In:
Zeitschrift für Naturforschung A, Walter de Gruyter GmbH, Vol. 48, No. 4 ( 1993-4-1), p. 563-569
Abstract:
A detailed proton second moment and spin-lattice relaxation time investigation of the bilayered compound (C 10 H 21 NH 3 ) 2 CdCl 4 is reported. In the low temperature phase the methyl group exe-cutes a classical threefold reorientation, while the NH 3 group is involved in a similar reorientation in an asymmetric potential well. Evidence for defect chain motions in this phase has been found, and infomation regarding the potential wells associated with these motions has been extracted from the data. In the high temperature phase, slow chain defect motions and fast fourfold reorientations of chains about their long axes, parallel to the normal to the bilayer, have been observed.
Type of Medium:
Online Resource
ISSN:
1865-7109
,
0932-0784
DOI:
10.1515/zna-1993-0405
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
1993
detail.hit.zdb_id:
2079610-9
detail.hit.zdb_id:
124634-3
detail.hit.zdb_id:
124633-1
detail.hit.zdb_id:
2767412-5
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