In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 354, No. 3-4 ( 1967-10), p. 184-191
Abstract:
V(CO) 6 disproportionates in pure liquid NH 3 between −30 and +20°C to [V(NH 3 ) 6 ] [V(CO) 6 ] 2 , whereas in the presence of KCN or NH 4 Cl analogously K 4 [V(CN) 6 ] and K[V(CO) 6 ] or [V(NH 3 ) 6 ]Cl 2 and NH 4 [V(CO) 6 ] are formed. The eliminated CO is partially evolved in the gaseous state, and partially reducing the unreacted starting carbonyl to hexacarbonylvanadate (‐I), NH 4 [V(CO) 6 ], under formation of urea. The reactions are quantitatively investigated and the products characterized by analytical and IR methods.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.v354:3/4
DOI:
10.1002/zaac.19673540308
Language:
English
Publisher:
Wiley
Publication Date:
1967
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
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