In:
Angewandte Chemie, Wiley, Vol. 129, No. 43 ( 2017-10-16), p. 13557-13561
Abstract:
Ferrocene, Cp 2 Fe, is quantitatively protonated in a mixture of liquid HF/PF 5 to yield [Cp 2 FeH](PF 6 ), which was characterized by 1 H/ 13 C NMR and 57 Fe Mössbauer spectroscopy as well as single‐crystal X‐ray diffraction analysis. X‐ray diffraction analysis at 100 K revealed a disordered, iron‐coordinated hydrido ligand, which was unambiguously located by aspherical atom refinement at 100 K, and by analyzing the non‐disordered crystal structure at 30 K, revealing a non‐agostic structure.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v129.43
DOI:
10.1002/ange.201704854
Language:
English
Publisher:
Wiley
Publication Date:
2017
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