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  • 1
    Online Resource
    Online Resource
    AIP Publishing ; 1954
    In:  The Journal of Chemical Physics Vol. 22, No. 5 ( 1954-05-01), p. 900-903
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 22, No. 5 ( 1954-05-01), p. 900-903
    Abstract: An investigation of the infrared spectrum of S16O18O results in the following frequency assignment: ν1=1122±1 cm−1,  ν2=506.8±0.5 cm−1,  ν3=1341±0.5 cm−1. These data combined with the fundamental frequencies of S16O2 have been used to calculate the potential constants for sulfur dioxide. These are fd=10.02,  fdd=0.03,  1dfdα=0.20,  1d2fα=0.793.
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    Language: English
    Publisher: AIP Publishing
    Publication Date: 1954
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
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  • 2
    Online Resource
    Online Resource
    AIP Publishing ; 2012
    In:  Journal of Applied Physics Vol. 111, No. 7 ( 2012-04-01)
    In: Journal of Applied Physics, AIP Publishing, Vol. 111, No. 7 ( 2012-04-01)
    Abstract: The induction heating effects in amorphous and nanocrystalline wires, Fe73.5-xCrxSi13.5Cu1B9Nb3 (x = 3, 7, and 10), are analyzed in this work. In these alloys, the Curie temperature of the amorphous phase, TC, can be tailored through the Cr content of the alloy or the volume crystalline fraction after nanocrystallization. Four samples were selected; amorphous with x = 0 and 10 and nanocrystalline x = 7 with different crystalline fractions. The Curie temperature of the residual amorphous phase, TCa, was experimentally determined by the temperature dependence of the self-inductance of the samples. The analysis of the frequency dependence of the complex magnetic susceptibility enabled the estimation of the magnetic power losses in the samples. The heating effects on the wires were analyzed under the application of an ac magnetic field employing a home-made hyperthermia set-up. A single piece of a wire was immersed in a water bath (initial temperature from 291 K to 325 K) and subjected to the ac magnetic field. The specific absorption rate (SAR) was estimated through the initial slope of the temperature increase as a function of time. Maximum SAR values were obtained in the amorphous sample (x = 3) with the highest TC and enhanced magnetic power losses. In the nanocrystalline samples (x = 7), the detected heating effects above TCa are interpreted as a consequence of the magnetization process of the ferromagnetic grains. However, in spite of the low SAR displayed by the amorphous wire with TC ≈ 300 K (x = 10), interesting self-regulated characteristics are observed in this sample.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2012
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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  • 3
    Online Resource
    Online Resource
    AIP Publishing ; 2010
    In:  Journal of Applied Physics Vol. 107, No. 12 ( 2010-06-15)
    In: Journal of Applied Physics, AIP Publishing, Vol. 107, No. 12 ( 2010-06-15)
    Abstract: Ni–Mn–Ga ferromagnetic shape memory wires (Ni2.10Mn0.98Ga0.92, mean diameter 170 μm) are obtained by the rotating water bath melt spinning technique. The compositional heterogeneity linked to its dendritelike structure gives rise to a complex and broad martensitic transformation (MT). The reduced value of magnetization in the as-spun sample is ascribed to Mn–Mn antiferromagnetic interactions at structural defects as atomic disorder, vacancies, and antiphase boundaries structures. Moreover, the observed low temperature magnetic relaxation process is characterized by a splitting in the zero-field-cooled/field-cooled magnetization curves and the frequency shift in the ac magnetic susceptibility. The results are interpreted in terms of the coexistence of a reduced magnetization state and nearly noninteracting magnetic clusters. A high temperature treatment optimizes both the MT and the magnetic characteristics (i.e., decrease in the hysteresis of the MT and magnetization recovery, respectively).
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2010
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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  • 4
    Online Resource
    Online Resource
    AIP Publishing ; 2010
    In:  Review of Scientific Instruments Vol. 81, No. 5 ( 2010-05-01)
    In: Review of Scientific Instruments, AIP Publishing, Vol. 81, No. 5 ( 2010-05-01)
    Abstract: A low-cost, automated apparatus has been used to perform micrometric deposition of small pendant drops onto a quiet liquid surface. The approach of the drop to the surface is obtained by means of discrete, micron-scale translations in order to achieve deposition at adiabatically zero velocity. This process is not only widely used in scientific investigations in fluid mechanics and thermal sciences but also in engineering and biomedical applications. The apparatus has been designed to produce accurate deposition onto the surface and minimize the vibrations induced in the drop by the movement of the capillary tip. Calibration tests of the apparatus have shown that a descent of the drop by discrete translational steps of ∼5.6 μm and duration of 150–200 ms is sufficient to minimize its penetration depth into the liquid when it touches the surface layer and reduce to a level of noise the vibrations transmitted to it by the translation of the dispenser. Different settings of the experimental setup can be easily implemented for use in a variety of other applications, including deposition onto solid surfaces, surface tension measurements of pendant drops, and wire bonding in microelectronics.
    Type of Medium: Online Resource
    ISSN: 0034-6748 , 1089-7623
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2010
    detail.hit.zdb_id: 209865-9
    detail.hit.zdb_id: 1472905-2
    SSG: 11
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  • 5
    Online Resource
    Online Resource
    AIP Publishing ; 2013
    In:  Journal of Applied Physics Vol. 113, No. 17 ( 2013-05-07)
    In: Journal of Applied Physics, AIP Publishing, Vol. 113, No. 17 ( 2013-05-07)
    Abstract: Room-temperature ferromagnetism in non-magnetic doped TiO2 semiconductor nanoparticles is analyzed in the present work. Undoped and N-doped TiO2 nanoparticles were obtained employing sol-gel procedure using urea as the nitrogen source. The obtained gels were first dried at 70 °C and afterwards calcined in air at 300 °C. A residual carbon concentration was retained in the samples as a consequence of the organic decomposition process. Post-annealing treatments at 300 °C under air and vacuum conditions were also performed. The crystallographic structure of nanoparticles was analyzed by X-ray diffraction, obtaining a single anatase crystalline phase after the calcinations (mean nanoparticle diameters around 5–8 nm). SQUID magnetometry was employed to analyze the magnetic response of the samples. Whereas for the undoped samples synthesized with hydrolysis rate h = 6, paramagnetic like behavior is observed at room temperature, the N-doped nanoparticles (h = 3) show a weak ferromagnetic response (saturation magnetization ≈10−3 emu/g). Moreover, a clear reinforcement of the room-temperature ferromagnetism response is found with the post-annealing treatments, in particular that performed in vacuum. Thus, the results indicate the dominant role of the oxygen stoichiometry and the oxygen vacancies in the room temperature ferromagnetic response of these TiO2 nanoparticles.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2013
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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  • 6
    Online Resource
    Online Resource
    AIP Publishing ; 1953
    In:  The Journal of Chemical Physics Vol. 21, No. 8 ( 1953-08-01), p. 1426-1426
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 21, No. 8 ( 1953-08-01), p. 1426-1426
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    Language: English
    Publisher: AIP Publishing
    Publication Date: 1953
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
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  • 7
    Online Resource
    Online Resource
    AIP Publishing ; 2019
    In:  Journal of Applied Physics Vol. 125, No. 18 ( 2019-05-14)
    In: Journal of Applied Physics, AIP Publishing, Vol. 125, No. 18 ( 2019-05-14)
    Abstract: The analysis of the thermoluminiscence (TL) kinetics parameters of SOL-GEL α-Al2O3 with several different concentrations of impurities prepared through the solgel process is reported. A TL glow curve measured at 0.2 K/s after beta irradiation to 0.5 Gy revealed one peak at approximately 447 K. TL spectra were acquired and showed luminescent emission bands around 420 nm and 750 nm. The activation energies, the frequency factors, and the kinetic order involved in the TL emission were evaluated using the maximum peak temperature response, the peak shape of the TL glow curve, the TL glow curve area, and the glow curve fitting methods. The order of kinetics of the peak was evaluated as first order using TM dependence on the radiation dose. The (TM–Tstop) technique was used for determining the number of peaks in the glow curve. The activation energies obtained are in agreement with all the applied methods. The activation energy calculated by various methods varied from 0.885 ± 0.008 eV to 1.05 ± 0.10 eV. The frequency factor determined by all methods was of the order of 109 s−1. The dosimetric peak is affected by thermal quenching. The following thermal quenching parameters were estimated: the activation energy of the thermal quenching W = 1.05 ± 0.15 eV and the constant C = 8.27 × 1010 s−1. The trapping parameters of SOL-GEL α-Al2O3 detectors are reported in the present work for the first time.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2019
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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  • 8
    Online Resource
    Online Resource
    AIP Publishing ; 1995
    In:  Applied Physics Letters Vol. 67, No. 4 ( 1995-07-24), p. 485-487
    In: Applied Physics Letters, AIP Publishing, Vol. 67, No. 4 ( 1995-07-24), p. 485-487
    Abstract: Diamond crystals of 1 μm mean size were grown on (100) silicon substrates by ArF (193 nm) laser ablation of graphite in a hydrogen atmosphere with a laser power density of 1.3×108 W/cm2 at relatively low substrate temperature (450 °C). Raman spectroscopy analysis confirmed the diamond cubic structure of the crystals by the presence of a sharp peak at 1332 cm−1. When a KrF (248 nm) laser was used instead of the ArF no diamond phases were detected in the deposited films and the Raman spectra showed only the two bands centered at 1340 and 1600 cm−1 characteristic of amorphous carbon. The results demonstrated that the laser wavelength is a determinant parameter in the growth of diamond by laser ablation of graphite.
    Type of Medium: Online Resource
    ISSN: 0003-6951 , 1077-3118
    RVK:
    Language: English
    Publisher: AIP Publishing
    Publication Date: 1995
    detail.hit.zdb_id: 211245-0
    detail.hit.zdb_id: 1469436-0
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  • 9
    Online Resource
    Online Resource
    AIP Publishing ; 2021
    In:  The Journal of Chemical Physics Vol. 154, No. 11 ( 2021-03-21)
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 154, No. 11 ( 2021-03-21)
    Abstract: Spatio-temporal oscillations can be induced under batch conditions with ubiquitous bimolecular reactions in the absence of any nonlinear chemical feedback, thanks to an active interplay between the chemical process and chemically driven hydrodynamic flows. When two reactants A and B, initially separated in space, react upon diffusive contact, they can power convective flows by inducing a localized variation of surface tension and density at the mixing interface. These flows feedback with the reaction-diffusion dynamics, bearing damped or sustained spatio-temporal oscillations of the concentrations and flow field. By means of numerical simulations, we detail the mechanism underlying these chemohydrodynamic oscillations and classify the main dynamical scenarios in the relevant space drawn by parameters ΔM and ΔR, which rule the surface tension- and buoyancy-driven contributions to convection, respectively. The reactor height is found to play a critical role in the control of the dynamics. The analysis reveals the intimate nature of these oscillatory phenomena and the hierarchy among the different phenomena at play: oscillations are essentially hydrodynamic and the chemical process features the localized trigger for Marangoni flows unstable toward oscillatory instabilities. The characteristic size of Marangoni convective rolls mainly determines the critical conditions and properties of the oscillations, which can be further tuned or suppressed by the buoyancy competition. We finally discuss the possible experimental implementation of such a class of chemo-hydrodynamic oscillator and its implications in fundamental and applied terms.
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2021
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
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  • 10
    Online Resource
    Online Resource
    AIP Publishing ; 2006
    In:  Applied Physics Letters Vol. 88, No. 13 ( 2006-03-27)
    In: Applied Physics Letters, AIP Publishing, Vol. 88, No. 13 ( 2006-03-27)
    Abstract: The magnetic entropy change in three different polycrystalline Ni53+xFe20−xGa27 (x=0.5,1,2) alloys was analyzed as a function of temperature under different applied magnetic fields. The temperature dependence of the ac magnetic susceptibility (χ) and the magnetization of the alloys have been used to characterize the different structural and magnetic transformations. In spite of the different magnetic states, the alloys show comparable magnetic entropy values. For x⩽1 the martensitic transformation takes place in the ferromagnetic state for measuring temperatures below room temperature, whereas the alloy with x=2 displays the martensitic transformation above room temperature between two paramagnetic phases. Maximum values of the magnetic entropy change are correlated with the martensitic transformation, irrespective of the particular magnetic state (ferromagnetic or paramagnetic) during the transformation.
    Type of Medium: Online Resource
    ISSN: 0003-6951 , 1077-3118
    RVK:
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2006
    detail.hit.zdb_id: 211245-0
    detail.hit.zdb_id: 1469436-0
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