In:
Zeitschrift für Kristallographie - Crystalline Materials, Walter de Gruyter GmbH, Vol. 220, No. 7 ( 2005-7-1), p. 622-625
Abstract:
The synthesis, molecular and crystal structure of ( n BuSn) 9 (V V O) 3 O 14 (OH) 6 Cl 2 (dmso) 2 · 3 DMSO ( 1 ) are described. The yellow compound crystallizes in the monoclinic space group P 2(1)/ n (No. 14) with a = 17.961(5) Å, b = 19.222(4) Å, c = 26.748(6) Å, β = 106.776(2)°, V = 8842(4) Å 3 , Z = 4. The neutral monoorganotin-polyoxo-vanadium molecule ( n BuSn) 9 (V V O) 3 O 14 (OH) 6 Cl 2 × (dmso) 2 ( 1a ) shows the same distorted icosahedral arrangement of the metal atoms and a very similar metal-oxygen framework as the well known [( i PrSn) 12 O 14 (OH) 6 ] 2+ ion ( 2 ) from which it can be derived formally by substitution of three square pyramidally coordinated {RSnO 4 } groups by three {OVO 4 } groups of the same geometry. In addition, two further {RSnO 4 } groups are replaced by two octahedral {RSnO 3 Cl(dmso)} units.
Type of Medium:
Online Resource
ISSN:
2196-7105
,
2194-4946
DOI:
10.1524/zkri.220.7.622.67107
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
2005
SSG:
13
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