In:
Australian Journal of Chemistry, CSIRO Publishing, Vol. 50, No. 9 ( 1997), p. 879-
Abstract:
The crystal and molecular structures of
Ru4(µ-H)4(CO)11(CNBut) (2), obtained with Ru4(µ-
H)4(CO)10(CNBut)2 by hydrogenation of
Ru5(µ5-CNBut)(CO)14(CNBut) (1), have been determined. Crystals of (2) are monoclinic, space group
P 21/c, with a 12·349(1), b
11·627(3), c 17·0222(7) Å, β 105·785(4)°, V 2351·9(6)
Å3 and Z 4. The structure was solved by direct methods and refined using 4478 reflections to final
R 0·028(Rw0·033).
An improved procedure for the preparation of (1) in 35–40% yields is also described.
Type of Medium:
Online Resource
ISSN:
0004-9425
Language:
English
Publisher:
CSIRO Publishing
Publication Date:
1997
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