In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 44, No. 8 ( 1989-8-1), p. 946-950
Abstract:
The title compound 1 was obtained by the reaction of CuBr 2 and thiobenzamide in methanol. Its magnetic susceptibility and its EPR spectrum show it to be a Cu(II) compound. The two different ligands PhCSNH 2 (2) and [PhCSNH] - (3) show up by distinct absorption bands in the IR spectrum. The crystal structure of 1 was determined by X-ray diffraction (1289 observed, unique reflexions, R = 0.048). Crystal data: monoclinic, space group P2 1 /n, Z = 2, a = 912.0(2), b = 1859.7(8), c = 1006.2(6) pm, β = 110.73(4)°. There are dimeric, centrosymmetric molecules in which the copper atoms are linked via the sulfur atoms of either 2 or 3, probably 3. The copper atoms show the coordination of a flattened tetrahedron.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-1989-0815
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
1989
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
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