In:
Chemistry – An Asian Journal, Wiley, Vol. 15, No. 1 ( 2020-01-02), p. 66-71
Abstract:
Two silylene‐spaced (( E )‐vinylsilyl)anthracene‐dipyrromethane dyads have been designed and synthesized by RhCl(PPh 3 ) 3 ‐catalyzed hydrosilylation reactions of 5‐methyl‐5′‐(ethynylaryl)dipyrromethanes with (9‐Anthryl)‐dimethylsilane. The complexation studies of dyads toward different anions have also been performed, which reveal that dyads exhibit a highly selective response towards fluoride anion attributable to both hydrogen‐bonding and pentacoordination phenomena. This dual‐mode fluoride recognition event is unprecedented and may pave the way for future developments in the areas of porphyrinoids, organosilicon, polymer, and supramolecular chemistry.
Type of Medium:
Online Resource
ISSN:
1861-4728
,
1861-471X
DOI:
10.1002/asia.201901424
Language:
English
Publisher:
Wiley
Publication Date:
2020
detail.hit.zdb_id:
2233006-9
Bookmarklink