In:
Acta Crystallographica Section E Structure Reports Online, International Union of Crystallography (IUCr), Vol. 70, No. 7 ( 2014-07-01), p. i36-i37
Abstract:
The title compound, dirubidium dimanganese(II) tris(tetraoxomolybdate), Rb 2 Mn 2 (MoO 4 ) 3 , was prepared by solid-state reactions. The structure can be described as being composed of MnO 6 octahedra sharing corners with MoO 4 tetrahedra. The three-dimensional framework contains cavities in which the rubidium ions are located. The Rb + cations are within distorted nine- and 12-vertex polyhedra. The pairs of different Mn 2+ and Rb + cations are each located on threefold rotation axes.. Rb 2 Mn 2 (MoO 4 ) 3 is isotypic with compounds of the Cs 2 M 2 Mo 3 O 12 ( M = Ni, Fe) family. A comparative structural description is provided between the structure of the title compound and those of related phases. Differences with structures such as alluaudite are discussed.
Type of Medium:
Online Resource
ISSN:
1600-5368
DOI:
10.1107/S1600536814013099
DOI:
10.1107/S1600536814013099/ru2059sup1.cif
DOI:
10.1107/S1600536814013099/ru2059Isup2.hkl
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2014
detail.hit.zdb_id:
2843762-7
detail.hit.zdb_id:
2041947-8
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