In:
Asian Journal of Organic Chemistry, Wiley, Vol. 7, No. 12 ( 2018-12), p. 2504-2510
Abstract:
Total synthesis of the revised cryptorigidifoliol K and 2′‐ epi ‐cryptorigidifoliol K was accomplished. Salient features of the synthesis involve tandem isomerization followed by C−O and C−C bond forming reaction, iodolactonization and Nozaki‐Hiyama‐Kishi reaction. The synthesis allowed for confirmation of the structure as well as the elucidation of the unassigned stereocenter present in the side chain of the revised structure by correlating the spectral and analytical data of the synthetic cryptorigidifoliol K and 2′‐ epi ‐cryptorigidifoliol K with the natural product data, which was found to be 1 S ,5 R ,7 S ,2′ R ,3′ E .
Type of Medium:
Online Resource
ISSN:
2193-5807
,
2193-5815
DOI:
10.1002/ajoc.201800522
Language:
English
Publisher:
Wiley
Publication Date:
2018
detail.hit.zdb_id:
2679333-7
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