In:
Acta Crystallographica Section C Structural Chemistry, International Union of Crystallography (IUCr), Vol. 76, No. 10 ( 2020-10-01), p. 947-951
Abstract:
First reported in 1930, MoCl 3 O(Et 2 O) 2 is a by-product of the reductive synthesis of MoCl 4 (OEt 2 ) 2 from MoCl 5 . We report herein the X-ray crystal structure and Hirshfeld surface characteristics of mer -MoCl 3 O(Et 2 O) 2 , or [MoCl 3 O(C 4 H 10 O) 2 ]. The compound crystallizes in the orthorhombic space group P 2 1 2 1 2 1 . The molybdenyl (Mo=O) bond length is 1.694 (3) Å and the cis - and trans -Mo—O distances are 2.157 (3) and 2.304 (3) Å, respectively. Intermolecular Mo=O...H bonding is present in the lattice, with the shortest distance being 2.572 Å.
Type of Medium:
Online Resource
ISSN:
2053-2296
DOI:
10.1107/S2053229620011626
DOI:
10.1107/S2053229620011626/ef3009sup1.cif
DOI:
10.1107/S2053229620011626/ef3009Isup2.hkl
DOI:
10.1107/S2053229620011626/ef3009sup3.pdf
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2020
detail.hit.zdb_id:
2025703-X
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