In:
Journal of Materials Chemistry A, Royal Society of Chemistry (RSC), Vol. 10, No. 39 ( 2022), p. 21142-21148
Abstract:
The development of single-atom-catalysts (SACs) has been an important goal in catalysis research over the last years. Despite great efforts devoted to new synthetic methods for producing atomically dispersed metal atoms, the practical application of single-atom-catalysts still suffers from very low loading of metal atoms, poor selectivity of atomic dispersion and the instability of single atoms on the surface. Here, we show that atomically dispersed Fe atoms on non-defective VS 2 are stable at temperatures well above room temperature and remain generally mono-dispersed due to strong Fe–Fe repulsion and high diffusion barriers. Theoretically, the coverage of Fe 1 sites may exceed 11.1%. Subsequently, we demonstrate catalytic activity of this Fe 1 /VS 2 catalyst with the electrochemical N 2 reduction reaction (NRR). Our calculations show that the Fe 1 /VS 2 catalyst exhibits outstanding catalytic activity for N 2 fixation at room temperature through a hybrid mechanism, with a low overpotential of 0.35 V. This work should provide some insights and guidance for the design of scalable single metal catalysts on non-defective supports in the future.
Type of Medium:
Online Resource
ISSN:
2050-7488
,
2050-7496
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2022
detail.hit.zdb_id:
2702232-8
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