In:
Acta Crystallographica Section E Structure Reports Online, International Union of Crystallography (IUCr), Vol. 70, No. 2 ( 2014-02-01), p. m39-m40
Abstract:
In the title compound, [Ru 2 (C 10 H 14 ) 2 Cl 2 (C 16 H 8 N 4 )](PF 6 ) 2 ·2C 3 H 6 O, the binuclear Ru II complex dication, [{RuCl(η 6 -cym)} 2 (μ-tape)] 2+ , built up by a planar 1,6,7,12-tetraazaperylene (tape) bridge, two η 6 -bound cymene (cym) ligands and two chloride ligands, includes an inversion center. The Ru II atom shows the typical piano-stool motif for arene coordination. The counter-charge is provided by a hexafluoridophosphate anion and the asymmetric unit is completed by an acetone molecule of crystallization. The components of the structure are connected into a three-dimensional architecture by C—H...O/F/Cl interactions.
Type of Medium:
Online Resource
ISSN:
1600-5368
DOI:
10.1107/S160053681400035X
DOI:
10.1107/S160053681400035X/tk5277sup1.cif
DOI:
10.1107/S160053681400035X/tk5277Isup2.hkl
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2014
detail.hit.zdb_id:
2843762-7
detail.hit.zdb_id:
2041947-8
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