In:
Journal of The Electrochemical Society, The Electrochemical Society, Vol. 167, No. 9 ( 2020-01-07), p. 090551-
Abstract:
The initial capacity and cycle retention properties of all-solid lithium batteries (ASLBs) were greatly improved by utilizing polyethylene oxide (PEO)/lithium salts in conjunction with LiFSi, and coating the nickel manganese cobalt oxide (NCM) cathode component with lithium manganese oxide (LMO). That is, composite cathodes for ASLBs were fabricated by using lithium salts (LiClO 4 /LiFSi (8:2)) with PEO, Al-LLZO powder, Super-P, and LMO-coated NCM-424/622, respectively (Al-LLZO = Li 6.25 Al 0.25 La 3 Zr 2 O 12 ). LiFSi was added to a solution of PEO/LiClO 4 ([EO]:[Li] = 13:1) to generate a composite cathode and composite solid electrolyte (CSE) sheet. The initial capacity and cycle retention of the resulting cells were improved by controlling the side reactions and the improving kinetic characteristics. Moreover, NCM-424 and NCM-622 were coated with LMO; the optimum LMO coating amount (1 wt%) and NCM-424/622 ratio (9:1) for simultaneously improving the capacity and cycle retention were explored. Overall, the initial capacity of the ASLBs reached 152 mAh g −1 , with a capacity retention rate of 92% at the 100th cycle.
Type of Medium:
Online Resource
ISSN:
0013-4651
,
1945-7111
DOI:
10.1149/1945-7111/ab9a06
Language:
Unknown
Publisher:
The Electrochemical Society
Publication Date:
2020
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