In:
Angewandte Chemie, Wiley, Vol. 129, No. 7 ( 2017-02-06), p. 1899-1902
Abstract:
The palladium(II)‐catalyzed β‐ and γ‐alkynylation of amide C(sp 3 )−H bonds is enabled by pyridine‐based ligands. This alkynylation reaction is compatible with substrates containing α‐tertiary or α‐quaternary carbon centers. The β‐methylene C(sp 3 )−H bonds of various carbocyclic rings were also successfully alkynylated.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.201610426
Language:
English
Publisher:
Wiley
Publication Date:
2017
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1479266-7
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