In:
Angewandte Chemie, Wiley, Vol. 130, No. 39 ( 2018-09-24), p. 13047-13050
Abstract:
Intermolecular, stepwise functionalization by BH bonds of a (triphosphine)Mo IV –nitrido complex generated by N 2 splitting is reported. The imido–hydride and di‐hydride–amido Mo IV complexes have been isolated and characterized. Addition of PinBH to the [Mo(H) 2 (N(BPin) 2 )] + complex at room temperature results in the liberation of borylamines from the metal center.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v130.39
DOI:
10.1002/ange.201805915
Language:
English
Publisher:
Wiley
Publication Date:
2018
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