In:
Zeitschrift für Naturforschung A, Walter de Gruyter GmbH, Vol. 57, No. 6-7 ( 2002-7-1), p. 620-622
Abstract:
The nuclear quadrupole interaction of 187 W(β - ) 187 Re in W(VI)-EDTA complexes at room temperature was determined by time differential perturbed angular correlations (TDPAC) to be V Q = 1270(8) MHz with an asymmetry parameter η= 0.403(4). While the coordination geometry of the Mo(VI)- EDTA complex is known, there appears to be none for the W-analogue. The rather similar asymmetry parameters for the 187 W(β - ) 187 Re in W(VI)-EDTA complex and for the 99 Mo(β - ) 99 Tc in Mo(VI)- EDTA complex, determined previously, supports the idea that the coordination geometries in the Moand W-complexes are similar
Type of Medium:
Online Resource
ISSN:
1865-7109
,
0932-0784
DOI:
10.1515/zna-2002-6-761
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
2002
detail.hit.zdb_id:
2079610-9
detail.hit.zdb_id:
124634-3
detail.hit.zdb_id:
124633-1
detail.hit.zdb_id:
2767412-5
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