In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2007, No. 33 ( 2007-11), p. 5173-5176
Abstract:
A one‐pot synthesis of the new enantiopure heteroscorpionate ligand HOPhbpm 3cam ( 3 ) was described. Ligand 3 was obtained in a pyridine‐catalysed Peterson rearrangement starting from camphorpyrazole, thionyl chloride, and salicylaldehyde. κ 2 ‐ and κ 3 ‐coordination of the ligand was observed, and the ligand was shown to form a tetrahedral zinc complex [Zn‐κ 3 ‐(OPhbpm 3cam )CH 3 ] ( 4 ) as well as an octahedral rhenium complex [Re‐κ 3 ‐(OPhbpm 3cam )(CO) 3 ] ( 6 ). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2007:33
DOI:
10.1002/ejic.200700827
Language:
English
Publisher:
Wiley
Publication Date:
2007
detail.hit.zdb_id:
1475009-0
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