In:
Advanced Functional Materials, Wiley, Vol. 31, No. 19 ( 2021-05)
Abstract:
Multi‐heteroatoms co‐doped carbon coating can significantly enhance the electronic conductivity and mass transfer rate of the electrode materials due to the synergistic effect. In this study N, S co‐doped carbon coating is introduced on the surface of niobium oxides (GNO@NSC) by using a convenient thiourea evaporation method. Theory calculations and experimental results confirm the synergistic effect of N, S co‐doping in GNO@NSC composite. N, S co‐doping not only enlarges the layer distance of the carbon materials but also leads to more activation sites for lithium storage; meanwhile, the introduction of the co‐doping carbon layer on GNO significantly enhances the bonding interaction with GNO, leading to excellent structural stability and conductivity of the composite. As a result, the GNO@NSC composite possesses excellent structural reversibility, a large specific capacity, and high‐rate performance. GNO@NSC nanowires deliver a highly reversible capacity of 288 mAh g –1 and display excellent cycling stability, and its capacity retention is 78.9% after 6000 cycles at a high current density of 1 A g –1 . This study reveals the functional mechanism of N, S co‐doped carbon coating and the origin of performance improvement of niobium oxides, which can be used for reference to design and develop relevant materials.
Type of Medium:
Online Resource
ISSN:
1616-301X
,
1616-3028
DOI:
10.1002/adfm.202100311
Language:
English
Publisher:
Wiley
Publication Date:
2021
detail.hit.zdb_id:
2029061-5
detail.hit.zdb_id:
2039420-2
SSG:
11
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