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  • Gruen, D. M.  (18)
  • 2000-2004  (18)
  • 1
    In: Surface and Interface Analysis, Wiley, Vol. 36, No. 5-6 ( 2004-05), p. 449-454
    Abstract: This work reports on electronic properties of nitrogen‐doped, n‐type ultrananocrystalline diamond (UNCD) films grown on p‐type Si substrates from CH 4 –Ar–N 2 gas mixtures using a microwave plasma chemical vapor deposition technique. Films ∼1 µm thick were grown with 5%N 2 and 10%N 2 in the plasmas. Charge‐based deep‐level transient spectroscopy showed a shallow level of point defects with an activation energy of ∼0.05 eV. The density of these shallow defects was increased with increasing nitrogen content in the plasma. Complex scanning probe microscopy methods were applied to study the film microstructure. Generally it was found that the nitrogen‐doped UNCD films showed a periodic ‘cell‐like’ structure in which the cell with a lateral size of several nanometers was less conducting than the boundary between the cells. The boundary width was found to be 0.5–1 nm. The observed details of the periodic structure can be associated with diamond nanocrystallites (grains) and grain boundaries, respectively. In addition, 2–5 nm high‐conducting inclusions clustered on the film surface were observed. It was noted that the emission field was inversely proportional to the film electroconductivity, and the lowest emission field of F ∼ 10 V µm −1 was detected near the high‐conducting inclusions. Moreover, the surface electron potential at the emission sites was lowered. The reasons why the shallow donor center is predominantly introduced by nitrogen incorporated into the grain boundaries and the possible mechanisms of low‐field electron emission from the nitrogen‐doped UNCD films have been discussed. Copyright © 2004 John Wiley & Sons, Ltd.
    Type of Medium: Online Resource
    ISSN: 0142-2421 , 1096-9918
    URL: Issue
    RVK:
    Language: English
    Publisher: Wiley
    Publication Date: 2004
    detail.hit.zdb_id: 2023881-2
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  • 2
    Online Resource
    Online Resource
    American Vacuum Society ; 2000
    In:  Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena Vol. 18, No. 5 ( 2000-09-01), p. 2427-2432
    In: Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena, American Vacuum Society, Vol. 18, No. 5 ( 2000-09-01), p. 2427-2432
    Abstract: Vertical edge emitter arrays of thin walled (500–8000 Å) hollow cylinders have been fabricated by the deposition of Cu–20 at. % Li alloy (Cu4Li) thin films on arrays of Si posts, followed by selective etching of the Si core. What remains is a hollow cylinder of Cu4Li, where the thickness of the emitting edge is determined by the deposited film thickness. Additionally, lateral edge emitters were fabricated from arrays of holes in SiO2 or Si3N4 films on flat Si surfaces. In this case, the emitting edge is formed by selectively overetching the Si beneath the hole, creating an edge from the overhang of the SiO2 (Si3N4) thin film upon which the Cu4Li alloy is deposited. The Cu4Li alloy provides a surface covered with a monolayer of Li atoms formed via Gibbsian segregation. The formation of Li–Cu atom dipoles on the surface of the alloy yields a work function lower than that of either a pure Li or Cu surface, resulting in enhanced electron emission and very low threshold fields. The alloy coating maintains a segregated monolayer of Li atoms on the surface even under adverse operational conditions, including ion bombardment of the surface. Edge emitters offer many potential advantages over the standard microtip arrays including ease of fabrication, higher emission currents per emitter due to the larger emission area of the edge, and greater physical robustness. The Cu4Li edge emitters exhibit threshold fields as low as E0=5 V/μm, high current densities, and long-lived, stable emission.
    Type of Medium: Online Resource
    ISSN: 1071-1023 , 1520-8567
    RVK:
    Language: English
    Publisher: American Vacuum Society
    Publication Date: 2000
    detail.hit.zdb_id: 3117331-7
    detail.hit.zdb_id: 3117333-0
    detail.hit.zdb_id: 1475429-0
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  • 3
    Online Resource
    Online Resource
    AIP Publishing ; 2001
    In:  Journal of Applied Physics Vol. 90, No. 1 ( 2001-07-01), p. 118-122
    In: Journal of Applied Physics, AIP Publishing, Vol. 90, No. 1 ( 2001-07-01), p. 118-122
    Abstract: Ultrananocrystalline diamond (UNCD) films, grown using microwave plasma-enhanced chemical vapor deposition with gas mixtures of Ar–1%CH4 or Ar–1%CH4–5%H2, have been examined with transmission electron microscopy (TEM). The films consist of equiaxed nanograins (2–10 nm in diameter) and elongated twinned dendritic grains. The area occupied by dendritic grains increases with the addition of H2. High resolution electron microscopy shows no evidence of an amorphous phase at grain boundaries, which are typically one or two atomic layer thick (0.2–0.4 nm). Cross-section TEM reveals a noncolumnar structure of the films. The initial nucleation of diamond occurs directly on the Si substrate when H2 is present in the plasma. For the case of UNCD growth from a plasma without addition of H2, the initial nucleation occurs on an amorphous carbon layer about 10–15 nm thick directly grown on the Si substrate. This result indicates that hydrogen plays a critical role in determining the nucleation interface between the UNCD films and the Si substrate. The relation between diamond nuclei and Si is primarily random and occasionally epitaxial.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2001
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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  • 4
    Online Resource
    Online Resource
    AIP Publishing ; 2003
    In:  Journal of Applied Physics Vol. 93, No. 9 ( 2003-05-01), p. 5606-5612
    In: Journal of Applied Physics, AIP Publishing, Vol. 93, No. 9 ( 2003-05-01), p. 5606-5612
    Abstract: The transport properties of diamond thin films are well known to be sensitive to the sp2/sp3-bonded carbon ratio, the presence of the grain boundaries and other defects, and to the presence of various impurities. In order to clarify the roles these factors play in the conduction mechanisms of nitrogen-doped ultrananocrystalline diamond (UNCD), Raman scattering, near edge x-ray absorption fine structure (NEXAFS), soft x-ray fluorescence (SXF), and secondary ion mass spectroscopy (SIMS) measurements were performed. Transmission electron microscopy analysis of nitrogen doped UNCD has previously indicated that the films are composed of crystalline diamond nano-grains with boundaries of amorphous carbon, and NEXAFS measurements reveal that the global amount of sp2-bonded carbon in these films increases slightly with nitrogen doping. The nitrogen content is quantified with high-resolution SIMS analysis, while NEXAFS and SXF indicates that the nitrogen exists primarily in tetrahedrally coordinated sites. These measurements indicate that the overall grain boundary volume of nitrogen-doped ultrananocrystalline diamond is increasing, while the grains themselves remain pure diamond. This supports our previously reported hypothesis that grain boundary conduction is the mechanism for the observed increase in conductivity in ultrananocrystalline diamond with nitrogen doping.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2003
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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  • 5
    In: Journal of Wide Bandgap Materials, SAGE Publications, Vol. 8, No. 3-4 ( 2001-01-01), p. 171-188
    Type of Medium: Online Resource
    ISSN: 1524-511X
    Language: English
    Publisher: SAGE Publications
    Publication Date: 2001
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  • 6
    Online Resource
    Online Resource
    Springer Science and Business Media LLC ; 2003
    In:  Experimental Mechanics Vol. 43, No. 3 ( 2003-9), p. 256-268
    In: Experimental Mechanics, Springer Science and Business Media LLC, Vol. 43, No. 3 ( 2003-9), p. 256-268
    Type of Medium: Online Resource
    ISSN: 0014-4851 , 1741-2765
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2003
    detail.hit.zdb_id: 2080895-1
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  • 7
    Online Resource
    Online Resource
    American Vacuum Society ; 2003
    In:  Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena Vol. 21, No. 4 ( 2003-07-01), p. 1644-1647
    In: Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena, American Vacuum Society, Vol. 21, No. 4 ( 2003-07-01), p. 1644-1647
    Abstract: The effect of O2 exposure on field emission properties of ultrananocrystalline diamond (UNCD) coated ungated Si tip arrays is reported. The behavior of current degradation during O2 exposure and current recovery following evacuation of O2 strongly depended on the initial current/electric field applied to the emitters. At a low initial current of 50 μA/electric field of 5.8 V/μm, O2 exposure (1×10−7, 5×10−7, and 1×10−6 Torr) resulted in a rapid decrease in current in the beginning, followed by a slow decrease. The current made a strong recovery toward the original value when O2 was pumped out. With an increased initial current of 180 μA/electric field of 10.3 V/μm, the currents recovered only to a lesser extent after O2 was evacuated. At an even higher initial current of 930 μA/electric field of 20.5 V/μm, the current decreased steadily and finally stabilized after an exposure of 720 L with only 34% degradation. To explain these observations, we propose a hypothesis of oxygen interaction with the UNCD surface.
    Type of Medium: Online Resource
    ISSN: 1071-1023 , 1520-8567
    RVK:
    Language: English
    Publisher: American Vacuum Society
    Publication Date: 2003
    detail.hit.zdb_id: 3117331-7
    detail.hit.zdb_id: 3117333-0
    detail.hit.zdb_id: 1475429-0
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  • 8
    Online Resource
    Online Resource
    AIP Publishing ; 2003
    In:  Applied Physics Letters Vol. 83, No. 10 ( 2003-09-08), p. 2001-2003
    In: Applied Physics Letters, AIP Publishing, Vol. 83, No. 10 ( 2003-09-08), p. 2001-2003
    Abstract: The contact behavior of various metals on n-type nitrogen-doped ultrananocrystalline diamond (UNCD) thin films has been investigated. The influences of the following parameters on the current–voltage characteristics of the contacts are presented: (1) electronegativity and work function of various metals, (2) an oxidizing acid surface cleaning step, and (3) oxide formation at the film/contact interface. Near-ideal ohmic contacts are formed in every case, while Schottky barrier contacts prove more elusive. These results counter most work discussed to date on thin diamond films, and are discussed in the context of the unique grain-boundary conductivity mechanism of the nitrogen-doped UNCD.
    Type of Medium: Online Resource
    ISSN: 0003-6951 , 1077-3118
    RVK:
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2003
    detail.hit.zdb_id: 211245-0
    detail.hit.zdb_id: 1469436-0
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  • 9
    Online Resource
    Online Resource
    AIP Publishing ; 2001
    In:  Applied Physics Letters Vol. 79, No. 6 ( 2001-08-06), p. 800-802
    In: Applied Physics Letters, AIP Publishing, Vol. 79, No. 6 ( 2001-08-06), p. 800-802
    Abstract: Conducting diffusion barrier layers play a critical role in high-density memory integration. We recently demonstrated that Ti–Al can be used as a diffusion barrier layer for the integration of ferroelectric capacitors with complementary metal–oxide semiconductor devices for the fabrication of nonvolatile ferroelectric random access memories (NVFRAMs). Here, we discuss results from systematic studies designed to understand Ti–Al film growth and oxidation processes using in situ ion beam sputter deposition in conjunction with complementary in situ atomic layer-resolution mass spectroscopy of recoil ion (MSRI) and surface sensitive x-ray photoelectron spectroscopy (XPS). The concurrent MSRI/XPS analysis revealed that amorphous Ti–Al layers produced by tailored sputter-deposition methods are resistant to oxidation to at least 600 °C, and that oxidation occurs only when the a-Ti–Al layers are exposed to oxygen at & gt;600 °C, via the segregation of Ti species to the surface and TiO2 formation. The a-Ti–Al layers discussed in this letter could be used in the double functionality of a bottom electrode/diffusion barrier for the integration of ferroelectric capacitors with Si substrates for the fabrication of NVFRAMs and other devices.
    Type of Medium: Online Resource
    ISSN: 0003-6951 , 1077-3118
    RVK:
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2001
    detail.hit.zdb_id: 211245-0
    detail.hit.zdb_id: 1469436-0
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  • 10
    Online Resource
    Online Resource
    AIP Publishing ; 2003
    In:  Journal of Applied Physics Vol. 94, No. 6 ( 2003-09-15), p. 4079-4083
    In: Journal of Applied Physics, AIP Publishing, Vol. 94, No. 6 ( 2003-09-15), p. 4079-4083
    Abstract: We performed studies of electron emission from ultrananocrystalline diamond (UNCD)-coated, ungated silicon field emitters as a function of in situ exposure to various gases during current versus voltage and current versus time measurements. The emitter arrays were fabricated by a subtractive tip fabrication process and coated with UNCD films using microwave plasma chemical vapor deposition with a CH4/Ar plasma chemistry. The emission characteristics of the coated tip arrays were studied in the diode configuration; using a 2 mm diameter anode with rounded edges to suppress arcing. Significant enhancement of the electron emission was observed, increasing from 35% to 100%, after the emitting surface was exposed to H2 at pressures in the 10−5 and 10−4 Torr range. Upon termination of the H2 exposure, the current decreased to the initial value of 2 μA. The emission current subsequently remained stable at 2 μA upon continued evacuation down to the base pressure below 10−9 Torr. The emission current variation is repeatable with ensuing hydrogen exposure, indicating that the enhancement is due to the hydrogen exposure. Negligible emission current variations are observed at pressures less than 10−5 Torr. Exposure to either Ar or N2 resulted in a reduction of the emission current for ambients of up to 10−5 Torr. This effect is reversible. The effect of the investigated gases on the emission characteristics of UNCD-coated Si tip arrays is attributed to a modification of the effective work function at the localized sites from where electrons are being emitted.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2003
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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