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  • American Vacuum Society  (15)
  • 1
    Online Resource
    Online Resource
    American Vacuum Society ; 1987
    In:  Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films Vol. 5, No. 4 ( 1987-07-01), p. 2763-2767
    In: Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, American Vacuum Society, Vol. 5, No. 4 ( 1987-07-01), p. 2763-2767
    Abstract: VBe12 compound and porous titanium composites infiltrated with a lithium bearing copper alloy have been investigated as a means of reducing fusion plasma impurities and sputter erosion associated with fusion tokamak limiter and divertor surfaces. These materials possess high-temperature strength and melt-layer stability properties in conjunction with the self-sustainment of a low-Z overlayer that inhibits erosion of the underlying structural substrate. The sputter erosion and redeposition properties of these materials have been analyzed by calculating the sputtering coefficients via TRIM, which are subsequently used in the REDEP code to evaluate their performance for various plasma-edge temperature regimes. The results have been compared to elemental beryllium, tungsten, and graphite on the basis of minimizing plasma impurities and material erosion, suppressing runaway self-sputtering, and/or enhancing thermal properties.
    Type of Medium: Online Resource
    ISSN: 0734-2101 , 1520-8559
    RVK:
    Language: English
    Publisher: American Vacuum Society
    Publication Date: 1987
    detail.hit.zdb_id: 1475424-1
    detail.hit.zdb_id: 797704-9
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  • 2
    Online Resource
    Online Resource
    American Vacuum Society ; 1986
    In:  Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films Vol. 4, No. 3 ( 1986-05-01), p. 1227-1231
    In: Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, American Vacuum Society, Vol. 4, No. 3 ( 1986-05-01), p. 1227-1231
    Abstract: We discuss the use of composite materials based on the use of self-sustaining coatings to reduce sputtering-induced erosion in magnetic confinement fusion devices while providing enhanced high-heat flux properties. One material, a copper–lithium alloy has been described previously. A second group of materials consists of porous tungsten, tungsten carbide, or tantalum, impregnated with an alkali metal alumino-silicate. These materials form an alkali metal overlayer similar to that found on the Cu–Li alloy. A third group of materials is obtained by infiltrating the porous high-Z refractory metal with an alkali-metal-bearing alloy such as Cu–Li or Al–Li. These materials combine the high thermal conductivity of the infiltrate material with the high-temperature strength and melt layer stability of tungsten or tantalum. Calculations of the sputtering properties indicate that it may be possible to use a tungsten composite limiter at plasma edge temperature up to ∼300 eV.
    Type of Medium: Online Resource
    ISSN: 0734-2101 , 1520-8559
    RVK:
    Language: English
    Publisher: American Vacuum Society
    Publication Date: 1986
    detail.hit.zdb_id: 1475424-1
    detail.hit.zdb_id: 797704-9
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  • 3
    Online Resource
    Online Resource
    American Vacuum Society ; 1994
    In:  Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films Vol. 12, No. 4 ( 1994-07-01), p. 1943-1951
    In: Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, American Vacuum Society, Vol. 12, No. 4 ( 1994-07-01), p. 1943-1951
    Abstract: Low-energy (5–15 keV) pulsed ion beam surface analysis comprises several different surface spectroscopies which possess the ability to provide a remarkably wide range of information directly relevant to the growth of single and multicomponent semiconductor, metal and metal-oxide thin films and layered structures. Ion beam methods have not however, been widely used as anin situ monitor of thin film growth because existing commercial instrumentation causes excessive film damage, physically conflicts with the deposition equipment, and requires a chamber pressure ∼10−7–10−8 Torr, i.e., much lower than that associated with most deposition processes (≥10−4 Torr). We have developed time-of-flight ion scattering and recoil spectroscopy (TOF-SARS) as a nondestructive, insitu, real-time probe of thin film composition and structure which does not physically interfere with the deposition process. Several TOF-SARS implementations are exceptionally surface specific, yet in a properly designed system can yield high-resolution data at ambient pressures well in excess of 10 mTorr (4–6 orders of magnitude higher than conventional surface analytic methods). Because of the exceptional surface specificity of these methods, TOF-SARS is ideally suited as a means of studying ultrathin layers and atomically abrupt interfaces. TOF-SARS instrumentation designed specifically for use as an in situ, real-time monitor of growth processes for single and multicomponent thin films and layered structures is described here. Representative data are shown for in situ analysis of Pb and Zr layers at room temperature and high vacuum, as well as under conditions appropriate to the growth of Pb(ZrxTi1−x)O3 (PZT) perovskite films on MgO and RuO2 substrates.
    Type of Medium: Online Resource
    ISSN: 0734-2101 , 1520-8559
    RVK:
    Language: English
    Publisher: American Vacuum Society
    Publication Date: 1994
    detail.hit.zdb_id: 1475424-1
    detail.hit.zdb_id: 797704-9
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  • 4
    Online Resource
    Online Resource
    American Vacuum Society ; 1994
    In:  Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films Vol. 12, No. 4 ( 1994-07-01), p. 1557-1564
    In: Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, American Vacuum Society, Vol. 12, No. 4 ( 1994-07-01), p. 1557-1564
    Abstract: A time-of-flight (TOF) ion scattering and direct recoil spectrometer (ISS/DRS) has been developed to study the surface composition and reconstruction of metals, metal-oxides, and semiconductors, and to provide in situ characterization of the thin-film deposition process. The in situ, real-time study of Pb, Zr, and Ru ultrathin films produced by ion beam sputter deposition is presented here as the first demonstration of TOF-ISS as a means of characterizing monolayer and submonolayer growth, both in UHV and in mTorr oxygen background. The capability of performing surface analysis at pressures ≳10−3 Torr is unique to pulsed ion beam surface analysis among surface analytical methods and enables the in situ monitoring of oxide thin-film growth processes and surface–gas phase reactions. Using angular-resolved ISS combined with Auger electron spectroscopy, we studied the oxygen adsorption and reconstruction of (001) oriented InSb thin-film surfaces. It was found that the adsorption of molecular oxygen on the InSb (001) surface is consistent with the Langmuir model. Oxygen adsorption preferentially occurs on the antimony sites corresponding to the extension of the lattice into the vacuum and reduces the inward contraction of the first two layers of the clean InSb (001) surface relative to the bulk atomic spacing.  
    Type of Medium: Online Resource
    ISSN: 0734-2101 , 1520-8559
    RVK:
    Language: English
    Publisher: American Vacuum Society
    Publication Date: 1994
    detail.hit.zdb_id: 1475424-1
    detail.hit.zdb_id: 797704-9
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  • 5
    Online Resource
    Online Resource
    American Vacuum Society ; 1998
    In:  Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films Vol. 16, No. 3 ( 1998-05-01), p. 1779-1784
    In: Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, American Vacuum Society, Vol. 16, No. 3 ( 1998-05-01), p. 1779-1784
    Abstract: We have used the ion spectroscopic techniques of direct recoil spectroscopy and mass spectroscopy of recoiled ions to demonstrate that low energy reactive ion sputtering of Ge is capable of removing surface impurities such as carbon. The experiments were performed in a vacuum chamber maintained at 3.5×10−7 Torr. At these pressures, physical sputtering using noble gas is not effective for cleaning Ge surfaces as carbon redeposits onto the surface. In this article, we demonstrate that reactive sputtering of Ge using 4.0 keV nitrogen at a Ge surface temperature of ∼740 K and above removes surface carbon and deposits nitrogen on the Ge surface. Heating the nitrogen exposed Ge surface to above ∼880 K results in the desorption of nitrogen and generates an atomically clean Ge surface, under poor vacuum conditions.
    Type of Medium: Online Resource
    ISSN: 0734-2101 , 1520-8559
    RVK:
    Language: English
    Publisher: American Vacuum Society
    Publication Date: 1998
    detail.hit.zdb_id: 1475424-1
    detail.hit.zdb_id: 797704-9
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  • 6
    Online Resource
    Online Resource
    American Vacuum Society ; 1988
    In:  Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films Vol. 6, No. 3 ( 1988-05-01), p. 2073-2076
    In: Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, American Vacuum Society, Vol. 6, No. 3 ( 1988-05-01), p. 2073-2076
    Abstract: Methoxyl carbon and oxygen are shown to specifically add to the lithium fraction of a CuLi surface exposed to methanol. The lithium surface fraction is determined by direct recoil spectroscopic (DRS) measurement of the H, C, and O added to the surface by methanol exposure and by subsequent comparison to the amounts of C, O, and metal determined by Auger electron spectroscopy (AES) or x-ray photoelectron spectroscopy (XPS). Direct determination of surface Li by AES or XPS is complicated by relatively large sampling depths (5 or 20 Å). The indirect determination of surface Li by methanol chemisorption/AES has been used to calibrate the sensitivity of 5-keV K+ DRS for lithium.
    Type of Medium: Online Resource
    ISSN: 0734-2101 , 1520-8559
    RVK:
    Language: English
    Publisher: American Vacuum Society
    Publication Date: 1988
    detail.hit.zdb_id: 1475424-1
    detail.hit.zdb_id: 797704-9
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  • 7
    Online Resource
    Online Resource
    American Vacuum Society ; 1999
    In:  Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films Vol. 17, No. 5 ( 1999-09-01), p. 2634-2641
    In: Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, American Vacuum Society, Vol. 17, No. 5 ( 1999-09-01), p. 2634-2641
    Abstract: We have modeled, designed, built, and tested a novel reflectron time-of-flight (TOF) analyzer, which is capable of performing surface analysis using both secondary ion mass spectroscopy (SIMS) and mass spectroscopy of recoiled ions (MSRI). All elements (including H and He) can be identified, with isotopic resolution, using both MSRI and SIMS. For ions of a given mass, the higher energy ions penetrate further into the reflectron before being turned around while the lower energy ions do not penetrate as deeply. By properly adjusting both the experimental geometry and the reflectron voltages, all ions of a given mass arrive at the detector simultaneously—resulting in enhanced mass resolution compared with simple TOF detection. SIM spectra are complicated by molecular fragments in addition to elemental ions. In MSRI only elemental ions are detected. As a result, data analysis in MSRI is less complicated than in SIMS. Being able to use a single analyzer to selectively obtain SIMS or MSRI data provides complementary surface information. MSRI has a number of unique capabilities for surface studies. In situ, real-time surface analysis can be performed during film growth at pressures of ∼2.5 mTorr at the substrate by differentially pumping both the ion source and the reflectron analyzer region. It has been demonstrated that the ratio of the positive to negative ion yield is phase specific; for example, one can clearly distinguish the different forms of carbon (diamond versus graphite versus amorphous carbon) during film growth. MSRI analysis of poorly conducting surfaces is possible.
    Type of Medium: Online Resource
    ISSN: 0734-2101 , 1520-8559
    RVK:
    Language: English
    Publisher: American Vacuum Society
    Publication Date: 1999
    detail.hit.zdb_id: 1475424-1
    detail.hit.zdb_id: 797704-9
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  • 8
    Online Resource
    Online Resource
    American Vacuum Society ; 2000
    In:  Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena Vol. 18, No. 5 ( 2000-09-01), p. 2427-2432
    In: Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena, American Vacuum Society, Vol. 18, No. 5 ( 2000-09-01), p. 2427-2432
    Abstract: Vertical edge emitter arrays of thin walled (500–8000 Å) hollow cylinders have been fabricated by the deposition of Cu–20 at. % Li alloy (Cu4Li) thin films on arrays of Si posts, followed by selective etching of the Si core. What remains is a hollow cylinder of Cu4Li, where the thickness of the emitting edge is determined by the deposited film thickness. Additionally, lateral edge emitters were fabricated from arrays of holes in SiO2 or Si3N4 films on flat Si surfaces. In this case, the emitting edge is formed by selectively overetching the Si beneath the hole, creating an edge from the overhang of the SiO2 (Si3N4) thin film upon which the Cu4Li alloy is deposited. The Cu4Li alloy provides a surface covered with a monolayer of Li atoms formed via Gibbsian segregation. The formation of Li–Cu atom dipoles on the surface of the alloy yields a work function lower than that of either a pure Li or Cu surface, resulting in enhanced electron emission and very low threshold fields. The alloy coating maintains a segregated monolayer of Li atoms on the surface even under adverse operational conditions, including ion bombardment of the surface. Edge emitters offer many potential advantages over the standard microtip arrays including ease of fabrication, higher emission currents per emitter due to the larger emission area of the edge, and greater physical robustness. The Cu4Li edge emitters exhibit threshold fields as low as E0=5 V/μm, high current densities, and long-lived, stable emission.
    Type of Medium: Online Resource
    ISSN: 1071-1023 , 1520-8567
    RVK:
    Language: English
    Publisher: American Vacuum Society
    Publication Date: 2000
    detail.hit.zdb_id: 3117331-7
    detail.hit.zdb_id: 3117333-0
    detail.hit.zdb_id: 1475429-0
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  • 9
    Online Resource
    Online Resource
    American Vacuum Society ; 1988
    In:  Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films Vol. 6, No. 3 ( 1988-05-01), p. 2064-2068
    In: Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, American Vacuum Society, Vol. 6, No. 3 ( 1988-05-01), p. 2064-2068
    Abstract: The depth of origin of sputtered atoms is a subject of considerable interest. The surface sensitivity of analytical techniques such as secondary ion mass spectrometry and surface analysis by resonance ionization of sputtered atoms (SARISA), and the sputtering properties of strongly segregating alloy systems, are critically dependent on the sputtering depth of origin. A significant discrepancy exists between the predictions of existing analytical sputtering theories and computer sputtering models; in general, the computer models predict a much shallower depth of origin. The existing experimental evidence suggests that most of the sputtered atoms originate in the topmost atomic layer, but until recently, the results have not been definitive. We have experimentally determined the depth of origin of atoms sputtered from surfaces consisting of Cu films of & lt;2 monolayers on a Ru(0001) substrate. The Cu/Ru target was statically sputtered using 3.6-keV Ar+. The sputtered neutrals were nonresonantly laser ionized and detected using SARISA. The Cu/Ru sputtering yield ratio and the suppression of the Ru sputtering yield were determined for various Cu coverages. The results indicate that the majority of the sputtered atoms originate in the topmost atomic layer. The Cu/Ru system is also modeled using a modified transport of ions in matter (trim) code. It was found that trim c does not correctly treat the first atomic layer, resulting in a serious underestimate of the number of sputtered atoms which originate in this layer. The corrected version adequately describes the results, predicting that for the experimental conditions roughly two-thirds of the sputtered atoms originate in the first atomic layer. These results are significantly greater than the analytical theory estimate of & gt;40%.
    Type of Medium: Online Resource
    ISSN: 0734-2101 , 1520-8559
    RVK:
    Language: English
    Publisher: American Vacuum Society
    Publication Date: 1988
    detail.hit.zdb_id: 1475424-1
    detail.hit.zdb_id: 797704-9
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  • 10
    Online Resource
    Online Resource
    American Vacuum Society ; 1983
    In:  Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films Vol. 1, No. 2 ( 1983-04-01), p. 924-928
    In: Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, American Vacuum Society, Vol. 1, No. 2 ( 1983-04-01), p. 924-928
    Abstract: Previous experiments on segregation in dilute alloys of lithium in aluminum have demonstrated rapid enrichment of lithium in the uppermost monolayer, as well as a slower buildup in the subsurface region as a result of radiation-induced segregation effects during sputtering. Surface and subsurface enrichment of lithium in copper and aluminum alloys has been observed by secondary ion mass spectroscopy (SIMS), Auger electron spectroscopy (AES), and x-ray photoemission spectroscopy (XPS). The activation energies for lithium diffusion in Cu and Al have been measured and segregation kinetics are compared for dilute alloys of Li in Cu and Al, and a high lithium content copper alloy. The results are interpreted in terms of both Gibbsian and radiation-induced segregation effects.
    Type of Medium: Online Resource
    ISSN: 0734-2101 , 1520-8559
    RVK:
    Language: English
    Publisher: American Vacuum Society
    Publication Date: 1983
    detail.hit.zdb_id: 1475424-1
    detail.hit.zdb_id: 797704-9
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