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  • MDPI AG  (4)
  • 1
    In: Processes, MDPI AG, Vol. 11, No. 5 ( 2023-04-27), p. 1349-
    Abstract: The microstructure mechanisms and mechanical properties of 0.23C-1.96Si-1.94Cr-1.93 Mn-0.35 Mo ultra-high strength steel treated by the deep cryogenic treatment at −196 °C were investigated after the steel was hot rolled at different temperatures. Experimental results show that austenitizing zone rolling with a large reduction in a single pass can comprehensively enhance the mechanical properties due to the high volume of retained austenite and refined lath martensite and bainite. The high strain gradient was suppressed, and tensile strength, yield strength, impact toughness, and total elongation were 2221 MPa, 2017 MPa, 65.5 J, and 16.9%, respectively. In addition, the austenitizing zone rolling can promote the formation of film retained austenite more than dual phase zone rolling, and retained austenite was decreased with an increase in rolling pass in a total rolling reduction of 75%. It is demonstrated that deep cryogenic treatment after austenite zone rolling with a large reduction is the proper method to enhance strength and toughness via refinement strengthening and retained austenite. This work not only reveals that the effects of refinement strengthening and high strain gradients can be markedly improved by deep cryogenic treatment after austenitizing zone rolling with large reduction strategies, but also provides a realistic preparation technology for the exploitation of superior steel applications.
    Type of Medium: Online Resource
    ISSN: 2227-9717
    Language: English
    Publisher: MDPI AG
    Publication Date: 2023
    detail.hit.zdb_id: 2720994-5
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  • 2
    In: Materials, MDPI AG, Vol. 15, No. 19 ( 2022-10-04), p. 6892-
    Abstract: Ag-Zn alloys are identified as highly active and selective electrocatalysts for CO2 reduction reaction (CO2RR), while how the phase composition of the alloy affects the catalytic performances has not been systematically studied yet. In this study, we fabricated a series of Ag-Zn alloy catalysts by magnetron co-sputtering and further explored their activity and selectivity towards CO2 electroreduction in an aqueous KHCO3 electrolyte. The different Ag-Zn alloys involve one or more phases of Ag, AgZn, Ag5Zn8, AgZn3, and Zn. For all the catalysts, CO is the main product, likely due to the weak CO binding energy on the catalyst surface. The Ag5Zn8 and AgZn3 catalysts show a higher CO selectivity than that of pure Zn due to the synergistic effect of Ag and Zn, while the pure Ag catalyst exhibits the highest CO selectivity. Zn alloying improves the catalytic activity and reaction kinetics of CO2RR, and the AgZn3 catalyst shows the highest apparent electrocatalytic activity. This work found that the activity and selectivity of CO2RR are highly dependent on the element concentrations and phase compositions, which is inspiring to explore Ag-Zn alloy catalysts with promising CO2RR properties.
    Type of Medium: Online Resource
    ISSN: 1996-1944
    Language: English
    Publisher: MDPI AG
    Publication Date: 2022
    detail.hit.zdb_id: 2487261-1
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  • 3
    In: Energies, MDPI AG, Vol. 15, No. 10 ( 2022-05-22), p. 3818-
    Abstract: The thermal evolution process of organic matter is associated with the complete hydrocarbon generation and expulsion process in shale, however, the thermal evolution of organic matter is a long process and cannot be realized without experimental simulations. Although several scholars have substantially studied the thermal evolution of organic matter, it remains a challenging and much debated issue in the studies of organic geochemistry. Volcanic events are crucial in the enrichment of organic matter, and appropriate heating accelerates the thermal evolution of organic matter. However, how strong-rock baking restricts the evolution of organic matter in shale has not been specifically studied. The South Qilian Basin in China is a typical superimposed basin where complex tectonic movements have induced multiple volcanic events, which makes it a favorable location to perform the aforementioned research. This study used the Galedesi Formation shale in the Hala Lake Depression of the South Qilian Basin as an example for investigating the constraints of the volcanic events related to the thermal evolution of organic matter by integrating the results obtained using the geochemical and petrological methods. Our results demonstrate that the lacustrine Galedesi Formation shale of the Hala Lake Depression in the Late Triassic is a typical deep-lake facies deposit with good hydrocarbon generation potential. However, because of the influence of regional tectonic evolution, the burial depth of shale is not deep and the thermal evolution of organic matter is insufficient. Due to the influence of multiple volcanic thermal events in the later stages, the thermal maturity of organic matter in the Galedesi Formation shale generally exceeds 3.0%, which is abnormally high. The apparent carbonization of organic matter can be observed via scanning electron microscopy. Rapid magma baking typically cannot effectively promote the hydrocarbon generation of shale organic matter. Finally, the burial depth of lacustrine shale of the Galedesi Formation in the Hala Lake Depression of South Qilian Basin is too shallow. Organic matter hydrocarbon generation and later shale preservation conditions are not conducive to the enrichment, accumulation, exploration, and development of shale gas.
    Type of Medium: Online Resource
    ISSN: 1996-1073
    Language: English
    Publisher: MDPI AG
    Publication Date: 2022
    detail.hit.zdb_id: 2437446-5
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  • 4
    In: Energies, MDPI AG, Vol. 15, No. 10 ( 2022-05-22), p. 3813-
    Abstract: The intrusive rock buried-hill reservoir is one of the main targets for oil and gas exploration in the offshore sedimentary basins of China. In order to discover the reservoir as early as possible for decision-making to save costs, reservoir interpretation with mud-logging data needs to be studied. Previous studies have showed that the homogeneity rocks reservoir can be well interpreted with mud-logging data u the Kb (mechanical specific energy ratio) method and the WL (tangential power)-WH (vertical power) intersection method. However, reservoir interpretation with mud-logging data for intrusive rock buried-hill has not been reported. The key steps or parameters of these two kinds of methods used for reservoir interpretation need to be modified for the vertical variation of intrusive rock buried-hill. Furthermore, confirming the interpretation of these two kinds of methods has not been reported. Taking the Y area in the Qiongdongnan Basin of the South China Sea as an example, the intrusive rock buried-hill can be divided into four zones based on its characteristics and genesis in descending order: the sand–gravel weathering zone, the weathering fracture zone, the inner fracture zone, and the base rock zone. The reservoir can be well interpreted when taking the MSE (mechanical specific energy) geometrical mean of the base rock zone as a basic value to calculate Kb. The reservoir will also be well interpreted when WH ranges from 0 to 4.5 MPa and WL ranges from 0 to 99 MPa in the column while intersecting. The layers of the reservoir can be interpreted as Kb 〈 1 in the sand–gravel weathering zone and the weathering fracture zone. The Kb 〈 1 and effective intersection of WL-WH layers at the same time could be interpreted as a reservoir in the inner fracture zone and the base rock zone. After combining the Kb method with the WL-WH intersection method, the reservoir of intrusive rock buried-hill can be well interpreted. The total thickness of the uninterpretable reservoir ratio is less than 20% compared to reservoir interpretation with well-logging for each well.
    Type of Medium: Online Resource
    ISSN: 1996-1073
    Language: English
    Publisher: MDPI AG
    Publication Date: 2022
    detail.hit.zdb_id: 2437446-5
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