In:
Angewandte Chemie, Wiley, Vol. 134, No. 16 ( 2022-04-11)
Abstract:
It has been long believed that the FeMoS structure, where Fe is bonded with S, plays a pivotal role as a biomimetic catalyst for electrochemical nitrogen (N 2 ) fixation. Nevertheless, the structure of Fe bonded to heavier analogues (Se or Te) has never been explored for N 2 electrofixation. Here, we theoretically predict the electronic structure of FeMo(Se, Te) composed of tri‐coordinated Fe species with open shells for binding with Se, which forms a joint electron pool for promoting N 2 activation. Guided by this interesting prediction, we then demonstrate a two‐step procedure to synthesize such structures, which display remarkable N 2 electrofixation activities with an ammonia yield of 72.54 μg h −1 mg −1 and a Faradic efficiency of 51.67 % that are more than three times of the FeMoS counterpart. Further mechanism studies have been conducted by density function theory (DFT) simulations. This work provides new clues for designing versatile electrocatalytic materials for large‐scale industrialization.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v134.16
DOI:
10.1002/ange.202115198
Language:
English
Publisher:
Wiley
Publication Date:
2022
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