In:
Journal of Materials Chemistry C, Royal Society of Chemistry (RSC), Vol. 9, No. 32 ( 2021), p. 10288-10294
Abstract:
Cu( i )-based cyclic trinuclear complexes (CTCs) represent one of the most intensively investigated candidates in coinage metal-derived CTCs because of their rich photoluminescence properties. Beyond the molecular level, coordination polymers built upon Cu( i )-based CTCs have developed rapidly in recent times. However, most of the secondary building units (SBUs) on pyrazolyl moieties reported to-date have been centralized on pyrazoles, pyridines and carboxylates and most of the nodes for bridging linkers have been based on copper-halide clusters. This work presents the use of a thioether-functionalized pyrazole to construct Cu( i )-based CTC, 1, which was allowed to react with CuI and BiBr 3 for constructing coordination polymers, 2 and 3, respectively. Successful isolation of 2 and 3 highlights that the thioether pendant on the pyrazole can act as a novel class of SBUs on Cu( i )-based CTCs to assemble coordination polymers with a soft Lewis acid and not limited to copper-halide clusters.
Type of Medium:
Online Resource
ISSN:
2050-7526
,
2050-7534
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2021
detail.hit.zdb_id:
2702245-6
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