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  • 1
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 106, No. D23 ( 2001-12-16), p. 32481-32501
    Abstract: Eighteen long‐range flights over the Pacific Ocean between 38°S to 20°N and 166°E to 90°W were made by the NASA DC‐8 aircraft during the NASA Pacific Exploratory Mission (PEM) Tropics B conducted from March 6 to April 18, 1999. Two lidar systems were flown on the DC‐8 to remotely measure vertical profiles of ozone (O 3 ), water vapor (H 2 O), aerosols, and clouds from near the surface to the upper troposphere along their flight track. In situ measurements of a wide range of gases and aerosols were made on the DC‐8 for comprehensive characterization of the air and for correlation with the lidar remote measurements. The transition from northeasterly flow of Northern Hemispheric (NH) air on the northern side of the Intertropical Convergence Zone (ITCZ) to generally easterly flow of Southern Hemispheric (SH) air south of the ITCZ was accompanied by a significant decrease in O 3 , carbon monoxide, hydrocarbons, and aerosols and an increase in H 2 O. Trajectory analyses indicate that air north of the ITCZ came from Asia and/or the United States, while the air south of the ITCZ had a long residence time over the Pacific, perhaps originating over South America several weeks earlier. Air south of the South Pacific Convergence Zone (SPCZ) came rapidly from the west originating over Australia or Africa. This air had enhanced O 3 and aerosols and an associated decrease in H 2 O. Average latitudinal and longitudinal distributions of O 3 and H 2 O were constructed from the remote and in situ O 3 and H 2 O data, and these distributions are compared with results from PEM‐Tropics A conducted in August‐October 1996. During PEM‐Tropics B, low O 3 air was found in the SH across the entire Pacific Basin at low latitudes. This was in strong contrast to the photochemically enhanced O 3 levels found across the central and eastern Pacific low latitudes during PEM‐Tropics A. Nine air mass types were identified for PEM‐Tropics B based on their O 3 , aerosols, clouds, and potential vorticity characteristics. The data from each flight were binned by altitude according to air mass type, and these results showed the relative observational frequency of the different air masses as a function of altitude in seven regions over the Pacific. The average chemical composition of the major air mass types was determined from in situ measurements in the NH and SH, and these results provided insight into the origin, lifetime, and chemistry of the air in these regions.
    Type of Medium: Online Resource
    ISSN: 0148-0227
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2001
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  • 2
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 106, No. D23 ( 2001-12-16), p. 32591-32607
    Abstract: Analysis of chemical transport on Flight 10 of the 1999 Pacific Exploratory Mission (PEM) Tropics B mission clarifies the role of the South Pacific Convergence Zone (SPCZ) in establishing ozone and other trace gas distributions in the southwestern tropical Pacific. The SPCZ is found to be a barrier to mixing in the lower troposphere but a mechanism for convective mixing of tropical boundary layer air from northeast of the SPCZ with upper tropospheric air arriving from the west. A two‐dimensional cloud‐resolving model is used to quantify three critical processes in global and regional transport: convective mixing, lightning NO x production, and wet scavenging of soluble species. Very low NO and O 3 tropical boundary layer air from the northeastern side of the SPCZ entered the convective updrafts and was transported to the upper troposphere where it mixed with subtropical upper tropospheric air containing much larger NO and O 3 mixing ratios that had arrived from Australia. Aircraft observations show that very little NO appears to have been produced by electrical discharges within the SPCZ convection. We estimate that at least 90% of the HNO 3 and H 2 O 2 that would have been in upper tropospheric cloud outflow had been removed during transport through the cloud. Lesser percentages are estimated for less soluble species (e.g., 〈 50% for CH 3 OOH). Net ozone production rates were decreased in the upper troposphere by ∼60% due to the upward transport and outflow of low‐NO boundary layer air. However, this outflow mixed with much higher NO air parcels on the southwest edge of the cloud, and the mixture ultimately possessed a net ozone production potential intermediate between those of the air masses on either side of the SPCZ.
    Type of Medium: Online Resource
    ISSN: 0148-0227
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2001
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  • 3
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 106, No. D23 ( 2001-12-16), p. 32733-32747
    Abstract: Observations over the tropical Pacific during the Pacific Exploratory Mission (PEM)‐Tropics B experiment (March‐April 1999) are analyzed. Concentrations of CO and long‐lived nonmethane hydrocarbons in the region are significantly enhanced due to transport of pollutants from northern industrial continents. This pollutant import also enhances moderately O 3 concentrations but not NO x concentrations. It therefore tends to depress OH concentrations over the tropical Pacific. These effects contrast to the large enhancements of O 3 and NO x concentrations and the moderate increase of OH concentrations due to biomass burning outflow during the PEM‐Tropics A experiment (September‐October 1996). Observed CH 3 I concentrations, as in PEM‐Tropics A, indicate that convective mass outflux in the middle and upper troposphere is largely independent of altitude over the tropical Pacific. Constraining a one‐dimensional model with CH 3 I observations yields a 10‐day timescale for convective turnover of the free troposphere, a factor of 2 faster than during PEM‐Tropics A. Model simulated HO 2 , CH 2 O, H 2 O 2 , and CH 3 OOH concentrations are generally in agreement with observations. However, simulated OH concentrations are lower (∼25%) than observations above 6 km. Whereas models tend to overestimate previous field measurements, simulated HNO 3 concentrations during PEM‐Tropics B are too low (a factor of 2–4 below 6 km) compared to observations. Budget analyses indicate that chemical production of O 3 accounts for only 50% of chemical loss; significant transport of O 3 into the region appears to take place within the tropics. Convective transport Of CH 3 OOH enhances the production of HO x and O 3 in the upper troposphere, but this effect is offset by HO x loss due to the scavenging of H 2 O 2 . Convective transport and scavenging of reactive nitrogen species imply a necessary source of 0.4–1 Tg yr −1 of NO x in the free troposphere (above 4 km) over the tropics. A large fraction of the source could be from marine lightning. Oxidation of DMS transported by convection from the boundary layer could explain the observed free tropospheric SO 2 concentrations over the tropical Pacific. This source of DMS due to convection, however, would imply in the model free tropospheric concentrations much higher than observed. The model overestimate cannot be reconciled using recent kinetics measurements of the DMS‐OH adduct reaction at low pressures and temperatures and may reflect enhanced OH oxidation of DMS during convection.
    Type of Medium: Online Resource
    ISSN: 0148-0227
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2001
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  • 4
    Online Resource
    Online Resource
    American Geophysical Union (AGU) ; 2001
    In:  Journal of Geophysical Research: Atmospheres Vol. 106, No. D23 ( 2001-12-16), p. 32527-32538
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 106, No. D23 ( 2001-12-16), p. 32527-32538
    Abstract: In this paper we analyze distinct layers seen in the tropospheric ozone and water vapor profiles taken during NASA's Global Tropospheric Experiment (GTE) Pacific Exploratory Mission in the Tropical Pacific (PEM‐Tropics) Phase B campaign. In summary, fewer layers were observed in this campaign than during the PEM‐Tropics A campaign. However, of those layers found, there were relatively more ozone‐rich‐water‐vapor‐poor layers (68% versus 52%). The percentage of the sampled troposphere occupied by layers during PEM‐Tropics B was less than half of that found during PEM‐Tropics A (8% versus 20%). The differences between these two campaigns suggest a seasonal variation in the occurrence of layers. This is confirmed using measurements made by the Southern Hemisphere Additional Ozonesondes (SHADOZ) network.
    Type of Medium: Online Resource
    ISSN: 0148-0227
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2001
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  • 5
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 112, No. D10 ( 2007-05-27)
    Abstract: The sensitivity of regional air quality model to various lateral and top boundary conditions is studied at 2 scales: a 60 km domain covering the whole USA and a 12 km domain over northeastern USA. Three global models (MOZART‐NCAR, MOZART‐GFDL and RAQMS) are used to drive the STEM‐2K3 regional model with time‐varied lateral and top boundary conditions (BCs). The regional simulations with different global BCs are examined using ICARTT aircraft measurements performed in the summer of 2004, and the simulations are shown to be sensitive to the boundary conditions from the global models, especially for relatively long‐lived species, like CO and O 3 . Differences in the mean CO concentrations from three different global‐model boundary conditions are as large as 40 ppbv, and the effects of the BCs on CO are shown to be important throughout the troposphere, even near surface. Top boundary conditions show strong effect on O 3 predictions above 4 km. Over certain model grids, the model's sensitivity to BCs is found to depend not only on the distance from the domain's top and lateral boundaries, downwind/upwind situation, but also on regional emissions and species properties. The near‐surface prediction over polluted area is usually not as sensitive to the variation of BCs, but to the magnitude of their background concentrations. We also test the sensitivity of model to temporal and spatial variations of the BCs by comparing the simulations with time‐varied BCs to the corresponding simulations with time‐mean and profile BCs. Removing the time variation of BCs leads to a significant bias on the variation prediction and sometime causes the bias in predicted mean values. The effect of model resolution on the BC sensitivity is also studied.
    Type of Medium: Online Resource
    ISSN: 0148-0227
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2007
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  • 6
    In: Journal of Geophysical Research, American Geophysical Union (AGU), Vol. 112, No. D12 ( 2007-06-09)
    Type of Medium: Online Resource
    ISSN: 0148-0227
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2007
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  • 7
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 108, No. D21 ( 2003-11-16)
    Type of Medium: Online Resource
    ISSN: 0148-0227
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2003
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  • 8
    Online Resource
    Online Resource
    American Geophysical Union (AGU) ; 1994
    In:  Journal of Geophysical Research: Atmospheres Vol. 99, No. D1 ( 1994-01-20), p. 1671-1685
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 99, No. D1 ( 1994-01-20), p. 1671-1685
    Abstract: Airborne heat, moisture, O 3 , CO, and CH 4 flux measurements were obtained over the Hudson Bay lowlands (HBL) and northern boreal forest regions of Canada during July–August 1990. The airborne flux measurements were an integral part of the NASA/Arctic Boundary Layer Expedition (ABLE) 3B field experiment executed in collaboration with the Canadian Northern Wetlands Study (NOWES). Airborne CH 4 flux measurements were taken over a large portion of the HBL. The surface level flux of CH 4 was obtained from downward extrapolations of multiple‐level CH 4 flux measurements. Methane source strengths ranged from −1 to 31 mg m 2− d −1 , with the higher values occurring in relatively small, isolated areas. Similar measurements of the CH 4 source strength in the boreal forest region of Schefferville, Quebec, ranged from 6 to 27 mg m −2 d −1 and exhibited a diurnal dependence. The CH 4 source strengths found during the ABLE 3B expedition were much lower than the seasonally averaged source strength of 51 mg m −2 d −1 found for the Yukon‐Kuskokwim delta region of Alaska during the previous ABLE 3A study. Large positive CO fluxes (0.31 to 0.53 parts per billion by volume (ppbv) m s −1 ) were observed over the inland, forested regions of the HBL study area, although the mechanism for the generation of these fluxes was not identified. Repetitive measurements along the same ground track at various times of day near the Schefferville site also suggested a diurnal dependence for CO emissions. Measurements of surface resistance to the uptake of O 3 (1.91 to 0.80 s cm −1 ) for the HBL areas investigated were comparable to those observed near the Schefferville site (3.40 to 1.10s cm −1 ). Surface resistance values for the ABLE 3B study area were somewhat less than those observed over the Yukon‐Kuskokwim delta during the previous ABLE 3A study. The budgets for heat, moisture, O 3 , CO, and CH 4 were evaluated. The residuals from these budget studies indicated, for the cases selected, a moderate net photochemical production of O 3 present in the boundary layer over the HBL that coincided with an in situ destruction of CO, although the mechanism responsible for the destruction of CO was not identified. Results from the O 3 budget analysis indicate the importance of in situ photochemical production and its possible dominance over surface deposition to the local O 3 budget at the Schefferville site. Measurements of the in situ production of O 3 indicated a direct relationship between the presence of biomass burning or large‐scale pollution effects. Residuals from budget calculations for conserved quantities (heat, moisture, and CH 4 ) were compared with their respective surface fluxes to provide a measure of the internal selfconsistency of the flux measurements.
    Type of Medium: Online Resource
    ISSN: 0148-0227
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 1994
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  • 9
    Online Resource
    Online Resource
    American Geophysical Union (AGU) ; 1990
    In:  Journal of Geophysical Research: Atmospheres Vol. 95, No. D10 ( 1990-09-20), p. 16875-16886
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 95, No. D10 ( 1990-09-20), p. 16875-16886
    Abstract: In situ airborne measurements of turbulent heat, moisture, momentum, ozone, and carbon monoxide fluxes in a convective boundary layer were obtained over a tropical rain forest between 1100 and 1630 LT on May 4, 1987. The aircraft flight path was chosen so as to fly over the tower site at the Ducke Forest Reserve near Manaus, Amazonas, Brazil. Both turbulence statistics and mean quantities were used to study the budgets of heat, water vapor, ozone, and carbon monoxide. Residuals were found in the heat and water vapor budgets and are largely explainable in terms of the bandwidth of the respective sensors used for making flux measurements. The confidence of the findings for the O 3 and CO budgets were found to be limited by the error in the determination of the along‐track advective component. The ozone budget study shows an accumulation rate in the boundary layer of 0.3±0.2 ppbv h −1 . The surface resistance to ozone during this flight was determined to be 0.06±0.03 s cm −1 , while the aerodynamic resistance was 0.14–0.17 s cm −1 . Results from the CO budget analysis show a midday accumulation rate of 0.6±0.3 ppbv h −1 in the Amazonian boundary layer. The evidence suggests production of CO in the PBL. A source of CO may exist below the lowest flight level (≈ 150 m), although it was not possible to determine what part of the flux at flight level was due to chemical production and what part may be due to surface emission.
    Type of Medium: Online Resource
    ISSN: 0148-0227
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 1990
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  • 10
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 104, No. D13 ( 1999-07-20), p. 16213-16232
    Abstract: Aircraft measurements of nonmethane hydrocarbons (NMHCs) and halocarbons were made over the remote South Pacific Ocean during late August‐early October 1996 for NASA's Global Tropospheric Experiment (GTE) Pacific Exploratory Mission‐Tropics A (PEM‐Tropics A). This paper discusses the large‐scale spatial distributions of selected trace gases encountered during PEM‐Tropics A. The PEM‐Tropics A observations are compared to measurements made over the southwestern pacific in early November 1995 as part of Aerosol Characterization Experiment (ACE 1). Continental pollution in the form of layers containing elevated levels of O 3 was observed during a majority of PEM‐Tropics flights, as well as during several ACE 1 flights. The chemical composition of these air masses indicates that they were not fresh and were derived from nonurban combustion sources. The substantial impact of biomass burning on the vertical structure of the South Pacific troposphere is discussed.
    Type of Medium: Online Resource
    ISSN: 0148-0227
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 1999
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