the Luquillo mountains of Puerto Rico. Published 2017. This article is a U.S. Government work and is in the public domain in the USA
    Type of Medium: Online Resource
    ISSN: 0197-9337 , 1096-9837
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2017
    detail.hit.zdb_id: 1479188-2
    SSG: 14
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  • 4
    Online Resource
    Online Resource
    Wiley ; 2020
    In:  Earth Surface Processes and Landforms Vol. 45, No. 3 ( 2020-03-15), p. 652-665
    In: Earth Surface Processes and Landforms, Wiley, Vol. 45, No. 3 ( 2020-03-15), p. 652-665
    Abstract: We present a model of chemical reaction within hills to explore how evolving porosity (and by inference, permeability) affects flow pathways and weathering. The model consists of hydrologic and reactive‐transport equations that describe alteration of ferrous minerals and feldspar. These reactions were chosen because previous work emphasized that oxygen‐ and acid‐driven weathering affects porosity differently in felsic and mafic rocks. A parameter controlling the order of the fronts is presented. In the absence of erosion, the two reaction fronts move at different velocities and the relative depths depend on geochemical conditions and starting composition. In turn, the fronts and associated changes in porosity drastically affect both the vertical and lateral velocities of water flow. For these cases, estimates of weathering advance rates based on simple models that posit unidirectional constant‐velocity advection do not apply. In the model hills, weathering advance rates diminish with time as the Darcy velocities decrease with depth. The system can thus attain a dynamical steady state at any erosion rate where the regolith thickness is constant in time and velocities of both fronts become equal to one another and to the erosion rate. The slower the advection velocities in a system, the faster it attains a steady state. For example, a massive rock with relatively fast‐dissolving minerals such as diabase – where solute transport across the reaction front mainly occurs by diffusion – can reach a steady state more quickly than granitoid rocks in which advection contributes to solute transport. The attainment of a steady state is controlled by coupling between weathering and hydrologic processes that force water to flow horizontally above reaction fronts where permeability changes rapidly with depth and acts as a partial barrier to fluid flow. Published 2020. This article is a U.S. Government work and is in the public domain in the USA.
    Type of Medium: Online Resource
    ISSN: 0197-9337 , 1096-9837
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2020
    detail.hit.zdb_id: 1479188-2
    SSG: 14
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  • 5
    Online Resource
    Online Resource
    Wiley ; 2013
    In:  Earth Surface Processes and Landforms Vol. 38, No. 15 ( 2013-12), p. 1793-1807
    In: Earth Surface Processes and Landforms, Wiley, Vol. 38, No. 15 ( 2013-12), p. 1793-1807
    Type of Medium: Online Resource
    ISSN: 0197-9337
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2013
    detail.hit.zdb_id: 1479188-2
    SSG: 14
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  • 6
    Online Resource
    Online Resource
    American Journal of Science (AJS) ; 2023
    In:  American Journal of Science Vol. 323 ( 2023-2-7)
    In: American Journal of Science, American Journal of Science (AJS), Vol. 323 ( 2023-2-7)
    Abstract: Despite its importance, only a few researchers have incorporated the effects of fracturing into models of reactive transport for rock weathering. Here we explore 2D simulations that describe weathering under conditions of diffusive and advective transport within heterogeneous media consisting of rocky blocks and fractures. In our simulations, the Darcy velocities vary in space and time and depend on weathering processes within the rock matrix. We explore simulations with saturated and unsaturated flow for weathering bedrock that consists of blocks separated by inert or weathered material. The simulations show that a simplified homogenized model can approximate exact solutions for some of the simulated columns and hills and can allow exploration of coupling between flow and reaction in fractured rock. These hillslope simulations document that, even in the presence of 2D water flow, i) an increase in fracture density results in faster weathering advance rates; and ii) the water table locates deeper for a rock system that is weathered and fractured rather than weathered and unfractured. Some of these patterns have also been observed for natural systems. But these simulations also highlight how simplified models that do not use appropriate averaging of heterogeneities can be inaccurate in predicting weathering rate for natural systems. For example, if water flows both vertically and laterally through the vadose zone of a hill, then a prediction of the depth of regolith that is based on modeling strictly unidirectional downward infiltration will be unrealistically large. Likewise, if the fracture density observed near the land surface is used in a model to predict depth of weathering for a system where the fracture density decreases downward, the model will overestimate regolith depth. Learning how to develop accurately homogenized models could thus enable better conceptual models and predictions of weathering advance in natural systems.
    Type of Medium: Online Resource
    ISSN: 1945-452X , 0002-9599
    RVK:
    Language: English
    Publisher: American Journal of Science (AJS)
    Publication Date: 2023
    detail.hit.zdb_id: 2065810-2
    detail.hit.zdb_id: 2534734-2
    SSG: 13
    SSG: 25
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  • 7
    In: Geomorphology, Elsevier BV, Vol. 277 ( 2017-01), p. 100-117
    Type of Medium: Online Resource
    ISSN: 0169-555X
    Language: English
    Publisher: Elsevier BV
    Publication Date: 2017
    detail.hit.zdb_id: 2001554-9
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