In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2005, No. 20 ( 2005-10), p. 4064-4069
Abstract:
The supramolecular adduct C 60 · 5C 6 H 5 OH was obtained as single crystals by the slow hydrolysis of a solution of C 60 in triphenylphosphite. The crystal structure was determined with atomic resolution by single‐crystal X‐ray diffraction [triclinic, space group P $\tilde {1}$ , a = 1003.52(14) pm, b = 1011.71(14) pm, c = 1264.17(17) pm, α = 88.566(2) °, β = 84.026(2) °, γ = 83.485(2) °, V = 1.2681(3) nm 3 , Z = 1]. The overall structure can be described as a distorted square packing pattern of hydrogen‐bonded and π‐π interacting rods, 1 ∞ [C 60 (C 6 H 5 OH) 4 ]. The fullerene molecules are fully ordered and the C–C bond lengths exhibit remarkably small variations within the 6:6 and 6:5 subsets. The results are discussed in the context of an analysis of reliable crystal structure data for several different fullerene co‐crystal compounds. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2005:20
DOI:
10.1002/ejic.200500256
Language:
English
Publisher:
Wiley
Publication Date:
2005
detail.hit.zdb_id:
1475009-0
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