In:
Chemistry – A European Journal, Wiley, Vol. 14, No. 31 ( 2008-10-29), p. 9585-9590
Kurzfassung:
The chlorinated fullerenes C 78 (2)Cl 18 and C 78 (3)Cl 18 were synthesized by highly selective chlorination of the individual isomers. They were crystallized as C 78 (2)Cl 18 ⋅ Br 2 ⋅ TiCl 4 and solvent free C 78 (3)Cl 18 . The carbon connectivities of both isomers have been confirmed through X‐ray single‐crystal analysis. Studious investigation of both crystal packings together with the crystal structure of C 78 (4)Cl 18 has revealed the presence of unusually short intermolecular halogen–halogen contacts, which provide evidence for attractive intermolecular interactions, the nature of which is discussed.
Materialart:
Online-Ressource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.200801182
Sprache:
Englisch
Verlag:
Wiley
Publikationsdatum:
2008
ZDB Id:
1478547-X
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