In:
ChemistrySelect, Wiley, Vol. 4, No. 14 ( 2019-04-16), p. 4156-4158
Abstract:
An unprecedented conjugate addition/C−O ester migration of α ‐cyano arylacetates with a quinone monoamine was presented, which allowed for the synthesis of various 2,2‐diarylacetonitriles in moderate to quantitative yields. This method is applicable to a series of α ‐cyano arylacetates with different aryl groups. Moreover, in order to demonstrate the synthetic utility of this transformation, 2‐(cyano(phenyl))‐4‐(4‐methylphenylsulfonamido)ethyl carbonate was subjected in hydrogenation to generate a 2,2‐diarylethylcarbamate.
Type of Medium:
Online Resource
ISSN:
2365-6549
,
2365-6549
DOI:
10.1002/slct.201900773
Language:
English
Publisher:
Wiley
Publication Date:
2019
detail.hit.zdb_id:
2844262-3
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