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  • 1
    In: Meteoritics & Planetary Science, Wiley, Vol. 54, No. 3 ( 2019-03), p. 667-671
    Abstract: Executive summary provided in lieu of abstract.
    Type of Medium: Online Resource
    ISSN: 1086-9379 , 1945-5100
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2019
    detail.hit.zdb_id: 2011097-2
    SSG: 16,12
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  • 2
    In: Meteoritics & Planetary Science, Wiley, Vol. 54, No. S1 ( 2019-03)
    Abstract: Return of samples from the surface of Mars has been a goal of the international Mars science community for many years. Affirmation by NASA and ESA of the importance of Mars exploration led the agencies to establish the international MSR Objectives and Samples Team ( iMOST ). The purpose of the team is to re‐evaluate and update the sample‐related science and engineering objectives of a Mars Sample Return ( MSR ) campaign. The iMOST team has also undertaken to define the measurements and the types of samples that can best address the objectives. Seven objectives have been defined for MSR , traceable through two decades of previously published international priorities. The first two objectives are further divided into sub‐objectives. Within the main part of the report, the importance to science and/or engineering of each objective is described, critical measurements that would address the objectives are specified, and the kinds of samples that would be most likely to carry key information are identified. These seven objectives provide a framework for demonstrating how the first set of returned Martian samples would impact future Martian science and exploration. They also have implications for how analogous investigations might be conducted for samples returned by future missions from other solar system bodies, especially those that may harbor biologically relevant or sensitive material, such as Ocean Worlds (Europa, Enceladus, Titan) and others. Summary of Objectives and Sub‐Objectives for MSR Identified by iMOST Objective 1 Interpret the primary geologic processes and history that formed the Martian geologic record, with an emphasis on the role of water. Intent To investigate the geologic environment(s) represented at the Mars 2020 landing site, provide definitive geologic context for collected samples, and detail any characteristics that might relate to past biologic processes This objective is divided into five sub‐objectives that would apply at different landing sites. Characterize the essential stratigraphic, sedimentologic, and facies variations of a sequence of Martian sedimentary rocks. Intent To understand the preserved Martian sedimentary record. Samples A suite of sedimentary rocks that span the range of variation. Importance Basic inputs into the history of water, climate change, and the possibility of life Understand an ancient Martian hydrothermal system through study of its mineralization products and morphological expression. Intent To evaluate at least one potentially life‐bearing “habitable” environment Samples A suite of rocks formed and/or altered by hydrothermal fluids. Importance Identification of a potentially habitable geochemical environment with high preservation potential. Understand the rocks and minerals representative of a deep subsurface groundwater environment. Intent To evaluate definitively the role of water in the subsurface. Samples Suites of rocks/veins representing water/rock interaction in the subsurface. Importance May constitute the longest‐lived habitable environments and a key to the hydrologic cycle. Understand water/rock/atmosphere interactions at the Martian surface and how they have changed with time. Intent To constrain time‐variable factors necessary to preserve records of microbial life. Samples Regolith, paleosols, and evaporites. Importance Subaerial near‐surface processes could support and preserve microbial life. Determine the petrogenesis of Martian igneous rocks in time and space. Intent To provide definitive characterization of igneous rocks on Mars. Samples Diverse suites of ancient igneous rocks. Importance Thermochemical record of the planet and nature of the interior. Objective 2 Assess and interpret the potential biological history of Mars, including assaying returned samples for the evidence of life. Intent To investigate the nature and extent of Martian habitability, the conditions and processes that supported or challenged life, how different environments might have influenced the preservation of biosignatures and created nonbiological “mimics,” and to look for biosignatures of past or present life. This objective has three sub‐objectives: Assess and characterize carbon, including possible organic and pre‐biotic chemistry. Samples All samples collected as part of Objective 1. Importance Any biologic molecular scaffolding on Mars would likely be carbon‐based. Assay for the presence of biosignatures of past life at sites that hosted habitable environments and could have preserved any biosignatures. Samples All samples collected as part of Objective 1. Importance Provides the means of discovering ancient life. Assess the possibility that any life forms detected are alive, or were recently alive. Samples All samples collected as part of Objective 1. Importance Planetary protection, and arguably the most important scientific discovery possible. Objective 3 Quantitatively determine the evolutionary timeline of Mars. Intent To provide a radioisotope‐based time scale for major events, including magmatic, tectonic, fluvial, and impact events, and the formation of major sedimentary deposits and geomorphological features. Samples Ancient igneous rocks that bound critical stratigraphic intervals or correlate with crater‐dated surfaces. Importance Quantification of Martian geologic history. Objective 4 Constrain the inventory of Martian volatiles as a function of geologic time and determine the ways in which these volatiles have interacted with Mars as a geologic system. Intent To recognize and quantify the major roles that volatiles (in the atmosphere and in the hydrosphere) play in Martian geologic and possibly biologic evolution. Samples Current atmospheric gas, ancient atmospheric gas trapped in older rocks, and minerals that equilibrated with the ancient atmosphere. Importance Key to understanding climate and environmental evolution. Objective 5 Reconstruct the processes that have affected the origin and modification of the interior, including the crust, mantle, core and the evolution of the Martian dynamo. Intent To quantify processes that have shaped the planet's crust and underlying structure, including planetary differentiation, core segregation and state of the magnetic dynamo, and cratering. Samples Igneous, potentially magnetized rocks (both igneous and sedimentary) and impact‐generated samples. Importance Elucidate fundamental processes for comparative planetology. Objective 6 Understand and quantify the potential Martian environmental hazards to future human exploration and the terrestrial biosphere. Intent To define and mitigate an array of health risks related to the Martian environment associated with the potential future human exploration of Mars. Samples Fine‐grained dust and regolith samples. Importance Key input to planetary protection planning and astronaut health. Objective 7 Evaluate the type and distribution of in‐situ resources to support potential future Mars exploration. Intent To quantify the potential for obtaining Martian resources, including use of Martian materials as a source of water for human consumption, fuel production, building fabrication, and agriculture. Samples Regolith. Importance Production of simulants that will facilitate long‐term human presence on Mars. Summary of iMOST Findings Several specific findings were identified during the iMOST study. While they are not explicit recommendations, we suggest that they should serve as guidelines for future decision making regarding planning of potential future MSR missions. The samples to be collected by the Mars 2020 (M‐2020) rover will be of sufficient size and quality to address and solve a wide variety of scientific questions. Samples, by definition, are a statistical representation of a larger entity. Our ability to interpret the source geologic units and processes by studying sample sub sets is highly dependent on the quality of the sample context. In the case of the M‐2020 samples, the context is expected to be excellent, and at multiple scales. (A) Regional and planetary context will be established by the on‐going work of the multi‐agency fleet of Mars orbiters. (B) Local context will be established at field area‐ to outcrop‐ to hand sample‐ to hand lens scale using the instruments carried by M‐2020. A significant fraction of the value of the MSR sample collection would come from its organization into sample suites, which are small groupings of samples designed to represent key aspects of geologic or geochemical variation. If the Mars 2020 rover acquires a scientifically well‐chosen set of samples, with sufficient geological diversity, and if those samples were returned to Earth, then major progress can be expected on all seven of the objectives proposed in this study, regardless of the final choice of landing site. The specifics of which parts of Objective 1 could be achieved would be different at each of the final three candidate landing sites, but some combination of critically important progress could be made at any of them. An aspect of the search for evidence of life is that we do not know in advance how evidence for Martian life would be preserved in the geologic record.  In order for the returned samples to be most useful for both understanding geologic processes (Objective 1) and the search for life (Objective 2), the sample collection should contain BOTH typical and unusual samples from the rock units explored.  This consideration should be incorporated into sample selection and the design of the suites.  The retrieval missions of a MSR campaign should (1) minimize stray magnetic fields to which the samples would be exposed and carry a magnetic witness plate to record exposure, (2) collect and return atmospheric gas sample(s), and (3) collect additional dust and/or regolith sample mass if possible.
    Type of Medium: Online Resource
    ISSN: 1086-9379 , 1945-5100
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2019
    detail.hit.zdb_id: 2011097-2
    SSG: 16,12
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  • 3
    In: Science, American Association for the Advancement of Science (AAAS), Vol. 375, No. 6577 ( 2022-01-14), p. 172-177
    Abstract: Water-rock interactions are relevant to planetary habitability, influencing mineralogical diversity and the production of organic molecules. We examine carbonates and silicates in the martian meteorite Allan Hills 84001 (ALH 84001), using colocated nanoscale analyses, to characterize the nature of water-rock reactions on early Mars. We find complex refractory organic material associated with mineral assemblages that formed by mineral carbonation and serpentinization reactions. The organic molecules are colocated with nanophase magnetite; both formed in situ during water-rock interactions on Mars. Two potentially distinct mechanisms of abiotic organic synthesis operated on early Mars during the late Noachian period (3.9 to 4.1 billion years ago).
    Type of Medium: Online Resource
    ISSN: 0036-8075 , 1095-9203
    RVK:
    RVK:
    Language: English
    Publisher: American Association for the Advancement of Science (AAAS)
    Publication Date: 2022
    detail.hit.zdb_id: 128410-1
    detail.hit.zdb_id: 2066996-3
    detail.hit.zdb_id: 2060783-0
    SSG: 11
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  • 4
    In: Atmospheric Chemistry and Physics, Copernicus GmbH, Vol. 11, No. 16 ( 2011-08-19), p. 8459-8469
    Abstract: Abstract. Observations show that the fractional solubility of Fe (FS-Fe, percentage of dissolved to total Fe) in dust aerosol increases considerably from 0.1 % in regions of high dust mass concentration to 80 % in remote regions where concentrations are low. Here, we combined laboratory geochemical measurements with global aerosol model simulations to test the hypothesis that the increase in FS-Fe is due to physical size sorting during transport. We determined the FS-Fe and fractional solubility of Al (FS-Al) in size-fractionated dust generated from two representative soil samples collected from known Saharan dust source regions using a customized dust re-suspension and collection system. The results show that the FS-Fe is size-dependent and ranges from 0.1–0.3 % in the coarse size fractions (〉1 μm) to ~0.2–0.8 % in the fine size fractions (〈1 μm). The FS-Al shows a similar size distribution to that of the FS-Fe. The size-resolved FS-Fe data were then combined with simulated dust mass concentration and size distribution data from a global aerosol model, GLOMAP, to calculate the FS-Fe of dust aerosol over the tropical and subtropical North Atlantic Ocean. We find that the calculated FS-Fe in the dust aerosol increases systematically from ~0.1 % at high dust mass concentrations (e.g., 〉100 μg m−3) to ~0.2 % at low concentrations (〈100 μg m–3) due to physical size sorting (i.e., particle gravitational settling). These values are one to two orders of magnitude smaller than those observed on cruises across the tropical and sub-tropical North Atlantic Ocean under an important pathway of Saharan dust plumes for similar dust mass concentrations. Even when the FS-Fe of sub-micrometer size fractions (0.18–0.32 μm, 0.32–0.56 μm, and 0.56–1.0 μm) in the model is increased by a factor of 10 over the measured values, the calculated FS-Fe of the dust is still more than an order of magnitude lower than that measured in the field. Therefore, the physical sorting of dust particles alone is unlikely to be an important factor in the observed inverse relationship between the FS-Fe and FS-Al and the atmospheric mineral dust mass concentrations. The results suggest that processes such as chemical reactions and/or mixing with combustion particles are the main mechanisms to cause the increased FS-Fe in long-range transported dust aerosols.
    Type of Medium: Online Resource
    ISSN: 1680-7324
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2011
    detail.hit.zdb_id: 2092549-9
    detail.hit.zdb_id: 2069847-1
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  • 5
    Online Resource
    Online Resource
    Springer Science and Business Media LLC ; 2012
    In:  MRS Proceedings Vol. 1419 ( 2012)
    In: MRS Proceedings, Springer Science and Business Media LLC, Vol. 1419 ( 2012)
    Abstract: Aragonite can grow from calcium carbonate solutions as the favored phase, at ambient conditions, in the presence of 1:1 volume % water:ethanol. Its form is single and branched needles, with pseudohexagonal symmetry. Morphological evidence demonstrates that all precipitated aragonite is twinned. The recently popularized hypothesis of nonclassical growth by nanocrystal self assembly cannot describe the aragonite crystal form. Rather, its formation is effectively described as spherulitic growth, i.e. by classical crystal growth theory.
    Type of Medium: Online Resource
    ISSN: 0272-9172 , 1946-4274
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2012
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  • 6
    Online Resource
    Online Resource
    Mineralogical Society ; 2008
    In:  Mineralogical Magazine Vol. 72, No. 1 ( 2008-02), p. 345-348
    In: Mineralogical Magazine, Mineralogical Society, Vol. 72, No. 1 ( 2008-02), p. 345-348
    Abstract: Ice-hosted sediments in glaciers and icebergs from Antarctica and Svalbard contain authigenic nanoparticulates of schwertmannite, ferrihydrite and goethite that formed during sulphide oxidation. These phases indicate the existence of subglacial biogeochemical hotspots containing fluids of low pH (2—4), rich in dissolved Fe(III) and sulphate. Nanophase Fe is partially bioavailable and potentially important to global biogeochemical cycles, since the flux delivered by icebergs to the Southern Ocean is comparable to the flux of soluble, bioavailable Fe from aeolian dust.
    Type of Medium: Online Resource
    ISSN: 0026-461X , 1471-8022
    RVK:
    Language: English
    Publisher: Mineralogical Society
    Publication Date: 2008
    detail.hit.zdb_id: 2034522-7
    SSG: 13
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  • 7
    In: Scientific Reports, Springer Science and Business Media LLC, Vol. 5, No. 1 ( 2015-07-22)
    Abstract: Trees and their associated rhizosphere organisms play a major role in mineral weathering driving calcium fluxes from the continents to the oceans that ultimately control long-term atmospheric CO 2 and climate through the geochemical carbon cycle. Photosynthate allocation to tree roots and their mycorrhizal fungi is hypothesized to fuel the active secretion of protons and organic chelators that enhance calcium dissolution at fungal-mineral interfaces. This was tested using 14 CO 2 supplied to shoots of Pinus sylvestris ectomycorrhizal with the widespread fungus Paxillus involutus in monoxenic microcosms, revealing preferential allocation by the fungus of plant photoassimilate to weather grains of limestone and silicates each with a combined calcium and magnesium content of over 10 wt.%. Hyphae had acidic surfaces and linear accumulation of weathered calcium with secreted oxalate, increasing significantly in sequence: quartz, granite 〈 basalt, olivine, limestone 〈 gabbro. These findings confirmed the role of mineral-specific oxalate exudation in ectomycorrhizal weathering to dissolve calcium bearing minerals, thus contributing to the geochemical carbon cycle.
    Type of Medium: Online Resource
    ISSN: 2045-2322
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2015
    detail.hit.zdb_id: 2615211-3
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  • 8
    Online Resource
    Online Resource
    Mineralogical Society ; 2008
    In:  Mineralogical Magazine Vol. 72, No. 1 ( 2008-02), p. 385-388
    In: Mineralogical Magazine, Mineralogical Society, Vol. 72, No. 1 ( 2008-02), p. 385-388
    Abstract: In this paper, the kinetics of Mo and V (100 μM) uptake on ferrihydrite (FHY) were evaluated in batch, mono-sorbate systems at pH between 4 and 9, and in bi-sorbate systems in the presence of P (100 μM) at pH 7. In the Mo and V single-sorbate experiments, 100% adsorption was observed at pH values below 6 and 8, respectively. Above the point of zero charge (PZC = 7.97) of FHY, the adsorption efficiency for Mo dropped dramatically (20% at pH 8) while V showed high uptake efficiencies even at pH 9 (60% efficiency). The results from the bi-sorbate experiments (Mo-P and V-P) showed that at pH 7, P out-competed (97%) Mo for binding sites on FHY, while in the V-P binary system only ∼44% of the binding sites are occupied by P with the remaining sites being occupied by V.
    Type of Medium: Online Resource
    ISSN: 0026-461X , 1471-8022
    RVK:
    Language: English
    Publisher: Mineralogical Society
    Publication Date: 2008
    detail.hit.zdb_id: 2034522-7
    SSG: 13
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  • 9
    Online Resource
    Online Resource
    Mineralogical Society ; 2014
    In:  Mineralogical Magazine Vol. 78, No. 6 ( 2014-11), p. 1381-1389
    In: Mineralogical Magazine, Mineralogical Society, Vol. 78, No. 6 ( 2014-11), p. 1381-1389
    Abstract: Precipitation of amorphous silica (SiO 2 ) in geothermal power plants, although a common factor limiting the efficiency of geothermal energy production, is poorly understood and no universally applicable mitigation strategy to prevent or reduce precipitation is available. This is primarily due to the lack of understanding of the precipitation mechanism of amorphous silica in geothermal systems. In the present study data are presented about microstructures and compositions of precipitates formed on scaling plates inserted at five different locations in the pipelines at the Hellisheiði power station (SW-Iceland). Precipitates on these plates formed over 6 to 8 weeks of immersion in hot (120 or 60ºC), fast-flowing and silica-supersaturated geothermal fluids (~800 ppm of SiO 2 ). Although the composition of the precipitates is fairly homogeneous, with silica being the dominant component and Fe sulfides as a less common phase, the microstructures of the precipitates are highly variable and dependent on the location within the geothermal pipelines. The silica precipitates have grown through aggregation and precipitation of silica particles that precipitated homogeneously in the geothermal fluid. Five main factors were identified that may control the precipitation of silica: (1) temperature, (2) fluid composition, (3) fluid-flow regime, (4) distance along the flow path, and (5) immersion time. On all scaling plates, a corrosion layer was found underlying the silica precipitates indicating that, once formed, the presence of a silica layer probably protects the steel pipe surface against further corrosion. Yet silica precipitates influence the flow of the geothermal fluids and therefore can limit the efficiency of geothermal power stations.
    Type of Medium: Online Resource
    ISSN: 0026-461X , 1471-8022
    RVK:
    Language: English
    Publisher: Mineralogical Society
    Publication Date: 2014
    detail.hit.zdb_id: 2034522-7
    SSG: 13
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  • 10
    Online Resource
    Online Resource
    American Chemical Society (ACS) ; 2012
    In:  Crystal Growth & Design Vol. 12, No. 2 ( 2012-02-01), p. 842-853
    In: Crystal Growth & Design, American Chemical Society (ACS), Vol. 12, No. 2 ( 2012-02-01), p. 842-853
    Type of Medium: Online Resource
    ISSN: 1528-7483 , 1528-7505
    Language: English
    Publisher: American Chemical Society (ACS)
    Publication Date: 2012
    detail.hit.zdb_id: 2048329-6
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