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  • Online Resource  (5)
  • MDPI AG  (5)
  • 1
    Online Resource
    Online Resource
    MDPI AG ; 2018
    In:  Sustainability Vol. 10, No. 5 ( 2018-05-08), p. 1482-
    In: Sustainability, MDPI AG, Vol. 10, No. 5 ( 2018-05-08), p. 1482-
    Type of Medium: Online Resource
    ISSN: 2071-1050
    Language: English
    Publisher: MDPI AG
    Publication Date: 2018
    detail.hit.zdb_id: 2518383-7
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  • 2
    Online Resource
    Online Resource
    MDPI AG ; 2021
    In:  Sustainability Vol. 13, No. 7 ( 2021-03-31), p. 3872-
    In: Sustainability, MDPI AG, Vol. 13, No. 7 ( 2021-03-31), p. 3872-
    Abstract: The Baltic Sea is considered the marine water body most severely affected by eutrophication within Europe. Due to its limited water exchange nutrients have a particularly long residence time in the sea. While several studies have analysed the costs of reducing current nutrient emissions, the costs for remediating legacy nutrient loads of past emissions remain unknown. Although the Baltic Sea is a comparatively well-monitored region, current data and knowledge is insufficient to provide a sound quantification of legacy nutrient loads and much less their abatement costs. A first rough estimation of agricultural legacy nutrient loads yields an accumulation of 0.5–4.0 Mt N and 0.3–1.2 Mt P in the Baltic Sea and 0.4–0.5 Mt P in agricultural soils within the catchment. The costs for removing or immobilising this amount of nutrients via deep water oxygenation, mussel farming and soil gypsum amendment are in the range of few tens to over 100 billion €. These preliminary results are meant as a basis for future studies and show that while requiring serious commitment to funding and implementation, remediating agricultural legacy loads is not infeasible and may even provide economic benefits to local communities in the long run.
    Type of Medium: Online Resource
    ISSN: 2071-1050
    Language: English
    Publisher: MDPI AG
    Publication Date: 2021
    detail.hit.zdb_id: 2518383-7
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  • 3
    Online Resource
    Online Resource
    MDPI AG ; 2020
    In:  Minerals Vol. 10, No. 11 ( 2020-10-22), p. 937-
    In: Minerals, MDPI AG, Vol. 10, No. 11 ( 2020-10-22), p. 937-
    Abstract: Low-grade phosphate rock from Sra Ouertane (Tunisia) was beneficiated using a thermal treatment consisting of calcination, quenching, and disliming. Untreated phosphate rock samples (group 1), calcined phosphate rock samples (group 2), as well as calcined, quenched, and dislimed (group 3) phosphate rock samples, were investigated using inductively-coupled plasma atomic emission spectroscopy (ICP-AES), inductively-coupled plasma mass spectrometry (ICP-MS), thermogravimetric analysis (TGA), and X-ray powder diffraction (XRD). Besides, the particle size distribution of the aforementioned three groups was determined. The proposed thermal treatment successfully increased the P2O5 content of the untreated phosphate rock from 20.01 wt% (group 1) to 24.24 wt% (group 2) after calcination and, finally, 27.24 wt% (group 3) after calcination, quenching, and disliming. It was further found that the concentration of relevant accompanying rare earth elements (Ce, La, Nd, Pr, Sm, and Y) was increased and that the concentration of Cd could be significantly reduced from 30 mg/kg to 14 mg/kg with the proposed treatment. The resulting phosphate concentrate showed relatively high concentrations in metal oxides: Ʃ MgO, Fe2O3, Al2O3 = 3.63 wt% and silica (9.81 wt%) so that it did not meet the merchant grade specifications of a minimum P2O5 content of 30 wt% yet. Removal of these elements could be achieved using additional appropriate separation techniques.
    Type of Medium: Online Resource
    ISSN: 2075-163X
    Language: English
    Publisher: MDPI AG
    Publication Date: 2020
    detail.hit.zdb_id: 2655947-X
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  • 4
    Online Resource
    Online Resource
    MDPI AG ; 2018
    In:  Minerals Vol. 8, No. 9 ( 2018-09-08), p. 395-
    In: Minerals, MDPI AG, Vol. 8, No. 9 ( 2018-09-08), p. 395-
    Abstract: As an element, phosphorus (P) is one of a kind. While it is essential for all life on Earth, phosphorus is neither substitutable nor infinite especially in terms of highly concentrated phosphate rock deposits. Society as a whole—and key stakeholders in particular—must build on and extend the idea of a linear system that begins with exploration, continues with extraction and processing, and ends with the application of fertilizers, by applying mechanisms of circularity. The efficient and sustainable utilization of P including intra-generational and intergenerational fairness requires the recognition of its dissipative structure as an important first step. With its Manifesto for a Resource-Efficient Europe, the European Commission acknowledged the inevitability of the transition toward a regenerative Circular Economy (CE). The concept of a CE evolves around the avoidance of losses, which can be found all along the P supply chain in varying degrees of magnitude and leads to total nutrient-use efficiencies as low as 5% to 10%. This makes P a prime target for moving toward a circular economy. While common state-of-the-art work addresses mostly the loop (i.e., production, use, collection, and recycling) itself, we are discussing the current role of raw materials “feeding” the loop with respect to the mining phase. From a resilience perspective, the aim must be to keep every P atom flowing and circulating within our economy for as long as possible. Hereby, every measure needs to be considered under the principle of proportionality in terms of sustainable development. Therefore, changes to the current approach in the form of multidimensional innovation (e.g., products, processes, and structures) must be considered from various perspectives including technological, geological, and economic aspects. The economic framework conditions, in particular, determine the cut-off between valuable product and “waste”. We build our arguments on the “Phosphate Rock Mining–Innovation Nexus” and illustrate potential best-practice examples.
    Type of Medium: Online Resource
    ISSN: 2075-163X
    Language: English
    Publisher: MDPI AG
    Publication Date: 2018
    detail.hit.zdb_id: 2655947-X
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  • 5
    In: Sustainability, MDPI AG, Vol. 12, No. 6 ( 2020-03-24), p. 2567-
    Abstract: Despite the significant reduction of phosphorus (P) discharge in the Baltic Sea in the last decades, obtained through the implementation of some approaches within the Helsinki Convention, eutrophication is still considered the biggest problem for the Baltic Sea environment. Consequently, the reduction of P load is an urgent need to solve, but the complexity of both the environmental and legislative context of the area makes this process difficult (more than in the past). Eutrophication is an intricate issue requiring a proper framework of governance that is not easy to determine in the Baltic Sea Region where the needs of several different countries converge. To identify the most suitable strategy to reduce the eutrophication in the Baltic Sea, the InPhos project (no. 17022, 2018–2019, funded by the European Institute of Innovation & Technology (EIT) Raw Materials) adopted a holistic approach considering technical, political, economic, environmental and social aspects of P management. With the aims to raise awareness about the P challenge, foster the dialogue among all the stakeholders, and find solutions already developed in other countries (such as Germany and Switzerland) to be transferred in the Baltic Sea Region, the InPhos project consortium applied the methodology proposed in this paper, consisting of three main phases: (i) analysis of the available technologies to remove P from waste streams that contribute to eutrophication; (ii) analysis of the main streams involving P in Baltic Sea countries to highlight the potential of more sustainable and circular P management; (iii) study of the current context (e.g., already-existing initiatives and issues). This approach allowed us to identify four categories of recommendations and practical actions proposed to improve P management in the Baltic Sea region. During the project, the consortium mainly addressed social aspects. Following steps beyond the project will be more quantitative to determine the techno-economic feasibility of circular P management in selected demo cases in the region.
    Type of Medium: Online Resource
    ISSN: 2071-1050
    Language: English
    Publisher: MDPI AG
    Publication Date: 2020
    detail.hit.zdb_id: 2518383-7
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