In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 74, No. 10 ( 2019-10-25), p. 739-744
Abstract:
The reactions of Zn(NO 3 ) 2 · 6H 2 O/CuCl 2 · 2H 2 O and 1,4-bis(1-imidazolyl)benzene (bib)/1,4-bis(1-imidazol-1-ylmethyl)benzene (biyb), carried out under hydrothermal conditions, produced two new coordination polymers [Zn(bib)(HCOO) 2 · H 2 O] ( 1 ) and [Cu(biyb)Cl 2 ] ( 2 ), respectively, which were characterized by elemental analysis, infrared spectroscopy, thermogravimetric analyses, and single-crystal X-ray diffraction. In complex 1 , the Zn II centers are bridged by bib ligands to form a chain, where the adjacent chains are condensed by strong intermolecular O–H · · · O hydrogen-bonding and aromatic π-π stacking interactions to generate a 3D supramolecular structure. In 2 , the Cu II centers are bridged by biyb ligands to form, again, chains through C–H · · · Cl hydrogen bonds, and these adjacent chains with different orientations are joined to generate a 3D supramolecular structure.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-2019-0107
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
2019
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
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