In:
Chemische Berichte, Wiley, Vol. 104, No. 1 ( 1971-01), p. 333-342
Abstract:
Cyclic Organosilyl‐, Organogermyl‐ and Organostannyl‐phosphines. Diphenyldichlorosilane and diphenylgermanium dichloride react with dipotassium phenylphosphide as well as with potassium hydrogen phenylphosphide to form dimeric and trimeric (diphenylsilyl)phenylphosphine ( 1a , 1b ) and (diphenylgermyl)phenylphosphine ( 4a , 4b ), respectively. On the other hand the reaction of diphenylgermanium dichloride and phenylphosphine in the presence of triethylamine yields only bis(diphenylchlorogermyl)phenylphosphine ( 3 ), while dimethyl‐, dibutyl‐, and diphenyltin dichloride and phenylphosphine form the cyclic trimeric (dimethylstannyl)‐, (dibutylstannyl)‐, and (diphenylstannyl)phenylphosphines ( 5 – 7 ).
Type of Medium:
Online Resource
ISSN:
0009-2940
DOI:
10.1002/cber.19711040138
Language:
English
Publisher:
Wiley
Publication Date:
1971
detail.hit.zdb_id:
1475009-0
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