In:
Helvetica Chimica Acta, Wiley, Vol. 77, No. 1 ( 1994-02-09), p. 194-202
Abstract:
Various 2‐substituted purine and pyrrolo[2,3‐ d ]pyrimidine 2′‐deoxyribonucleosides with methylthio ( 13a ), chloro ( 13b ), methoxy ( 9b ), and oxo ( 2, 3 ) substituents at C(2) are prepared. They are obtained either via stereoselective nucleobase‐anion glycosylation or by base transformation. A three‐step synthesis of the unknown 2′‐deoxyisoinosine ( 2 ) from 2′‐deoxyguanosine ( 15 ) is described. Compound 2 as well as its 7‐deazapurine derivative 3 exhibit strong fluorescence.
Type of Medium:
Online Resource
ISSN:
0018-019X
,
1522-2675
DOI:
10.1002/hlca.19940770122
Language:
English
Publisher:
Wiley
Publication Date:
1994
detail.hit.zdb_id:
74-7
detail.hit.zdb_id:
1475013-2
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