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  • 1
    Online Resource
    Online Resource
    American Geophysical Union (AGU) ; 2017
    In:  Geophysical Research Letters Vol. 44, No. 8 ( 2017-04-28), p. 3858-3866
    In: Geophysical Research Letters, American Geophysical Union (AGU), Vol. 44, No. 8 ( 2017-04-28), p. 3858-3866
    Abstract: The representation of ozone in climate change simulations can lead to major differences in projected ENSO amplitudes Mechanistically, this effect is directly related to an ozone‐induced damping of the Walker circulation response to CO 2 forcing ENSO modeling studies with climatologically inconsistent ozone might be missing an important mechanism
    Type of Medium: Online Resource
    ISSN: 0094-8276 , 1944-8007
    URL: Issue
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2017
    detail.hit.zdb_id: 2021599-X
    detail.hit.zdb_id: 7403-2
    SSG: 16,13
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  • 2
    Online Resource
    Online Resource
    American Geophysical Union (AGU) ; 2023
    In:  Geophysical Research Letters Vol. 50, No. 9 ( 2023-05-16)
    In: Geophysical Research Letters, American Geophysical Union (AGU), Vol. 50, No. 9 ( 2023-05-16)
    Abstract: Future emission pathways driven by climate actions are projected to alleviate surface ozone pollution in most parts of China by 2030 However, for China's three main city clusters, model projections disagree strongly for two widely used chemical mechanisms This modeling uncertainty may arise from the inconsistency of categorizing ozone chemical regimes by different chemical mechanisms
    Type of Medium: Online Resource
    ISSN: 0094-8276 , 1944-8007
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2023
    detail.hit.zdb_id: 2021599-X
    detail.hit.zdb_id: 7403-2
    SSG: 16,13
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  • 3
    Online Resource
    Online Resource
    Springer Science and Business Media LLC ; 2023
    In:  Nature Geoscience Vol. 16, No. 7 ( 2023-07), p. 577-583
    In: Nature Geoscience, Springer Science and Business Media LLC, Vol. 16, No. 7 ( 2023-07), p. 577-583
    Abstract: Future increases in stratospheric water vapour risk amplifying climate change and slowing down the recovery of the ozone layer. However, state-of-the-art climate models strongly disagree on the magnitude of these increases under global warming. Uncertainty primarily arises from the complex processes leading to dehydration of air during its tropical ascent into the stratosphere. Here we derive an observational constraint on this longstanding uncertainty. We use a statistical-learning approach to infer historical co-variations between the atmospheric temperature structure and tropical lower stratospheric water vapour concentrations. For climate models, we demonstrate that these historically constrained relationships are highly predictive of the water vapour response to increased atmospheric carbon dioxide. We obtain an observationally constrained range for stratospheric water vapour changes per degree of global warming of 0.31 ± 0.39 ppmv K −1 . Across 61 climate models, we find that a large fraction of future model projections are inconsistent with observational evidence. In particular, frequently projected strong increases ( 〉 1 ppmv K −1 ) are highly unlikely. Our constraint represents a 50% decrease in the 95th percentile of the climate model uncertainty distribution, which has implications for surface warming, ozone recovery and the tropospheric circulation response under climate change.
    Type of Medium: Online Resource
    ISSN: 1752-0894 , 1752-0908
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2023
    detail.hit.zdb_id: 2396648-8
    detail.hit.zdb_id: 2405323-5
    SSG: 16,13
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  • 4
    Online Resource
    Online Resource
    Copernicus GmbH ; 2016
    In:  Atmospheric Chemistry and Physics Vol. 16, No. 6 ( 2016-03-31), p. 4191-4203
    In: Atmospheric Chemistry and Physics, Copernicus GmbH, Vol. 16, No. 6 ( 2016-03-31), p. 4191-4203
    Abstract: Abstract. Various forms of geoengineering have been proposed to counter anthropogenic climate change. Methods which aim to modify the Earth's energy balance by reducing insolation are often subsumed under the term solar radiation management (SRM). Here, we present results of a standard SRM modelling experiment in which the incoming solar irradiance is reduced to offset the global mean warming induced by a quadrupling of atmospheric carbon dioxide. For the first time in an atmosphere–ocean coupled climate model, we include atmospheric composition feedbacks for this experiment. While the SRM scheme considered here could offset greenhouse gas induced global mean surface warming, it leads to important changes in atmospheric composition. We find large stratospheric ozone increases that induce significant reductions in surface UV-B irradiance, which would have implications for vitamin D production. In addition, the higher stratospheric ozone levels lead to decreased ozone photolysis in the troposphere. In combination with lower atmospheric specific humidity under SRM, this results in overall surface ozone concentration increases in the idealized G1 experiment. Both UV-B and surface ozone changes are important for human health. We therefore highlight that both stratospheric and tropospheric ozone changes must be considered in the assessment of any SRM scheme, due to their important roles in regulating UV exposure and air quality.
    Type of Medium: Online Resource
    ISSN: 1680-7324
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2016
    detail.hit.zdb_id: 2092549-9
    detail.hit.zdb_id: 2069847-1
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  • 5
    In: Biogeosciences, Copernicus GmbH, Vol. 18, No. 12 ( 2021-06-29), p. 3861-3879
    Abstract: Abstract. The seasonal and longer-term dynamics of fuel accumulation affect fire seasonality and the occurrence of extreme wildfires. Failure to account for their influence may help to explain why state-of-the-art fire models do not simulate the length and timing of the fire season or interannual variability in burnt area well. We investigated the impact of accounting for different timescales of fuel production and accumulation on burnt area using a suite of random forest regression models that included the immediate impact of climate, vegetation, and human influences in a given month and tested the impact of various combinations of antecedent conditions in four productivity-related vegetation indices and in antecedent moisture conditions. Analyses were conducted for the period from 2010 to 2015 inclusive. Inclusion of antecedent vegetation conditions representing fuel build-up led to an improvement of the global, climatological out-of-sample R2 from 0.579 to 0.701, but the inclusion of antecedent vegetation conditions on timescales ≥ 1 year had no impact on simulated burnt area. Current moisture levels were the dominant influence on fuel drying. Additionally, antecedent moisture levels were important for fuel build-up. The models also enabled the visualisation of interactions between variables, such as the importance of antecedent productivity coupled with instantaneous drying. The length of the period which needs to be considered varies across biomes; fuel-limited regions are sensitive to antecedent conditions that determine fuel build-up over longer time periods (∼ 4 months), while moisture-limited regions are more sensitive to current conditions that regulate fuel drying.
    Type of Medium: Online Resource
    ISSN: 1726-4189
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2021
    detail.hit.zdb_id: 2158181-2
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  • 6
    In: Atmospheric Chemistry and Physics, Copernicus GmbH, Vol. 21, No. 6 ( 2021-03-31), p. 5015-5061
    Abstract: Abstract. Stratospheric ozone and water vapour are key components of the Earth system, and past and future changes to both have important impacts on global and regional climate. Here, we evaluate long-term changes in these species from the pre-industrial period (1850) to the end of the 21st century in Coupled Model Intercomparison Project phase 6 (CMIP6) models under a range of future emissions scenarios. There is good agreement between the CMIP multi-model mean and observations for total column ozone (TCO), although there is substantial variation between the individual CMIP6 models. For the CMIP6 multi-model mean, global mean TCO has increased from ∼ 300 DU in 1850 to ∼ 305 DU in 1960, before rapidly declining in the 1970s and 1980s following the use and emission of halogenated ozone-depleting substances (ODSs). TCO is projected to return to 1960s values by the middle of the 21st century under the SSP2-4.5, SSP3-7.0, SSP4-3.4, SSP4-6.0, and SSP5-8.5 scenarios, and under the SSP3-7.0 and SSP5-8.5 scenarios TCO values are projected to be ∼ 10 DU higher than the 1960s values by 2100. However, under the SSP1-1.9 and SSP1-1.6 scenarios, TCO is not projected to return to the 1960s values despite reductions in halogenated ODSs due to decreases in tropospheric ozone mixing ratios. This global pattern is similar to regional patterns, except in the tropics where TCO under most scenarios is not projected to return to 1960s values, either through reductions in tropospheric ozone under SSP1-1.9 and SSP1-2.6, or through reductions in lower stratospheric ozone resulting from an acceleration of the Brewer–Dobson circulation under other Shared Socioeconomic Pathways (SSPs). In contrast to TCO, there is poorer agreement between the CMIP6 multi-model mean and observed lower stratospheric water vapour mixing ratios, with the CMIP6 multi-model mean underestimating observed water vapour mixing ratios by ∼ 0.5 ppmv at 70 hPa. CMIP6 multi-model mean stratospheric water vapour mixing ratios in the tropical lower stratosphere have increased by ∼ 0.5 ppmv from the pre-industrial to the present-day period and are projected to increase further by the end of the 21st century. The largest increases (∼ 2 ppmv) are simulated under the future scenarios with the highest assumed forcing pathway (e.g. SSP5-8.5). Tropical lower stratospheric water vapour, and to a lesser extent TCO, shows large variations following explosive volcanic eruptions.
    Type of Medium: Online Resource
    ISSN: 1680-7324
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2021
    detail.hit.zdb_id: 2092549-9
    detail.hit.zdb_id: 2069847-1
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  • 7
    Online Resource
    Online Resource
    Copernicus GmbH ; 2020
    In:  Atmospheric Chemistry and Physics Vol. 20, No. 23 ( 2020-12-11), p. 15461-15485
    In: Atmospheric Chemistry and Physics, Copernicus GmbH, Vol. 20, No. 23 ( 2020-12-11), p. 15461-15485
    Abstract: Abstract. Many modelling studies suggest that the El Niño–Southern Oscillation (ENSO), in interaction with the tropical Pacific background climate, will change with rising atmospheric greenhouse gas concentrations. Solar geoengineering (reducing the solar flux from outer space) has been proposed as a means to counteract anthropogenic climate change. However, the effectiveness of solar geoengineering concerning a variety of aspects of Earth's climate is uncertain. Robust results are particularly challenging to obtain for ENSO because existing geoengineering simulations are too short (typically ∼ 50 years) to detect statistically significant changes in the highly variable tropical Pacific background climate. We here present results from a 1000-year-long solar-geoengineering simulation, G1, carried out with the coupled atmosphere–ocean general circulation model HadCM3L. In agreement with previous studies, reducing the solar irradiance (4 %) to offset global mean surface warming in the model more than compensates the warming in the tropical Pacific that develops in the 4 × CO2 scenario. We see an overcooling of 0.3 ∘C and a 0.23 mm d−1 (5 %) reduction in mean rainfall over the tropical Pacific relative to preindustrial conditions in the G1 simulation, owing to the different latitudinal distributions of the shortwave (solar) and longwave (CO2) forcings. The location of the Intertropical Convergence Zone (ITCZ) in the tropical Pacific, which moved 7.5∘ southwards under 4 × CO2, is restored to its preindustrial position. However, other aspects of the tropical Pacific mean climate are not reset as effectively. Relative to preindustrial conditions, in G1 the time-averaged zonal wind stress, zonal sea surface temperature (SST) gradient, and meridional SST gradient are each statistically significantly reduced by around 10 %, and the Pacific Walker Circulation (PWC) is consistently weakened, resulting in conditions conducive to increased frequency of El Niño events. The overall amplitude of ENSO strengthens by 9 %–10 % in G1, but there is a 65 % reduction in the asymmetry between cold and warm events: cold events intensify more than warm events. Notably, the frequency of extreme El Niño and La Niña events increases by ca. 60 % and 30 %, respectively, while the total number of El Niño events increases by around 10 %. All of these changes are statistically significant at either 95 or 99 % confidence level. Somewhat paradoxically, while the number of total and extreme events increases, the extreme El Niño events become weaker relative to the preindustrial state, while the extreme La Niña events become even stronger. That is, such extreme El Niño events in G1 become less intense than under preindustrial conditions but also more frequent. In contrast, extreme La Niña events become stronger in G1, which is in agreement with the general overcooling of the tropical Pacific in G1 relative to preindustrial conditions.
    Type of Medium: Online Resource
    ISSN: 1680-7324
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2020
    detail.hit.zdb_id: 2092549-9
    detail.hit.zdb_id: 2069847-1
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  • 8
    In: Nature Communications, Springer Science and Business Media LLC, Vol. 10, No. 1 ( 2019-05-09)
    Abstract: Charge transport in conjugated polymer semiconductors has traditionally been thought to be limited to a low-mobility regime by pronounced energetic disorder. Much progress has recently been made in advancing carrier mobilities in field-effect transistors through developing low-disorder conjugated polymers. However, in diodes these polymers have to date not shown much improved mobilities, presumably reflecting the fact that in diodes lower carrier concentrations are available to fill up residual tail states in the density of states. Here, we show that the bulk charge transport in low-disorder polymers is limited by water-induced trap states and that their concentration can be dramatically reduced through incorporating small molecular additives into the polymer film. Upon incorporation of the additives we achieve space-charge limited current characteristics that resemble molecular single crystals such as rubrene with high, trap-free SCLC mobilities up to 0.2 cm 2 /Vs and a width of the residual tail state distribution comparable to k B T .
    Type of Medium: Online Resource
    ISSN: 2041-1723
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2019
    detail.hit.zdb_id: 2553671-0
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  • 9
    In: Atmospheric Chemistry and Physics, Copernicus GmbH, Vol. 23, No. 18 ( 2023-09-28), p. 10775-10794
    Abstract: Abstract. The radiative effects of clouds make a large contribution to the Earth's energy balance, and changes in clouds constitute the dominant source of uncertainty in the global warming response to carbon dioxide forcing. To characterize and constrain this uncertainty, cloud-controlling factor (CCF) analyses have been suggested that estimate sensitivities of clouds to large-scale environmental changes, typically in cloud-regime-specific multiple linear regression frameworks. Here, local sensitivities of cloud radiative effects to a large number of controlling factors are estimated in a regime-independent framework from 20 years (2001–2020) of near-global (60∘ N–60∘ S) satellite observations and reanalysis data using statistical learning. A regularized linear regression (ridge regression) is shown to skillfully predict anomalies of shortwave (R2=0.63) and longwave cloud radiative effects (CREs) (R2=0.72) in independent test data on the basis of 28 CCFs, including aerosol proxies. The sensitivity of CREs to selected CCFs is quantified and analyzed. CRE sensitivities to sea surface temperature and estimated inversion strength are particularly pronounced in low-cloud regions and generally in agreement with previous studies. The analysis of CRE sensitivities to three-dimensional wind field anomalies reflects the fact that CREs in tropical ascent regions are mainly driven by variability of large-scale vertical velocity in the upper troposphere. In the subtropics, CRE is sensitive to free-tropospheric zonal and meridional wind anomalies, which are likely to encapsulate information on synoptic variability that influences subtropical cloud systems by modifying wind shear and thus turbulence and dry-air entrainment in stratocumulus clouds, as well as variability related to midlatitude cyclones. Different proxies for aerosols are analyzed as CCFs, with satellite-derived aerosol proxies showing a larger CRE sensitivity than a proxy from an aerosol reanalysis, likely pointing to satellite aerosol retrieval biases close to clouds, leading to overestimated aerosol sensitivities. Sensitivities of shortwave CREs to all aerosol proxies indicate a pronounced cooling effect from aerosols in stratocumulus regions that is counteracted to a varying degree by a longwave warming effect. The analysis may guide the selection of CCFs in future sensitivity analyses aimed at constraining cloud feedback and climate forcings from aerosol–cloud interactions using data from both observations and global climate models.
    Type of Medium: Online Resource
    ISSN: 1680-7324
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2023
    detail.hit.zdb_id: 2092549-9
    detail.hit.zdb_id: 2069847-1
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  • 10
    Online Resource
    Online Resource
    American Geophysical Union (AGU) ; 2018
    In:  Journal of Geophysical Research: Atmospheres Vol. 123, No. 9 ( 2018-05-16), p. 4630-4641
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 123, No. 9 ( 2018-05-16), p. 4630-4641
    Abstract: The impacts of different ozone representations in climate sensitivity simulations are assessed with HadGEM3‐AO We find significant impacts on global warming and other composition‐climate feedbacks, such as the stratospheric water vapor feedback Our results imply that some ozone implementations in climate sensitivity simulations need to be reconsidered
    Type of Medium: Online Resource
    ISSN: 2169-897X , 2169-8996
    URL: Issue
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2018
    detail.hit.zdb_id: 710256-2
    detail.hit.zdb_id: 2016800-7
    detail.hit.zdb_id: 2969341-X
    SSG: 16,13
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