In:
Journal of Porphyrins and Phthalocyanines, World Scientific Pub Co Pte Ltd, Vol. 17, No. 01n02 ( 2013-01), p. 92-98
Abstract:
Zinc 5-(4-carboxy-phenylethynyl)-10,20-biphenylporphines bearing various substituents on the 10,20-phenyl rings are studied for their electrochemical and spectroelectrochemical properties. Cyclic voltammetry and optically transparent thin-layer electrochemical measurements suggest that the first reductions of these porphyrins should be the reduction reaction of the carboxylic protons. For the porphyrin ring reactions, our study shows that the redox properties can be significantly affected by the alkoxyl chains on the 10,20-phenyl rings.
Type of Medium:
Online Resource
ISSN:
1088-4246
,
1099-1409
DOI:
10.1142/S1088424612501313
Language:
English
Publisher:
World Scientific Pub Co Pte Ltd
Publication Date:
2013
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