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  • 1
    Online Resource
    Online Resource
    Springer Science and Business Media LLC ; 2013
    In:  ATZ - Automobiltechnische Zeitschrift Vol. 115, No. 7-8 ( 2013-07), p. 612-615
    In: ATZ - Automobiltechnische Zeitschrift, Springer Science and Business Media LLC, Vol. 115, No. 7-8 ( 2013-07), p. 612-615
    Type of Medium: Online Resource
    ISSN: 0001-2785 , 2192-8800
    RVK:
    RVK:
    RVK:
    Language: German
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2013
    detail.hit.zdb_id: 124863-7
    detail.hit.zdb_id: 2097891-1
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  • 2
    Online Resource
    Online Resource
    Wiley ; 2015
    In:  Progress in Photovoltaics: Research and Applications Vol. 23, No. 9 ( 2015-09), p. 1120-1130
    In: Progress in Photovoltaics: Research and Applications, Wiley, Vol. 23, No. 9 ( 2015-09), p. 1120-1130
    Abstract: A new approach on decreasing the optical shadowing of the solar cell grid fingers is presented. The approach relies on a local change of the optical properties in the bulk of the photovoltaic module encapsulation material ethylene vinyl acetate (EVA). In particular, scattering and diffractive optical elements are locally generated within the volume of cross‐linked EVA encapsulation material by applying a femtosecond‐laser‐writing process. When these optical elements are located above the metal grid fingers, the optical shadowing of these grid fingers can be decreased. In an experimental proof of concept, the optical performance of this approach is demonstrated. The best results obtained so far indicate a decrease in optical shadowing by 17%. The material characteristics of the volume optics were investigated by applying confocal Raman microscopic characterisation, which indicates that the EVA material partially degraded upon the impact of the laser beam and is partly carbonised. Supplementary optical simulations show that the light deflection is caused by diffraction. However, parasitic absorption substantially deteriorates the optical performance of the deflective volume optics. Copyright © 2014 John Wiley & Sons, Ltd.
    Type of Medium: Online Resource
    ISSN: 1062-7995 , 1099-159X
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2015
    detail.hit.zdb_id: 2023295-0
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  • 3
    In: Progress in Photovoltaics: Research and Applications, Wiley, Vol. 31, No. 7 ( 2023-07), p. 716-728
    Abstract: Although the technical and economic properties of the standard polymer photovoltaic (PV) materials (ethylene‐vinyl acetate (EVA) encapsulant and fluorine‐containing polyethylene terephthalate (PET) backsheet) meet the basic technical requirements, more sustainable polyolefin‐based encapsulants and backsheets have been developed. These new polyolefin materials have to prove their performance compared to the established standard materials in terms of the electrical performance of the modules and in terms of reliability. The long‐term stability of the new materials is tested and evaluated using accelerated aging tests and degradation modelling. Based on experimental results, the influence of the type of encapsulant and backsheet (i) on the electrical output power of PV test modules and (ii) on the aging‐related electrical and material degradation under accelerated stress tests was estimated using statistical modelling approaches. First results showing significant effects for encapsulant, backsheet and the combination of both on the initial power output are presented. In general, modules with polypropylene‐based backsheets have a higher initial power (P MPP ) than those with PET‐based backsheets, with the combination of thermoplastic polyolefin (TPO) encapsulation material and polyolefin backsheet being superior to the other material combinations. A comparison of the material‐dependent degradation rates obtained from the mixed‐effects models clearly shows that the degradation rate upon damp heat exposure for modules with EVA is significantly larger than that using polyolefin encapsulants. The derived relations aim to provide valuable input for innovative material developments as well as predictive maintenance specifications.
    Type of Medium: Online Resource
    ISSN: 1062-7995 , 1099-159X
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2023
    detail.hit.zdb_id: 2023295-0
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  • 4
    Online Resource
    Online Resource
    Wiley ; 2013
    In:  Journal of Applied Polymer Science Vol. 127, No. 1 ( 2013-01-05), p. 230-236
    In: Journal of Applied Polymer Science, Wiley, Vol. 127, No. 1 ( 2013-01-05), p. 230-236
    Type of Medium: Online Resource
    ISSN: 0021-8995
    Language: English
    Publisher: Wiley
    Publication Date: 2013
    detail.hit.zdb_id: 1491105-X
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  • 5
    In: Journal of Applied Polymer Science, Wiley, Vol. 132, No. 24 ( 2015-06-20)
    Abstract: In reliability testing of components for PV modules an always remaining question is about material (in)compatibilities and synergistic effects and thus, how results of singly tested materials correlate with materials aged within PV modules. Testing of single materials would simplify sample preparation, reduce costs and offer more testing options. Therefore the main objective of this study was to compare the aging behavior of single backsheets with that of backsheets incorporated within PV modules. Four different types of backsheets were chosen, all of them comprising of polyethylene terephthalate (PET) core layers, but differing outer protection layers. Test modules using identical components, varying only in the type of backsheet used were produced and damp heat aged (85°C/85% RH ≤2000 h). The results revealed no influence of the PV module lamination on the thermal characteristics of the polymeric backsheets. Even after DH aging, differences between single and module laminated backsheets were negligible. Degradation effects of PET could be detected for all aged sheets by thermal analysis and were confirmed by tensile tests and rheological measurements. Thus, it can be stated that testing of single PET based backsheets under DH aging conditions is a practicable way to investigate the applicability of a new backsheet. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132 , 42093.
    Type of Medium: Online Resource
    ISSN: 0021-8995 , 1097-4628
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2015
    detail.hit.zdb_id: 1491105-X
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  • 6
    In: Renewable Energy, Elsevier BV, Vol. 118 ( 2018-04), p. 138-145
    Type of Medium: Online Resource
    ISSN: 0960-1481
    Language: English
    Publisher: Elsevier BV
    Publication Date: 2018
    detail.hit.zdb_id: 2001449-1
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  • 7
    In: Solar Energy Materials and Solar Cells, Elsevier BV, Vol. 203 ( 2019-12), p. 110194-
    Type of Medium: Online Resource
    ISSN: 0927-0248
    Language: English
    Publisher: Elsevier BV
    Publication Date: 2019
    detail.hit.zdb_id: 2012677-3
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  • 8
    In: Progress in Photovoltaics: Research and Applications, Wiley, Vol. 27, No. 11 ( 2019-11), p. 934-949
    Abstract: As the PV market shows enormous potential with huge growth rates especially in climatic‐sensible regions, specific artificial ageing test procedures are a key point for an efficient and fast product development of new PV modules/materials optimized for the use in specific climatic regions. Based on the definition of four climate profiles (dry and hot—arid, moderate, humid, and hot—tropical and high irradiation—alpine), a program was worked out with 14 climate specific test conditions for accelerated ageing tests. The big challenge in this respect was the adaption/advancement of existing standard procedures for PV modules/components testing in a way that reliable testing for certain climatic conditions optimized PV modules is possible. The time‐dependent repeated application of combined climatic and environmental stresses (temperature, temperature cycles, humidity, irradiation, mechanical load, salt mist) was used to induce performance losses, material degradation, and failures in test modules which resemble those effects occurring in real‐life PV installations under comparable climatic and environmental conditions. For this demanding task, a large number of identical test modules with respect to composition and module design was manufactured. A detailed nondestructive analysis/characterization of all modules was performed: (1) before; (2) during (six intermediate stages); and (3) after the accelerated ageing test. The nondestructive characterization methods used to follow the module's ageing processes throughout the whole accelerated ageing procedure were current‐voltage characteristics measurements and electroluminiscence images for the electrical performance evaluation and ultraviolet fluorescence (spectroscopic and imaging) measurements, Fourier transform infrared spectroscopy as well as colour measurements of the backsheets outer layer for recording of chemical changes of the encapsulant and backsheet. The electrical and material characterization data were incorporated in an optimized database. As stated above, a set of three identical modules was exposed together in the respective climate specific ageing tests and subsequently characterized in order to increase statistical reliability of the measuring results. The analysis of the data and first approaches of advanced data treatment have already clearly shown that the electrical and material degradation of the test modules is dependent on (1) the type and combination, (2) duration, and (3) mode (sequential versus constant) of the stresses applied. On the one hand, the simulation of environmental stresses like heavy snow and wind load and enhanced frequency of temperature cycling resulting in cell cracks and cell connector breakage could be demonstrated. Additional treatment in salty atmosphere, on the other hand, did not show an accelerating effect on degradation on the electrical or material side. The accelerating effect of enhanced temperature, humidity, or additional irradiation on the degradation of power and materials could be shown very well. Direct evidence for the formation of acetic acid and lead‐acetate in the encapsulant ethylene vinyl acetate after prolonged damp‐heat exposure could be found and directly related to cell corrosion effects paralleled by power losses.
    Type of Medium: Online Resource
    ISSN: 1062-7995 , 1099-159X
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2019
    detail.hit.zdb_id: 2023295-0
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  • 9
    Online Resource
    Online Resource
    SAGE Publications ; 2013
    In:  Applied Spectroscopy Vol. 67, No. 11 ( 2013-11), p. 1296-1301
    In: Applied Spectroscopy, SAGE Publications, Vol. 67, No. 11 ( 2013-11), p. 1296-1301
    Abstract: Vibrational spectroscopy was found to be a suitable method for the determination of the degree of cross-linking of ethylene vinyl acetate (EVA) polymers. Spectral changes in the Raman spectra of EVA with increasing lamination time (which equals increasing degree of cross-linking) were mainly detected in the CH vibrational regions, namely, in the relative intensities of the characteristic CH 3 and CH 2 bands. These spectral regions were chosen for a chemometric evaluation where a calibration was performed with the Raman spectra of reference EVA samples and the results obtained from corresponding thermal analysis (differential scanning calorimetry) and Soxhlet extraction data. These datasets were subsequently used to non-destructively determine the progress of cross-linking in EVA foils, embedded in various mini-modules by Raman microscopy. Thus, we could show that Raman spectroscopy is a highly interesting method for quality control in the production of photovoltaic (PV) modules. However, this approach is valid only for a given grade of EVA, meaning a demand for a new calibration when changing the supplier or the type of EVA used. In addition, the applicability of infrared spectroscopy for the determination of the degree of cross-linking was tested. A good correlation of the decrease in intensity of the characteristic cross-linker infrared bands with increasing progress of the cross-linking was found, as determined by reference methods. However, this analytical method requires taking samples of the EVA foils and is, thus, unsuitable for the non-destructive determination of the degree of cross-linking of the EVA encapsulated within a PV module.
    Type of Medium: Online Resource
    ISSN: 0003-7028 , 1943-3530
    RVK:
    Language: English
    Publisher: SAGE Publications
    Publication Date: 2013
    detail.hit.zdb_id: 1474251-2
    SSG: 11
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  • 10
    Online Resource
    Online Resource
    SAGE Publications ; 2014
    In:  Applied Spectroscopy Vol. 68, No. 5 ( 2014-05), p. 584-592
    In: Applied Spectroscopy, SAGE Publications, Vol. 68, No. 5 ( 2014-05), p. 584-592
    Abstract: Three different spectroscopic approaches, Raman linescans, Raman imaging, and attenuated total reflection Fourier transform infrared spectroscopy (ATR FT-IR) imaging were evaluated for the visualization of the thin adhesive layers (3–6 μm) present in polymeric photovoltaic backsheets. The cross-sections of the multilayer laminates in the original, weathered, and artificially aged samples were investigated spectroscopically in order to describe the impact of the environmental factors on the evenness and thickness of the adhesive layers. All three methods were found to be suitable tools to detect and visualize these thin layers within the original and aged polymeric laminates. However, as the adhesive layer is not very uniform in thickness and partly disintegrates upon weathering and/or artificial aging, Raman linescans yield only qualitative information and do not allow for an estimation of the layer thickness. Upon increasing the measuring area by moving from one-dimensional linescans to two-dimensional Raman images, a much better result could be achieved. Even though a longer measuring time has to be taken into account, the information on the uniformity and evenness of the adhesive layer obtainable using the imaging technique is much more comprehensive. Although Raman spectroscopy is known to have the superior lateral resolution as compared with ATR FT-IR spectroscopy, the adhesive layers of the samples used within this study (layer thickness 3–6 μm) could also be detected and visualized by applying the ATR FT-IR spectroscopic imaging method. However, the analysis of the images was quite a demanding task, as the thickness of the adhesive layer was in the region of the resolution limit of this method. The information obtained for the impact of artificial aging and weathering on the adhesive layer obtained using Raman imaging and ATR FT-IR imaging was in good accordance.
    Type of Medium: Online Resource
    ISSN: 0003-7028 , 1943-3530
    RVK:
    Language: English
    Publisher: SAGE Publications
    Publication Date: 2014
    detail.hit.zdb_id: 1474251-2
    SSG: 11
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