In:
Acta Crystallographica Section E Crystallographic Communications, International Union of Crystallography (IUCr), Vol. 71, No. 12 ( 2015-12-01), p. o1061-o1062
Abstract:
The reaction of the orthoamide 1,1,1-tris(dimethylamino)-4-methyl-4-(trimethylsilyloxy)pent-2-yne with bromine in benzene, yields the title salt, C 15 H 33 BrN 3 OSi + ·Br − . The C—N bond lengths in the amidinium unit are 1.319 (6) and 1.333 (6) Å, indicating double-bond character, pointing towards charge delocalization within the NCN plane. The C—Br bond length of 1.926 (5) Å is characteristic for a C—Br single bond. Additionally, there is a bromine–bromine interaction [3.229 (3) Å] present involving the anion and cation. In the crystal, weak C—H...Br interactions between the methyl H atoms of the cation and the bromide ions are present.
Type of Medium:
Online Resource
ISSN:
2056-9890
DOI:
10.1107/S205698901502383X
DOI:
10.1107/S205698901502383X/ff2146sup1.cif
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2015
detail.hit.zdb_id:
2843762-7
detail.hit.zdb_id:
2041947-8
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