In:
Angewandte Chemie, Wiley, Vol. 129, No. 27 ( 2017-06-26), p. 8052-8055
Abstract:
Low‐temperature UV‐photolysis of mesitylphosphiranes under highly anaerobic conditions leads to the formation of the triplet mesitylphosphinidene (MesP). The recorded X‐band EPR spectrum of triplet MesP and the derived zero‐field splitting parameter D =4.116 cm −1 differ significantly from those reported previously for this intermediate. New magnetic parameters of mesitylphosphinidene are discussed along with the results of DFT calculations.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v129.27
DOI:
10.1002/ange.201703629
Language:
English
Publisher:
Wiley
Publication Date:
2017
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