In:
Zeitschrift für Naturforschung C, Walter de Gruyter GmbH, Vol. 28, No. 5-6 ( 1973-6-1), p. 241-246
Abstract:
All possible enantiomers of stereospecifically labelled [1- 2 H] ethanol, propanol and butanol have been prepared on a scale of up to 7 ml. The R forms have been obtained by incubation of the alcohols with alcohol dehydrogenase and diaphorase (NAD: Lipoamide oxidoreductase, EC 1.6.4.3) in presence of catalytic amounts of NAD + /NADH in deuterium oxide. The S forms have been prepared with the same enzymes in ordinary water, from the corresponding [1,1- 2 H] alcohols. (IS) [1- 2 H] ethanol was prepared from [1,1- 2 H] ethanol and ordinary water, by a yeast catalyzed exchange reaction.
Type of Medium:
Online Resource
ISSN:
1865-7125
,
0939-5075
DOI:
10.1515/znc-1973-5-603
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
1973
detail.hit.zdb_id:
2078107-6
SSG:
12
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