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  • Mineralogical Society  (13)
  • Earth Sciences  (13)
  • 1
    Online Resource
    Online Resource
    Mineralogical Society ; 1976
    In:  Mineralogical Magazine Vol. 40, No. 313 ( 1976-03), p. 523-524
    In: Mineralogical Magazine, Mineralogical Society, Vol. 40, No. 313 ( 1976-03), p. 523-524
    Type of Medium: Online Resource
    ISSN: 0026-461X , 1471-8022
    RVK:
    Language: English
    Publisher: Mineralogical Society
    Publication Date: 1976
    detail.hit.zdb_id: 2034522-7
    SSG: 13
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  • 2
    Online Resource
    Online Resource
    Mineralogical Society ; 2020
    In:  Mineralogical Magazine Vol. 84, No. 1 ( 2020-02), p. 65-80
    In: Mineralogical Magazine, Mineralogical Society, Vol. 84, No. 1 ( 2020-02), p. 65-80
    Abstract: The Huanglongpu carbonatites are located in the north-western part of the Qinling orogenic belt in central China. Calcite carbonatite dykes at the Dashigou open pit are unusual due to their enrichment in heavy rare earth elements ( HREE ) relative to light rare earth elements ( LREE ), leading to a flat REE pattern, and in that the majority of dykes have a quartz core. They also host economic concentrations of molybdenite. The calcite carbonatite dykes show two styles of mineralogy according to the degree of hydrothermal reworking, and these are reflected in REE distribution and concentration. The REE in the little-altered calcite carbonatite occur mostly in magmatic REE minerals, mainly monazite-(Ce), and typically have Σ LREE /( HREE +Y) ratios from 9.9 to 17. In hydrothermally altered calcite carbonatites, magmatic monazite-(Ce) is partially replaced to fully replaced by HREE -enriched secondary phases and the rocks have Σ LREE /( HREE +Y) ratios from 1.1 to 3.8. The fluid responsible for hydrothermal REE redistribution is preserved in fluid inclusions in the quartz lenses. The bulk of the quartz lacks fluid inclusions but is cut by two later hydrothermal quartz generations, both containing sulfate-rich fluid inclusions with sulfate typically present as multiple trapped solids, as well as in solution. The estimated total sulfate content of fluid inclusions ranges from 6 to 〉 33 wt.% K 2 SO 4 equivalent. We interpret these heterogeneous fluid inclusions to be the result of reaction of sulfate-rich fluids with the calcite carbonatite dykes. The final HREE enrichment is due to a combination of factors: (1) the progressive HREE enrichment of later magmatic calcite created a HREE -enriched source; (2) REE –SO 4 2– complexing allowed the REE to be redistributed without fractionation; and (3) secondary REE mineralisation was dominated by minerals such as HREE -enriched fluorocarbonates, xenotime-(Y) and churchite-(Y) whose crystal structures tends to favour HREE .
    Type of Medium: Online Resource
    ISSN: 0026-461X , 1471-8022
    RVK:
    Language: English
    Publisher: Mineralogical Society
    Publication Date: 2020
    detail.hit.zdb_id: 2034522-7
    SSG: 13
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  • 3
    Online Resource
    Online Resource
    Mineralogical Society ; 1996
    In:  Mineralogical Magazine Vol. 60, No. 398 ( 1996-02), p. 5-40
    In: Mineralogical Magazine, Mineralogical Society, Vol. 60, No. 398 ( 1996-02), p. 5-40
    Abstract: From G. F. Becker's and L. V. Pirsson's early enunciations linking the dynamics of magma chambers to the rock records of sills and plutons to this day, two features stand at the centre of nearly every magmatic process: solidification fronts and phenocrysts. The structure and behaviour of the envisioned solidification front, however, has been mostly that akin to non-silicate, non-multiply-saturated systems, which has led to confusion in appreciating its role in magmatic evolution. The common habit of intruding magmas to carry significant amounts of phenocrysts, which can lead to efficient fractionation, layering, and interstitial melt flow within extensive mush piles, when coupled with solidification fronts, allows a broad understanding of the processes leading to the rock records of sills and lava lakes. These same processes are fundamental to understanding all magmas. The spatial manifestation of the liquidus and solidus is the Solidification Front (SF); all magmas, stationary or in transit, are encased by SFs. In the ideal case of an initially crystal-free, cooling magma, crystallinity increases from nucleation on the leading liquidus edge to a holocrystalline rock at the trailing solidus. The package of SF isotherms advances inward, thickening with time and, depending on location — roof, floor, or walls — and the initial crystallinity of the magma, is instrumental in controlling magmatic evolution. Bimodal volcanism as well as much of the structure of the oceanic crust may arise from the behaviour of SFs. In mafic magmas, somewhere near a crystallinity (N) of 55% (vol), depending on the phase assemblage, the SF changes from a viscous fluid (suspension (0 〈 N 〈 25) and mush (25 〈 N 〈 55%)) to an elastic crystalline network (rigid crust (55 〈 N 〈 100%)) of some strength containing interstitial residual melt. With thickening of the roofward SF of some mafic magmas, the weight of the leading, viscous portion repeatedly tears the crust near N ∼ 55–60%, efficiently segregating the local residual melt into zones of interdigitating silicic lenses. This is SF instability (SFI), a process of possible importance in continental crust initiation and evolution, in producing silicic segregations in oceanic crust, and in recording the inability of the viscous part of the upper SF ever to detach wholly in typical ( 〈 ∼ 1 km) sheet-like magmas. These granophyric and pegmatitic segregations, individually reaching 1–2 m in thickness and 30–50 m in length, form thick (∼ 50–75 m) zones that can be misconstrued as sandwich horizons where the last liquids might have accumulated. In effectively splitting the magma chemically and spatially, SFI is, in essence, a form of chaos (i.e. silicic chaos). Differentiation of initially crystal-free, stationary magmas is limited to processes occurring within SFs, which operate in competition with the rate of inward advancement of solidification. Local processes operating on characteristic time scales longer than the time for the SF to advance a distance equal to its own thickness are suppressed. Enormous increases in viscosity outward within the viscous, leading portion of the SF efficiently partition the distribution of melt accessible to eruption. Eruptible melts lie essentially inward of the SF and are thus severely restricted in silica enrichment. The silica-enriched SFI melts are thus generally inaccessible to collection and eviction unless the host SF is reprocessed or “burned back” through, respectively, later regional magmatism or massive, late-stage re-injection. And because of large viscosity contrasts between SFI melts and host basalts, once freed, SFI melts are literally impossible to homogenize back into the system and may collect and compact against the roof to form large silicic masses. Unusually voluminous, bulbous masses of silicic granophyre present along, and sometimes warping, the roofs of large diabase sills may reflect collections of remobilized blobs of SFI melts. These bulbous masses may be later added to the continental crust through solid state creep. In sheets made of phenocryst-rich, singly saturated magma, most phenocrysts are able through settling or floating to avoid capture by the advancing SFs. Significant differentiation is possible through extensive settling of initial phenocrysts and upward leakage of interstitial residual melt from the associated cumulate pile, which over-thickens the lower SF, greatly tipping the competitive edge against suppression of melt leakage by advancing solidification. Dense interstitial melts may similarly drain from roofward cumulates of light phenocrysts. The variation in crystal size and modal abundance in these cumulate piles are intimate records of prior crystallization, transport, and filling. Magmas in transit erode SFs and thoroughly charge the magma with crystals, facilitating fractionation and differentiation, especially if the body occasionally comes to rest. The key to protracted differentiation through fractional crystallization is not crystallization in stationary, closed chambers, but the repeated transport and chambering of magma or the periodic resupply to chambers of phenocryst-rich magma. This is punctuated differentiation, which may be the general case. Close corollaries are that thick, closed sheets of initially crystal-free, multiply-saturated magma undergo precious little overall differentiation, and that deciphering the sequence and crystallinity, including in transit phenocryst entrainment, growth, and sorting, of the filling events is central to unravelling intrusive history. Variations in temperature, whether on phase diagrams or in actual magmas, are intrinsically linked to commensurate variations in space and time in magmatic systems. The spectrum of all physical and chemical processes associated with magma is accordingly strongly partitioned in space and time. The idea of a magma chamber as a vat of low crystallinity melt crystallizing everywhere within and differentiating through crystal settling is unrealistic. A magma chamber formed of any number of crystal-laden inputs, encased by inward-propagating, dynamic solidification fronts, and where significant differentiation is tied to the dynamics of late-stage, interstitial melt within extensive mush piles is more in accord with the rock record.
    Type of Medium: Online Resource
    ISSN: 0026-461X , 1471-8022
    RVK:
    Language: English
    Publisher: Mineralogical Society
    Publication Date: 1996
    detail.hit.zdb_id: 2034522-7
    SSG: 13
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  • 4
    Online Resource
    Online Resource
    Mineralogical Society ; 1979
    In:  Mineralogical Magazine Vol. 43, No. 325 ( 1979-03), p. 141-148
    In: Mineralogical Magazine, Mineralogical Society, Vol. 43, No. 325 ( 1979-03), p. 141-148
    Abstract: The substitution of 2A1 3+ for Si 4+ + M 2+ ( M = Mg or Ni) has been studied by infra-red spectroscopy in 7 Å trioctahedral minerals over the composition range from Al = 0.00 to Al = 2.00. Significant differences are observed in the infra-red spectra and these make possible an estimation of the amount of Al in tetrahedral coordination. The most striking effect of the substitution is observed in the stretching vibrations of the outer hydroxyl groups and that of the silicate anion. The aluminous Mg-serpentines can be readily distinguished from their analogues, the aluminous Niserpentines, by the absence of the Mg-OH absorption band between 570 and 615 cm −1 in the latter.
    Type of Medium: Online Resource
    ISSN: 0026-461X , 1471-8022
    RVK:
    Language: English
    Publisher: Mineralogical Society
    Publication Date: 1979
    detail.hit.zdb_id: 2034522-7
    SSG: 13
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  • 5
    Online Resource
    Online Resource
    Mineralogical Society ; 1985
    In:  Mineralogical Magazine Vol. 49, No. 350 ( 1985-03), p. 77-79
    In: Mineralogical Magazine, Mineralogical Society, Vol. 49, No. 350 ( 1985-03), p. 77-79
    Abstract: Microprobe analyses of the halogen contents of apatites from two samples of amphibolite-facies schist from Connemara, Ireland, have been used to calculate the fugacity ratios f HCl / f H 2 O and f HF / f H 2 O using the experimental data of Korzhinskiy. The results imply fugacities for both acids in the range 0.03 to 0.1 bars, but whereas for the lower grade rock f HF 〉 f HCl , the migmatitic sample gives f HF ⋍ f HCl . An independent estimate of f HF / f H 2 O from the biotite composition in one sample is in acceptable agreement with the result obtained from apatite.
    Type of Medium: Online Resource
    ISSN: 0026-461X , 1471-8022
    RVK:
    Language: English
    Publisher: Mineralogical Society
    Publication Date: 1985
    detail.hit.zdb_id: 2034522-7
    SSG: 13
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  • 6
    Online Resource
    Online Resource
    Mineralogical Society ; 1973
    In:  Mineralogical Magazine Vol. 39, No. 303 ( 1973-09), p. 297-312
    In: Mineralogical Magazine, Mineralogical Society, Vol. 39, No. 303 ( 1973-09), p. 297-312
    Abstract: Twenty-six compositions in the system MgO-Al 2 O 3 -SiO 2 -H 2 O were investigated under conditions of 1 and 2 Kb water pressure and temperatures between 300 and 700°C. The solid solution for 7 Å and 14 Å chlorites has been delimited as well as that of the expanding phases (tri- and dioctahedral montmorillonites and expanding chlorites). Negative slopes were found for the transformation montmorillonite → expanding chlorite, and expanding chlorite → chlorite+quartz and a positive slope for 7Å → 4 Å transformation. The relative positions of the reactions chlorite+quartz → cordierite+talc, chlorite+andalusite → cordierite and chlorite+corundum → cordierite+spinel are located between 500 and 65°C. Cell dimensions of the synthetic chlorites can be correlated with their chemical composition. Solid solution in synthetic minerals compares well with 325 analysis of natural minerals from the literature, indicating that the chemiographic relations between phases in the simplified synthetic system are applicable to natural mineral assemblages. The phase relations indicate that at low temperature the 7Å aluminous chlorite is not stable with quartz or another silica phase.
    Type of Medium: Online Resource
    ISSN: 0026-461X , 1471-8022
    RVK:
    Language: English
    Publisher: Mineralogical Society
    Publication Date: 1973
    detail.hit.zdb_id: 2034522-7
    SSG: 13
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  • 7
    Online Resource
    Online Resource
    Mineralogical Society ; 2020
    In:  Mineralogical Magazine Vol. 84, No. 1 ( 2020-02), p. 49-64
    In: Mineralogical Magazine, Mineralogical Society, Vol. 84, No. 1 ( 2020-02), p. 49-64
    Abstract: The Cretaceous Okorusu carbonatite, Namibia, includes diopside-bearing and pegmatitic calcite carbonatites, both exhibiting hydrothermally altered mineral assemblages. In unaltered carbonatite, Sr, Ba and rare earth elements ( REE ) are hosted principally by calcite and fluorapatite. However, in hydrothermally altered carbonatites, small ( 〈 50 µm) parisite-(Ce) grains are the dominant REE host, while Ba and Sr are hosted in baryte, celestine, strontianite and witherite. Hydrothermal calcite has a much lower trace-element content than the original, magmatic calcite. Regardless of the low REE contents of the hydrothermal calcite, the REE patterns are similar to those of parisite-(Ce), magmatic minerals and mafic rocks associated with the carbonatites. These similarities suggest that hydrothermal alteration remobilised REE from magmatic minerals, predominantly calcite, without significant fractionation or addition from an external source. Barium and Sr released during alteration were mainly reprecipitated as sulfates. The breakdown of magmatic pyrite into iron hydroxide is inferred to be the main source of sulfate. The behaviour of sulfur suggests that the hydrothermal fluid was somewhat oxidising and it may have been part of a geothermal circulation system. Late hydrothermal massive fluorite replaced the calcite carbonatites at Okorusu and resulted in extensive chemical change, suggesting continued magmatic contributions to the fluid system.
    Type of Medium: Online Resource
    ISSN: 0026-461X , 1471-8022
    RVK:
    Language: English
    Publisher: Mineralogical Society
    Publication Date: 2020
    detail.hit.zdb_id: 2034522-7
    SSG: 13
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  • 8
    Online Resource
    Online Resource
    Mineralogical Society ; 1971
    In:  Mineralogical Magazine Vol. 38, No. 295 ( 1971-09), p. 317-323
    In: Mineralogical Magazine, Mineralogical Society, Vol. 38, No. 295 ( 1971-09), p. 317-323
    Abstract: The upper stability of margarite has been determined to be 450 °C at 1 kb and 530 °C at 2 kb total pressure (P H 2 O = P total ). Other experiments delimit in a general way the lower stability of this mineral and its paragenesis in more SiO 2 rich compositions. The presence of the 060 reflection at 1·475 Å can be used to distinguish between margarite and paragonite or muscovite.
    Type of Medium: Online Resource
    ISSN: 0026-461X , 1471-8022
    RVK:
    Language: English
    Publisher: Mineralogical Society
    Publication Date: 1971
    detail.hit.zdb_id: 2034522-7
    SSG: 13
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  • 9
    Online Resource
    Online Resource
    Mineralogical Society ; 1977
    In:  Mineralogical Magazine Vol. 41, No. 318 ( 1977-06), p. 292-294
    In: Mineralogical Magazine, Mineralogical Society, Vol. 41, No. 318 ( 1977-06), p. 292-294
    Type of Medium: Online Resource
    ISSN: 0026-461X , 1471-8022
    RVK:
    Language: English
    Publisher: Mineralogical Society
    Publication Date: 1977
    detail.hit.zdb_id: 2034522-7
    SSG: 13
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  • 10
    Online Resource
    Online Resource
    Mineralogical Society ; 1981
    In:  Mineralogical Magazine Vol. 44, No. 334 ( 1981-06), p. 125-131
    In: Mineralogical Magazine, Mineralogical Society, Vol. 44, No. 334 ( 1981-06), p. 125-131
    Abstract: Contact metamorphism in the aureole of the Easky adamellite produced andalusite at the expense of regional staurolite, kyanite, and garnet. In the inner aureole sillimanite and K-feldspar also grew. Cordierite is only rarely present. Conditions of metamorphism in the inner aureole have been deduced from five independent criteria as 595 ± 30 °C and 2.5 ± 0.5kb. The nearby Lough Talt adamellite was emplaced at slightly higher pressures. Some aureole rocks have undergone oxidation with conversion of regional garnet to magnetite and andalusite. The reacting assemblage buffered ƒ O 2 near 10 −17 bars. It is inferred that oxidation was caused by movement of H 2 O from the country rocks into the intrusion.
    Type of Medium: Online Resource
    ISSN: 0026-461X , 1471-8022
    RVK:
    Language: English
    Publisher: Mineralogical Society
    Publication Date: 1981
    detail.hit.zdb_id: 2034522-7
    SSG: 13
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