In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 33, No. 12 ( 1978-12-1), p. 1561-1562
Abstract:
Unlike chlorination fluorination of ammine complexes of platinum(IV) in aqueous solution does not lead to haloamido complexes. Instead, the triammine complexes [Pt(NH 3 ) 3 Cl 3 ]Cl and [Pt(NH 3 ) 3 (NCl 2 ) 2 Cl]Cl yield no definite main product, and the tetrammine and pentammine complexes trans-[Pt(NH 3 ) 4 Cl 2 ]Cl 2 , [Pt(NH 3 ) 4 (NCl 2 )Cl]Cl 2 , [Pt(NH 3 ) 5 Cl]Cl 3 , and [Pt(NH 3 ) 5 (OH)]Cl 3 form the sparingly soluble complex trans -[Pt (NH 3 ) 4 Cl 2 ](H 2 F 3 ) 2 · 2H 2 O as the main product.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-1978-1241
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
1978
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
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