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  • The Electrochemical Society  (11)
  • 1
    Online Resource
    Online Resource
    The Electrochemical Society ; 2018
    In:  ECS Transactions Vol. 85, No. 9 ( 2018-03-21), p. 69-76
    In: ECS Transactions, The Electrochemical Society, Vol. 85, No. 9 ( 2018-03-21), p. 69-76
    Type of Medium: Online Resource
    ISSN: 1938-6737 , 1938-5862
    Language: English
    Publisher: The Electrochemical Society
    Publication Date: 2018
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  • 2
    Online Resource
    Online Resource
    The Electrochemical Society ; 2021
    In:  ECS Meeting Abstracts Vol. MA2021-01, No. 61 ( 2021-05-30), p. 1636-1636
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2021-01, No. 61 ( 2021-05-30), p. 1636-1636
    Abstract: We fabricated the plasmonic nano-slit pore platforms for single molecule detection and other various applications. The nano-apertures on the Au/insulator/Au/SiN flat membrane, in addition to the 200 nm thick Au film on ~ 20 nm thick SiN membrane were fabricated using a focused ion beam drilling technique. The insulating materials of SiO2 or Al2O3 were deposited using an atomic layer epitaxy technique. The nanopores with a few nanometer size were fabricated under the proper control of drilling depth and pore opening. Optical characteristics were carried out dependent upon the pore opening width and sample thickness. The broad emission spectra from the (7x 7) slit pore array are obtained via spp-mediated emission on the ~200 nm thick Au/~ 20 nm thick SiN flat samples. A sharp strong infrared emission peak is also obtained due to Au nanoparticle. The fabricated Au double layer platform will be investigated for a single molecule sensor device and a possible radiative thermal energy transfer device.
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2021
    detail.hit.zdb_id: 2438749-6
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  • 3
    Online Resource
    Online Resource
    The Electrochemical Society ; 2021
    In:  ECS Meeting Abstracts Vol. MA2021-02, No. 55 ( 2021-10-19), p. 1566-1566
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2021-02, No. 55 ( 2021-10-19), p. 1566-1566
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2021
    detail.hit.zdb_id: 2438749-6
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  • 4
    Online Resource
    Online Resource
    The Electrochemical Society ; 2018
    In:  ECS Meeting Abstracts Vol. MA2018-01, No. 25 ( 2018-04-13), p. 1518-1518
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2018-01, No. 25 ( 2018-04-13), p. 1518-1518
    Abstract: Recently the portable device called MINion for single molecule analysis was developed by Oxford Nanopore Technology. The electrical detection technique for the solid state device was utilized for single molecule detection . However, the large error rates were reported by several journals, even though the significant error reduction was developed after the invention of the portable nanopore device. In this report, we introduce the optical nanopore fabrication by using plasmonic optical enhancement effect. First, the Au thin films were vacuum-deposited on the nanometer thin SiN film, followed by removal of SiN film and by drilling Au apertures by using focused ion beam (FIB) technique. Then, electron beam irradiations on the specimens either by using low energy field emission electron beam microscopy (FESEM) or high energy Transmission electron beam microscopy (TEM). In addition, the periodic grooves, or the periodic Au aperture array were fabricated on the Au sample in order to provide strong plamonic optical enhancements. During the electron irradiation on the fabricated Au surface, we observed the diffused binary Au-C membrane due to Ostwald ripening and also the unstable Au-C mixed phase change via spinodal decomposition. We also found that the Au cluster diffusion would depend upon the electron beam fluence. However, the exact understanding of this phenomenon is still on-going investigation. Figure 1
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2018
    detail.hit.zdb_id: 2438749-6
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  • 5
    Online Resource
    Online Resource
    The Electrochemical Society ; 2015
    In:  ECS Meeting Abstracts Vol. MA2015-01, No. 23 ( 2015-04-29), p. 1464-1464
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2015-01, No. 23 ( 2015-04-29), p. 1464-1464
    Abstract: In the electronic-device market, flexible displays using plastic substrates are considered to be one of the most promising alternatives for realizing the new functional needs of flat-panel displays. They are largely composed of a display element, thin film transistor (TFT) backplane, and a flexible substrate; the displays are an integrated system of these units. This means that the mechanical flexibility of each element to the physical stress while preserving the electrical stability is quite important because they reliably enable the overall flexibility of the integrated bending system. In this research, we report the effect of electromechanical and mechanical strain on coplanar amorphous indium-gallium-zinc-oxide (a-IGZO) thin film transistor regarding to the structural design of the device and the neutral axis location in bending. Here we show the highly reliable bending feature of the island structured (IS) device and its backplane after being subjected to an extreme cyclic bending stress [Fig.1]. The coplanar IS TFTs fabricated on polyimide (PI) substrate exhibit excellent bendability for an cyclic bending of 100,000 cycles with a radious less than 2 mm without a remarkable change of electrical properties although the coplanar device with the conventional structure shows an significant electrical failure at the same mechanical strain [Fig.2] . Competitive study of the device stability characterized by the neutral axis also reveals the strong effect of neutral plane (N.P) as well as the location from N.P for bending stress, which is also greatly assigned to the device configuration. That is, when the device is positioned close to the neutral plane using the sandwiched structure, the electrical characteristic of TFTs is quite stable for the induced mechanical bending without relying on the device configuration [Fig.3]. As the device is positioned apart from the neutral plane, the electrical performance is obiously degraded in the position about 30 μm from N.P on the device with the conventional structure as a function of bending cycles [Fig.4] . The onset of crack strain is also closely corresponds to that of the electrical failure of the device. On the otherhands, figure 4 clearly reveals that the positioning margin in the neutral zone is remarkably enhanced after emolying IS structure on a-IGZO devices for the extreme bending stress. IS TFTs achieved the stable electrical characterisic such as the mobility (μ) change less than 10 % compared to that of inital value (μ o ) for an cyclic bending of 100,000 cycles even they are subjcted to the mechanical tensile strain over 2.5 % without the cracks, which is corresponding to the device position in 50 μm far from N.P with a radius of 2 mm [Fig.4]. As a result, IS TFTs enable to bend until the radius of 1 mm thanks to the bendability enhancement, preserving μ decrease less than 20 % from μ o . To our knowledge, this is one of the highest bendable feature adopting the inorganic TFT and its backplane which is also comparable with that of flexible organic device. Since the mechanical flexibility of the backplane component is one of key elements to achieve the integrated bending system as we discussed eariler, this result shows unique potential of IS TFT and its backplane to open new form factor flexible displays such as folding or rolling displays. Figure 1
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2015
    detail.hit.zdb_id: 2438749-6
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  • 6
    Online Resource
    Online Resource
    The Electrochemical Society ; 2022
    In:  ECS Meeting Abstracts Vol. MA2022-02, No. 3 ( 2022-10-09), p. 325-325
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2022-02, No. 3 ( 2022-10-09), p. 325-325
    Abstract: The recharging capability of Ni-rich layered cathodes deteriorates rapidly upon cycling, mainly from mechanical instability caused by removing a large amount of Li ions from the host structure. 1,2 The resulting microcracks expose the cathode particle interior to electrolyte attack in addition to undermining the mechanical integrity of the cathode particle. In this study, we develop a Ni-rich layered cathode by combining precursor engineering and a new doping strategy during lithiation that generates minimal microcracking and exhibits substantially improved cycling stability. Excess Al is deliberately introduced into a concentration-gradient (CG) hydroxide precursor, which exhibits a highly oriented geometry in which elongated primary particles are aligned in the radial direction of a spherical secondary particles. The excess Al ions enable the refinement of the primary particles in a controlled manner and the precise tailoring of their morphology and orientation. It is demonstrated that the chemical and microstructural engineering of a Li[Ni x Co y Al 1–x–y ]O 2 (NCA) cathode starting from its precursor stage produces a unique structure that relieves the detrimental mechanical strain and significantly extends the battery life. Thus, the designed CG Li[Ni 0.86 Co 0.1 Al 0.04 ]O 2 retains 86.5% of the initial capacity after 2000 cycles and an unprecedented 78.0% even at a severe operation condition of 45 o C. The proposed CG Li[Ni 0.86 Co 0.1 Al 0.04 ]O 2 represents a new class of Ni-rich NCA cathodes that can meet the energy density required for next-generation electric vehicles, without compromising the battery life and safety. Reference s : [1] S. Watanabe, M. Kinoshita, T. Hosokawa, K. Morigaki, K. Nakura, J. Power Sources 258 (2014) 210–217. [2] H.-H. Ryu, K.-J. Park, C. S. Yoon, Y.-K. Sun, Chem. Mater. 30 (2018) 1155–1163.
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2022
    detail.hit.zdb_id: 2438749-6
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  • 7
    Online Resource
    Online Resource
    The Electrochemical Society ; 2015
    In:  ECS Transactions Vol. 66, No. 1 ( 2015-04-13), p. 241-247
    In: ECS Transactions, The Electrochemical Society, Vol. 66, No. 1 ( 2015-04-13), p. 241-247
    Abstract: The effect of electromechanical and mechanical strain was studied on amorphous indium-gallium-zinc-oxide (a-IGZO) thin film transistor regarding to the structural design of the device as well as the location from neutral plane (N.P) for bending stress. Here we show a highly reliable bending feature of the island structured (IS) device and its backplane against the mechanical strain after being subjected to an extreme tensile cyclic bending stress. The IS TFTs fabricated on polyimide (PI) substrate exhibit an pronounced bendability for an cyclic bending of 100,000 cycles with varying radii to a radius less than 2 mm with the electro-mechanical integrity. The onset of crack strain also closely corresponds to that of the electrical degradation of the device. The backplane array composed of IS TFTs clearly reveals that the island configuration remarkably reduce the bending stress accumulation on the sheets of inorganic stacked layers along to the uniaxial on plastic substrate.
    Type of Medium: Online Resource
    ISSN: 1938-5862 , 1938-6737
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2015
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  • 8
    Online Resource
    Online Resource
    The Electrochemical Society ; 2012
    In:  ECS Meeting Abstracts Vol. MA2012-01, No. 8 ( 2012-02-15), p. 416-416
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2012-01, No. 8 ( 2012-02-15), p. 416-416
    Abstract: Abstract not Available.
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2012
    detail.hit.zdb_id: 2438749-6
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  • 9
    Online Resource
    Online Resource
    The Electrochemical Society ; 2020
    In:  ECS Journal of Solid State Science and Technology Vol. 9, No. 11 ( 2020-01-12), p. 115015-
    In: ECS Journal of Solid State Science and Technology, The Electrochemical Society, Vol. 9, No. 11 ( 2020-01-12), p. 115015-
    Abstract: We have fabricated the Au nano-aperture array platforms on the Au films for single molecule analysis. Previously, we reported fabrication of the 200 nm wide double slits with various separations between two nanoslits, and the optical characteristics. In this paper, we will address the optical characteristics of various Au aperture platfoms; the double slits with a 50 nm opening width, the nanoslit array with its opening width less than 100 nm, and the circular type nano-aperture by using 30 keV focused Ga ion beam techniques, along with Au nanopore formation under the high energy electron beam irradiations at 200 keV. For the slit width less than 100 nm, we observed the surface plasmon polariton (SPP)-mediated intraband transmission peak at ∼500 nm, and the SPP-coupled peak around ∼650 nm. The optical intensities are measured to be dependent upon the size of the nano-aperture, the opening width of the slit, and the thickness of the Au film. For a 30 nm slit width, the broadband emission ranging from ∼600 nm to 800 nm were also observed. The fabricated Au plasmonic platforms can be utilized as single molecule bio-sensor.
    Type of Medium: Online Resource
    ISSN: 2162-8769 , 2162-8777
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2020
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  • 10
    Online Resource
    Online Resource
    The Electrochemical Society ; 2006
    In:  ECS Transactions Vol. 3, No. 8 ( 2006-10-20), p. 69-74
    In: ECS Transactions, The Electrochemical Society, Vol. 3, No. 8 ( 2006-10-20), p. 69-74
    Abstract: In the conventional SLS crystallization method, we just perform a basic pre-align on the substrate stage and apply a whole substrate area scanning. Therefore, each TFT has different grain boundary(GB) location in channel region. The number of grain boundaries in channel also varies from one to two, which can cause non-uniform TFT characteristics and image quality deterioration of the panel. In this paper, we present work that has been carried out using the SLS process to control grain boundary(GB) location in TFT channel region and it is possible to locate the GB at the same location in the channel region of each TFT. We fabricated TFT by applying a new alignment SLS process and compared the TFT characteristics between a normal SLS method and the grain boundary location controlled SLS method.
    Type of Medium: Online Resource
    ISSN: 1938-5862 , 1938-6737
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2006
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