In:
Chemistry – A European Journal, Wiley, Vol. 25, No. 68 ( 2019-12-05), p. 15656-15661
Abstract:
The binary lead fluoride Pb 3 F 8 was synthesized by the reaction of anhydrous HF with Pb 3 O 4 or by the reaction of BrF 3 with PbF 2 . The compound was characterized by single‐crystal and powder X‐ray diffraction, IR, Raman, and solid‐state MAS 19 F NMR spectroscopy, as well as thermogravimetric analysis, XP and near‐edge X‐ray absorption fine structure (NEXAFS) spectroscopy. Solid‐state quantum‐chemical calculations are provided for the vibrational analyses and band assignments. The electronic band structure offers an inside view of the mixed valence compound.
Type of Medium:
Online Resource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.201903954
Language:
English
Publisher:
Wiley
Publication Date:
2019
detail.hit.zdb_id:
1478547-X
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